View in EDS

The impact of bead milling on the thermodynamics and kinetics of the structural phase transition of VO2 particulate materials and their potential for use in thermochromic glazing.

Saved in:
Bibliographic Details
Title: The impact of bead milling on the thermodynamics and kinetics of the structural phase transition of VO2 particulate materials and their potential for use in thermochromic glazing.
Authors: Calvi, Lavinia1,2 (AUTHOR), van Geijn, Romy3,4,5 (AUTHOR), Leufkens, Luc3,4 (AUTHOR), Habets, Roberto3,4 (AUTHOR), Gurunatha, Kargal Laxminarayana6 (AUTHOR), Stout, Kathleen5 (AUTHOR), Mann, Daniel3,4 (AUTHOR), Papakonstantinou, Ioannis6 (AUTHOR), Parkin, Ivan P.7 (AUTHOR), Elen, Ken1,2 (AUTHOR), Hardy, An1,2 (AUTHOR), van Bael, Marlies K.1,2 (AUTHOR), Buskens, Pascal1,3,4 (AUTHOR) pascal.buskens@tno.nl
Source: Solar Energy Materials & Solar Cells. Aug2022, Vol. 242, pN.PAG-N.PAG. 1p.
Subject Terms: Phase transitions, Thermodynamics, Oxygen consumption, Potential energy, Activation energy, Electrochromic devices, Mechanical alloying
Abstract: The thermodynamics and kinetics of the structural phase transition from monoclinic VO 2 (M) to rutile VO 2 (R) and vice versa were studied for particulate materials obtained by bead milling of VO 2 (M) powder. Using wet bead milling, we decreased the particle size of VO 2 (M) powder from ∼1 μm to 129 nm. With progressive milling, the switching enthalpy decreased from 47 J g−1 to 29 J g−1 due to a loss of crystallinity. The switching kinetics were studied using Friedman's differential isoconversional method. The activation energy | E α | decreases with increasing difference between the actual temperature of the material and its switching temperature (T 0). Furthermore, | E α | decreases with progressive milling, and kinetic asymmetry is induced. For milled particulate materials, | E α | is lower for the switch from VO 2 (R) to VO 2 (M) than for the opposite switch. For hydrothermally synthesized nanoparticles, | E α | is in the same order of magnitude, albeit with inverse switching asymmetry. Latter may result from different defects that are introduced during both preparation techniques. Applying layers of milled particulate material to glass sheets yielded thermochromic coatings with luminous transmission of 40.7% and solar modulation of 8.3%. This demonstrates that milled VO 2 particles have potential for use in energy efficient thermochromic windows. [Display omitted] • Switching enthalpy of VO 2 particulate material decreases with progressive milling. • Activation energy of the structural phase transition decreases with particle size. • Progressive milling induces asymmetry in switching kinetics of particulate material. • Hydrothermally synthesized particles display inverse asymmetry in kinetics. • Milled VO 2 particulate materials are suited for use in thermochromic windows. [ABSTRACT FROM AUTHOR]
Copyright of Solar Energy Materials & Solar Cells is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: GreenFILE
FullText Text:
  Availability: 0
Header DbId: 8gh
DbLabel: GreenFILE
An: 156895061
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
IllustrationInfo
Items – Name: Title
  Label: Title
  Group: Ti
  Data: The impact of bead milling on the thermodynamics and kinetics of the structural phase transition of VO2 particulate materials and their potential for use in thermochromic glazing.
– Name: Author
  Label: Authors
  Group: Au
  Data: <searchLink fieldCode="AR" term="%22Calvi%2C+Lavinia%22">Calvi, Lavinia</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22van+Geijn%2C+Romy%22">van Geijn, Romy</searchLink><relatesTo>3,4,5</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Leufkens%2C+Luc%22">Leufkens, Luc</searchLink><relatesTo>3,4</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Habets%2C+Roberto%22">Habets, Roberto</searchLink><relatesTo>3,4</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Gurunatha%2C+Kargal+Laxminarayana%22">Gurunatha, Kargal Laxminarayana</searchLink><relatesTo>6</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Stout%2C+Kathleen%22">Stout, Kathleen</searchLink><relatesTo>5</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Mann%2C+Daniel%22">Mann, Daniel</searchLink><relatesTo>3,4</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Papakonstantinou%2C+Ioannis%22">Papakonstantinou, Ioannis</searchLink><relatesTo>6</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Parkin%2C+Ivan+P%2E%22">Parkin, Ivan P.</searchLink><relatesTo>7</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Elen%2C+Ken%22">Elen, Ken</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Hardy%2C+An%22">Hardy, An</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22van+Bael%2C+Marlies+K%2E%22">van Bael, Marlies K.</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Buskens%2C+Pascal%22">Buskens, Pascal</searchLink><relatesTo>1,3,4</relatesTo> (AUTHOR)<i> pascal.buskens@tno.nl</i>
– Name: TitleSource
  Label: Source
  Group: Src
  Data: <searchLink fieldCode="JN" term="%22Solar+Energy+Materials+%26+Solar+Cells%22">Solar Energy Materials & Solar Cells</searchLink>. Aug2022, Vol. 242, pN.PAG-N.PAG. 1p.
