An Antiferroelectric‐Coated Metal Foam Infiltrated with Liquid Metal as a Dielectric Capacitor.

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Title: An Antiferroelectric‐Coated Metal Foam Infiltrated with Liquid Metal as a Dielectric Capacitor.
Authors: Hanrahan, Brendan1 (AUTHOR) brendan.m.hanrahnan.civ@mail.mil, Leff, Asher2 (AUTHOR), Sesar, Alexis3 (AUTHOR), Fish, Michael1 (AUTHOR), Jaszewski, Samantha T.4 (AUTHOR), Kropp, Jaron A.5 (AUTHOR), Strnad, Nicholas1 (AUTHOR), Ihlefeld, Jon F.4,6 (AUTHOR), Lazarus, Nathan7 (AUTHOR)
Source: Energy Technology. Jan2025, Vol. 13 Issue 1, p1-7. 7p.
Subject Terms: Electric field strength, Power capacitors, Polarization (Electricity), Liquid metals, Metal foams
Abstract: Nickel metal foams serve as both a substrate and bottom electrode for a dielectric capacitor using atomic‐layer deposition (ALD) and a eutectic gallium–indium (EGaIn) liquid metal (LQM) counter electrode. The conformal dielectric has a composition of 6.25% Al–HfO2 in the antiferroelectric phase, confirmed with polarization versus electric field measurements. Liquid EGaIn is pressure‐infiltrated within the coated foams to form the dielectric capacitor. Capacitances up to 4 μF are realized. Calorimetry of the infiltrated capacitor shows a 60 J g−1 latent heat upon melting a frozen EGaIn electrode, suggesting that the phase change can alleviate thermal deviations from pulsed power capacitor operation. Infiltrated capacitors are also shown to survive bending and freeze–thaw cycles. The metal foam–ALD dielectric–LQM capacitor shows a combined set of thermal and electrical properties not available in other classes of capacitors. [ABSTRACT FROM AUTHOR]
Copyright of Energy Technology is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: An Antiferroelectric‐Coated Metal Foam Infiltrated with Liquid Metal as a Dielectric Capacitor.
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  Data: <searchLink fieldCode="AR" term="%22Hanrahan%2C+Brendan%22">Hanrahan, Brendan</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> brendan.m.hanrahnan.civ@mail.mil</i><br /><searchLink fieldCode="AR" term="%22Leff%2C+Asher%22">Leff, Asher</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Sesar%2C+Alexis%22">Sesar, Alexis</searchLink><relatesTo>3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Fish%2C+Michael%22">Fish, Michael</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Jaszewski%2C+Samantha+T%2E%22">Jaszewski, Samantha T.</searchLink><relatesTo>4</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Kropp%2C+Jaron+A%2E%22">Kropp, Jaron A.</searchLink><relatesTo>5</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Strnad%2C+Nicholas%22">Strnad, Nicholas</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Ihlefeld%2C+Jon+F%2E%22">Ihlefeld, Jon F.</searchLink><relatesTo>4,6</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Lazarus%2C+Nathan%22">Lazarus, Nathan</searchLink><relatesTo>7</relatesTo> (AUTHOR)
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  Data: <searchLink fieldCode="JN" term="%22Energy+Technology%22">Energy Technology</searchLink>. Jan2025, Vol. 13 Issue 1, p1-7. 7p.
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  Data: Nickel metal foams serve as both a substrate and bottom electrode for a dielectric capacitor using atomic‐layer deposition (ALD) and a eutectic gallium–indium (EGaIn) liquid metal (LQM) counter electrode. The conformal dielectric has a composition of 6.25% Al–HfO2 in the antiferroelectric phase, confirmed with polarization versus electric field measurements. Liquid EGaIn is pressure‐infiltrated within the coated foams to form the dielectric capacitor. Capacitances up to 4 μF are realized. Calorimetry of the infiltrated capacitor shows a 60 J g−1 latent heat upon melting a frozen EGaIn electrode, suggesting that the phase change can alleviate thermal deviations from pulsed power capacitor operation. Infiltrated capacitors are also shown to survive bending and freeze–thaw cycles. The metal foam–ALD dielectric–LQM capacitor shows a combined set of thermal and electrical properties not available in other classes of capacitors. [ABSTRACT FROM AUTHOR]
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  Label:
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  Data: <i>Copyright of Energy Technology is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1002/ente.202400956
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        Text: English
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      – SubjectFull: Electric field strength
        Type: general
      – SubjectFull: Power capacitors
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      – SubjectFull: Polarization (Electricity)
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      – SubjectFull: Liquid metals
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      – SubjectFull: Metal foams
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      – TitleFull: An Antiferroelectric‐Coated Metal Foam Infiltrated with Liquid Metal as a Dielectric Capacitor.
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              Text: Jan2025
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              Y: 2025
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