Search Results - "Jay A. Labinger"

Tutorial on Oxidative Addition.

Authors: Jay A. Labinger¹

Source: Organometallics. Oct2015, Vol. 34 Issue 20, p4784-4795. 12p.

Subjects: Oxidative addition, Organometallic chemistry, Haloalkanes, Addition reactions, Chemical research

Large Kinetic Isotope Effects for the Protonolysis of Metal–Methyl Complexes Are Not Reliable Mechanistic Indicators.

Authors: Valerie J. Scott Jay A. Labinger John E. Bercaw

Source: Organometallics. Aug2011, Vol. 30 Issue 16, p4374-4378. 5p.

Subjects: Chemical kinetics, Isotopes, Proton transfer reactions, Transition metal complexes, Quantum chemistry, Quantum tunneling, Reaction mechanisms (Chemistry), Statistical correlation

Trialkylborane-Assisted CO2Reduction by Late Transition Metal Hydrides.

Authors: Alexander J. M. Miller Jay A. Labinger John E. Bercaw

Source: Organometallics. Aug2011, Vol. 30 Issue 16, p4308-4314. 7p.

Subjects: Carbon dioxide, Boranes, Chemical reduction, Transition metal hydrides, Transition metal complexes, Chemical equilibrium, Reaction mechanisms (Chemistry)

Mechanism of Reductive Elimination of Methyl Iodide from a Novel Gold(III)−Monomethyl Complex.

Authors: Valerie J. Scott Jay A. Labinger John E. Bercaw

Source: Organometallics. Sep2010, Vol. 29 Issue 18, p4090-4096. 7p.

Subjects: Iodides, Methyl groups, Metal complexes, Gold, Oxidation, Nucleophilic reactions, Chemical reduction

Reactions of Indene and Indoles with Platinum Methyl Cations:  Indene C−H Activation, Indole versus Nitrogen Lone-Pair Coordination.

Authors: Travis J. Williams Jay A. Labinger John E. Bercaw

Source: Organometallics. Jan2007, Vol. 26 Issue 2, p281-287. 7p.

Subjects: Cations, Nitrogen, Platinum, Indole

Selective Oxidation of sp3C−H Bonds in Water Catalyzed by a Glycinate−Platinum(II) Complex.

Authors: George S. Chen Jay A. Labinger John E. Bercaw

Source: Organometallics. Sep2009, Vol. 28 Issue 17, p4899-4901. 3p.

Subjects: Metal complexes, Organoplatinum compounds, Chemical bonds, Oxidation, Water, Solution (Chemistry), Methyl groups, Sulfonates

Protonolysis of Platinum(II) and Palladium(II) Methyl Complexes: A Combined Experimental and Theoretical Investigation.

Authors: John E. Bercaw George S. Chen Jay A. Labinger et al.

Source: Organometallics. Oct2010, Vol. 29 Issue 19, p4354-4359. 6p.

Subjects: Organoplatinum compounds, Organopalladium compounds, Complex compounds, Density functionals, Temperature effect, Quantum tunneling, Electron donor-acceptor complexes, Ligands (Chemistry)

Transformations of Group 7 Carbonyl Complexes: Possible Intermediates in a Homogeneous Syngas Conversion Scheme.

Authors: Paul R. Elowe Nathan M. West Jay A. Labinger et al.

Source: Organometallics. Nov2009, Vol. 28 Issue 21, p6218-6227. 10p.

Subjects: Metal complexes, Carbonyl compounds, Intermediates (Chemistry), Chemical bonds, Synthesis gas, Metal catalysts, Boranes, Organomanganese compounds

Activation of a C−H Bond in Indene by [(COD)Rh(μ2-OH)]2†.

Authors: John E. Bercaw Nilay Hazari Jay A. Labinger

Source: Organometallics. Sep2009, Vol. 28 Issue 18, p5489-5492. 4p.

Subjects: Activation (Chemistry), Organorhodium compounds, Indene, Chemical bonds, Dimers, Reaction mechanisms (Chemistry), Molecular structure, Imines

Competitive Benzene C−H Bond Activation versus Olefin Insertion in a (Monomethyl)palladium(II) β-Diketiminate Complex.

Authors: Bo-Lin Lin Koyel X. Bhattacharyya Jay A. Labinger et al.

Source: Organometallics. Aug2009, Vol. 28 Issue 15, p4400-4405. 6p.

Subjects: Benzene, Chemical bonds, Activation (Chemistry), Alkenes, Organopalladium compounds, Metal complexes, Temperature effect

C−H Bond Activation by Dicationic Platinum(II) Complexes.

Authors: Tom G. Driver Travis J. Williams Jay A. Labinger et al.

Source: Organometallics. Jan2007, Vol. 26 Issue 2, p294-301. 8p.

Subjects: Complex compounds, Platinum, Coordination compounds, Activation (Chemistry)

Mechanistic Insights on the Controlled Switch fromOligomerization to Polymerization of 1-Hexene Catalyzed byan NHC-Zirconium Complex.

Authors: Emmanuelle Despagnet-Ayoub Michael K. Takase Lawrence M. Henling et al.

Source: Organometallics. Oct2015, Vol. 34 Issue 19, p4707-4716. 10p.

Robotic Lepidoptery: Structural Characterization of (mostly) Unexpected Palladium Complexes Obtained from High-Throughput Catalyst Screening.

Authors: John E. Bercaw Michael W. Day Suzanne R. Golisz et al.

Source: Organometallics. Sep2009, Vol. 28 Issue 17, p5017-5024. 8p.

Enhanced selectivity in the conversion of methanol to 2,2,3-trimethylbutane (triptane) over zinc iodide by added phosphorous or hypophosphorous acid.

Authors: John E. Bercaw Robert H. Grubbs Nilay Hazari et al.

Source: Chemical Communications. Jul2007, Vol. 2007 Issue 28, p2974-2976. 3p.