– Name: Subject
  Label: Subject Terms
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Phase+transitions%22">Phase transitions</searchLink><br /><searchLink fieldCode="DE" term="%22Thermodynamics%22">Thermodynamics</searchLink><br /><searchLink fieldCode="DE" term="%22Oxygen+consumption%22">Oxygen consumption</searchLink><br /><searchLink fieldCode="DE" term="%22Potential+energy%22">Potential energy</searchLink><br /><searchLink fieldCode="DE" term="%22Activation+energy%22">Activation energy</searchLink><br /><searchLink fieldCode="DE" term="%22Electrochromic+devices%22">Electrochromic devices</searchLink><br /><searchLink fieldCode="DE" term="%22Mechanical+alloying%22">Mechanical alloying</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: The thermodynamics and kinetics of the structural phase transition from monoclinic VO 2 (M) to rutile VO 2 (R) and vice versa were studied for particulate materials obtained by bead milling of VO 2 (M) powder. Using wet bead milling, we decreased the particle size of VO 2 (M) powder from ∼1 μm to 129 nm. With progressive milling, the switching enthalpy decreased from 47 J g−1 to 29 J g−1 due to a loss of crystallinity. The switching kinetics were studied using Friedman's differential isoconversional method. The activation energy | E α | decreases with increasing difference between the actual temperature of the material and its switching temperature (T 0). Furthermore, | E α | decreases with progressive milling, and kinetic asymmetry is induced. For milled particulate materials, | E α | is lower for the switch from VO 2 (R) to VO 2 (M) than for the opposite switch. For hydrothermally synthesized nanoparticles, | E α | is in the same order of magnitude, albeit with inverse switching asymmetry. Latter may result from different defects that are introduced during both preparation techniques. Applying layers of milled particulate material to glass sheets yielded thermochromic coatings with luminous transmission of 40.7% and solar modulation of 8.3%. This demonstrates that milled VO 2 particles have potential for use in energy efficient thermochromic windows. [Display omitted] • Switching enthalpy of VO 2 particulate material decreases with progressive milling. • Activation energy of the structural phase transition decreases with particle size. • Progressive milling induces asymmetry in switching kinetics of particulate material. • Hydrothermally synthesized particles display inverse asymmetry in kinetics. • Milled VO 2 particulate materials are suited for use in thermochromic windows. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Solar Energy Materials & Solar Cells is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
PLink https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&db=8gh&AN=156895061
RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1016/j.solmat.2022.111783
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 1
        StartPage: N.PAG
    Subjects:
      – SubjectFull: Phase transitions
        Type: general
      – SubjectFull: Thermodynamics
        Type: general
      – SubjectFull: Oxygen consumption
        Type: general
      – SubjectFull: Potential energy
        Type: general
      – SubjectFull: Activation energy
        Type: general
      – SubjectFull: Electrochromic devices
        Type: general
      – SubjectFull: Mechanical alloying
        Type: general
    Titles:
      – TitleFull: The impact of bead milling on the thermodynamics and kinetics of the structural phase transition of VO2 particulate materials and their potential for use in thermochromic glazing.
        Type: main
  BibRelationships:
    HasContributorRelationships:
      – PersonEntity:
          Name:
            NameFull: Calvi, Lavinia
      – PersonEntity:
          Name:
            NameFull: van Geijn, Romy
      – PersonEntity:
          Name:
            NameFull: Leufkens, Luc
      – PersonEntity:
          Name:
            NameFull: Habets, Roberto
      – PersonEntity:
          Name:
            NameFull: Gurunatha, Kargal Laxminarayana
      – PersonEntity:
          Name:
            NameFull: Stout, Kathleen
      – PersonEntity:
          Name:
            NameFull: Mann, Daniel
      – PersonEntity:
          Name:
            NameFull: Papakonstantinou, Ioannis
      – PersonEntity:
          Name:
            NameFull: Parkin, Ivan P.
      – PersonEntity:
          Name:
            NameFull: Elen, Ken
      – PersonEntity:
          Name:
            NameFull: Hardy, An
      – PersonEntity:
          Name:
            NameFull: van Bael, Marlies K.
      – PersonEntity:
          Name:
            NameFull: Buskens, Pascal
    IsPartOfRelationships:
      – BibEntity:
          Dates:
            – D: 01
              M: 08
              Text: Aug2022
              Type: published
              Y: 2022
          Identifiers:
            – Type: issn-print
              Value: 09270248
          Numbering:
            – Type: volume
              Value: 242
          Titles:
            – TitleFull: Solar Energy Materials & Solar Cells
              Type: main
ResultId 1