Effects of process parameters on the physicochemical properties of corn stalk hydrochar and the removal of alkali and alkaline earth metals.

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Title: Effects of process parameters on the physicochemical properties of corn stalk hydrochar and the removal of alkali and alkaline earth metals.
Authors: Yang, Li1,2, Wang, Hui1 wanghui_hb@hit.edu.cn, Sun, Jianwei1, Xu, Yiyun2, Li, Pengcheng2, Xu, Youning3, Wu, Shaohua1
Source: IET Renewable Power Generation (Wiley-Blackwell). May2021, Vol. 15 Issue 7, p1397-1407. 11p.
Subject Terms: *Hydrothermal carbonization, *Alkaline earth metals, *Biomass energy, Cornstalks, Alkali metal compounds, Scanning electron microscopy
Abstract: The advantages of the direct combustion of agricultural biomass for power generation are restricted due to the drawbacks of this biomass and the deep peak shaving trend. Hydrothermal carbonization can improve the physical and thermochemical properties of raw materials. Corn stalk samples were selected as the research object in this study. Corn stalk hydrochars were prepared with reaction pressures of 0–3 MPa, reaction temperatures of 160–240 °C, and residence times of 1–10 h. The effects of the process parameters on the physicochemical properties of hydrochar and on the removal of alkali and alkaline earth metals (AAEMs) were studied by measuring the hydrochar mass, energy yield, product composition, morphology, as well as the removal efficiency of AAEMs. The results indicated that the corn stalk hydrochar had higher mass and energy yields than the raw corn stalk. X‐ray diffraction showed that the carbon content in the hydrochar was greater than that in raw corn stalk. Scanning electron microscopy showed that the reaction temperature played a more significant role in the hydrothermal carbonization process than the reaction pressure and residence time. [ABSTRACT FROM AUTHOR]
Copyright of IET Renewable Power Generation (Wiley-Blackwell) is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Label: Title
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  Data: Effects of process parameters on the physicochemical properties of corn stalk hydrochar and the removal of alkali and alkaline earth metals.
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  Data: <searchLink fieldCode="AR" term="%22Yang%2C+Li%22">Yang, Li</searchLink><relatesTo>1,2</relatesTo><br /><searchLink fieldCode="AR" term="%22Wang%2C+Hui%22">Wang, Hui</searchLink><relatesTo>1</relatesTo><i> wanghui_hb@hit.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Sun%2C+Jianwei%22">Sun, Jianwei</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Xu%2C+Yiyun%22">Xu, Yiyun</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Li%2C+Pengcheng%22">Li, Pengcheng</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Xu%2C+Youning%22">Xu, Youning</searchLink><relatesTo>3</relatesTo><br /><searchLink fieldCode="AR" term="%22Wu%2C+Shaohua%22">Wu, Shaohua</searchLink><relatesTo>1</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22IET+Renewable+Power+Generation+%28Wiley-Blackwell%29%22">IET Renewable Power Generation (Wiley-Blackwell)</searchLink>. May2021, Vol. 15 Issue 7, p1397-1407. 11p.
– Name: Subject
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  Data: *<searchLink fieldCode="DE" term="%22Hydrothermal+carbonization%22">Hydrothermal carbonization</searchLink><br />*<searchLink fieldCode="DE" term="%22Alkaline+earth+metals%22">Alkaline earth metals</searchLink><br />*<searchLink fieldCode="DE" term="%22Biomass+energy%22">Biomass energy</searchLink><br /><searchLink fieldCode="DE" term="%22Cornstalks%22">Cornstalks</searchLink><br /><searchLink fieldCode="DE" term="%22Alkali+metal+compounds%22">Alkali metal compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Scanning+electron+microscopy%22">Scanning electron microscopy</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: The advantages of the direct combustion of agricultural biomass for power generation are restricted due to the drawbacks of this biomass and the deep peak shaving trend. Hydrothermal carbonization can improve the physical and thermochemical properties of raw materials. Corn stalk samples were selected as the research object in this study. Corn stalk hydrochars were prepared with reaction pressures of 0–3 MPa, reaction temperatures of 160–240 °C, and residence times of 1–10 h. The effects of the process parameters on the physicochemical properties of hydrochar and on the removal of alkali and alkaline earth metals (AAEMs) were studied by measuring the hydrochar mass, energy yield, product composition, morphology, as well as the removal efficiency of AAEMs. The results indicated that the corn stalk hydrochar had higher mass and energy yields than the raw corn stalk. X‐ray diffraction showed that the carbon content in the hydrochar was greater than that in raw corn stalk. Scanning electron microscopy showed that the reaction temperature played a more significant role in the hydrothermal carbonization process than the reaction pressure and residence time. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of IET Renewable Power Generation (Wiley-Blackwell) is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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    Identifiers:
      – Type: doi
        Value: 10.1049/rpg2.12082
    Languages:
      – Code: eng
        Text: English
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        PageCount: 11
        StartPage: 1397
    Subjects:
      – SubjectFull: Hydrothermal carbonization
        Type: general
      – SubjectFull: Alkaline earth metals
        Type: general
      – SubjectFull: Biomass energy
        Type: general
      – SubjectFull: Cornstalks
        Type: general
      – SubjectFull: Alkali metal compounds
        Type: general
      – SubjectFull: Scanning electron microscopy
        Type: general
    Titles:
      – TitleFull: Effects of process parameters on the physicochemical properties of corn stalk hydrochar and the removal of alkali and alkaline earth metals.
        Type: main
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            NameFull: Yang, Li
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            NameFull: Wang, Hui
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            NameFull: Sun, Jianwei
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            NameFull: Xu, Yiyun
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            NameFull: Li, Pengcheng
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            NameFull: Xu, Youning
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            – D: 01
              M: 05
              Text: May2021
              Type: published
              Y: 2021
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              Value: 17521416
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              Value: 15
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              Value: 7
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            – TitleFull: IET Renewable Power Generation (Wiley-Blackwell)
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