Effect of impurity interaction on the corrosion film characteristics and corrosion morphology evolution of X65 steel in water-saturated supercritical CO2 system.

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Title: Effect of impurity interaction on the corrosion film characteristics and corrosion morphology evolution of X65 steel in water-saturated supercritical CO2 system.
Authors: Sun, Chong1,2, Sun, Jianbo1 sunjianbo@upc.edu.cn, Wang, Yong1, Sui, Pengfei1, Lin, Xueqiang1, Liu, Huifeng1, Cheng, Xiangkun1, Zhou, Mingnan1
Source: International Journal of Greenhouse Gas Control. Oct2017, Vol. 65, p117-127. 11p.
Subject Terms: Supercritical carbon dioxide, Impurity-dislocation interactions, Corrosion & anti-corrosives testing, Water-saturated sites (Archaeology), Steel pipe
Abstract: The corrosion behavior of X65 steel in water-saturated supercritical CO 2 system containing NO 2 with or without O 2 , H 2 S and SO 2 impurities was investigated using weight loss measurement and surface analysis techniques. The interactions between NO 2 and O 2 , SO 2 or H 2 S promoted the formation of extra corrosive species and subsequently changed the corrosion film characteristics. In water-saturated supercritical CO 2 -NO 2 -O 2 -SO 2 -H 2 S system, FeSO 4 and S preferentially formed in the early corrosion stage due to the impurity interactions. As the corrosion time prolonged, (NH 4 )Fe 3 (SO 4 ) 2 (OH) 6 and FeOOH formed due to the subsequent reactions of the impurity interaction products, and S disappeared in the corrosion scale via participating in the subsequent corrosion reactions during long-term corrosion. Localized corrosion was initiated by the inhomogeneous precipitation of acid-rich water in the presence of NO 2 . However, the propagation rate of the corrosion pit in depth direction greatly reduced with time, and the corrosion morphology of X65 steel shifted from localized corrosion towards general corrosion during long-term corrosion. [ABSTRACT FROM AUTHOR]
Copyright of International Journal of Greenhouse Gas Control is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Label: Title
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  Data: Effect of impurity interaction on the corrosion film characteristics and corrosion morphology evolution of X65 steel in water-saturated supercritical CO2 system.
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  Data: <searchLink fieldCode="AR" term="%22Sun%2C+Chong%22">Sun, Chong</searchLink><relatesTo>1,2</relatesTo><br /><searchLink fieldCode="AR" term="%22Sun%2C+Jianbo%22">Sun, Jianbo</searchLink><relatesTo>1</relatesTo><i> sunjianbo@upc.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Wang%2C+Yong%22">Wang, Yong</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Sui%2C+Pengfei%22">Sui, Pengfei</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Lin%2C+Xueqiang%22">Lin, Xueqiang</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Liu%2C+Huifeng%22">Liu, Huifeng</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Cheng%2C+Xiangkun%22">Cheng, Xiangkun</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Zhou%2C+Mingnan%22">Zhou, Mingnan</searchLink><relatesTo>1</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22International+Journal+of+Greenhouse+Gas+Control%22">International Journal of Greenhouse Gas Control</searchLink>. Oct2017, Vol. 65, p117-127. 11p.
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  Data: <searchLink fieldCode="DE" term="%22Supercritical+carbon+dioxide%22">Supercritical carbon dioxide</searchLink><br /><searchLink fieldCode="DE" term="%22Impurity-dislocation+interactions%22">Impurity-dislocation interactions</searchLink><br /><searchLink fieldCode="DE" term="%22Corrosion+%26+anti-corrosives+testing%22">Corrosion & anti-corrosives testing</searchLink><br /><searchLink fieldCode="DE" term="%22Water-saturated+sites+%28Archaeology%29%22">Water-saturated sites (Archaeology)</searchLink><br /><searchLink fieldCode="DE" term="%22Steel+pipe%22">Steel pipe</searchLink>
– Name: Abstract
  Label: Abstract
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  Data: The corrosion behavior of X65 steel in water-saturated supercritical CO 2 system containing NO 2 with or without O 2 , H 2 S and SO 2 impurities was investigated using weight loss measurement and surface analysis techniques. The interactions between NO 2 and O 2 , SO 2 or H 2 S promoted the formation of extra corrosive species and subsequently changed the corrosion film characteristics. In water-saturated supercritical CO 2 -NO 2 -O 2 -SO 2 -H 2 S system, FeSO 4 and S preferentially formed in the early corrosion stage due to the impurity interactions. As the corrosion time prolonged, (NH 4 )Fe 3 (SO 4 ) 2 (OH) 6 and FeOOH formed due to the subsequent reactions of the impurity interaction products, and S disappeared in the corrosion scale via participating in the subsequent corrosion reactions during long-term corrosion. Localized corrosion was initiated by the inhomogeneous precipitation of acid-rich water in the presence of NO 2 . However, the propagation rate of the corrosion pit in depth direction greatly reduced with time, and the corrosion morphology of X65 steel shifted from localized corrosion towards general corrosion during long-term corrosion. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of International Journal of Greenhouse Gas Control is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1016/j.ijggc.2017.09.002
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      – Code: eng
        Text: English
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        PageCount: 11
        StartPage: 117
    Subjects:
      – SubjectFull: Supercritical carbon dioxide
        Type: general
      – SubjectFull: Impurity-dislocation interactions
        Type: general
      – SubjectFull: Corrosion & anti-corrosives testing
        Type: general
      – SubjectFull: Water-saturated sites (Archaeology)
        Type: general
      – SubjectFull: Steel pipe
        Type: general
    Titles:
      – TitleFull: Effect of impurity interaction on the corrosion film characteristics and corrosion morphology evolution of X65 steel in water-saturated supercritical CO2 system.
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            NameFull: Sun, Chong
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            NameFull: Lin, Xueqiang
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            – D: 01
              M: 10
              Text: Oct2017
              Type: published
              Y: 2017
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              Value: 65
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            – TitleFull: International Journal of Greenhouse Gas Control
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