Superabsorbent Hydrogel Based on Angico Gum Containing a Hybrid Mineral–Carbon Fraction for Environmental Remediation: Potential for Ciprofloxacin Removal.
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| Title: | Superabsorbent Hydrogel Based on Angico Gum Containing a Hybrid Mineral–Carbon Fraction for Environmental Remediation: Potential for Ciprofloxacin Removal. |
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| Authors: | Silva, Albert Santos1,2 (AUTHOR), de Oliveira, Luís Humberto1 (AUTHOR), Moura, Emerson Alves Costa1 (AUTHOR), Osajima, Josy Anteveli1 (AUTHOR), Muniz, Edvani Curti3 (AUTHOR), Medina-Carrasco, Santiago4 (AUTHOR), Orta Cuevas, Maria del Mar2 (AUTHOR) enmaorta@us.es, Silva-Filho, Edson C.1 (AUTHOR) |
| Source: | Journal of Polymers & the Environment. Jun2026, Vol. 34 Issue 6, p1-22. 22p. |
| Abstract: | The increasing presence of emerging contaminants in aquatic environments has motivated the development of adsorbent materials derived from natural matrices. In this study, for the first time, a superabsorbent hydrogel based on angico gum (HGA) was synthesized and modified by incorporating a hybrid mineral-carbon fraction (MIN), composed of montmorillonite, sepiolite, and activated carbon, aiming to combine the high adsorption capacity of mineral adsorbents with the structural and reusability advantages of hydrogels for the removal of ciprofloxacin (CPX) from aqueous solutions. The resulting composite (HGA-MIN) was characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermogravimetric analysis (TG), scanning electron microscopy (SEM), and X-ray microcomputed tomography (micro-CT). FTIR and XRD analyses confirmed the preservation of the polymeric structure and the successful incorporation of the mineral fraction into the matrix. Micro-CT analysis revealed a reduction in porosity from 81.32% (HGA) to 22.99% (HGA-MIN). The composite exhibited a high swelling capacity (14,811.83%) and a point of zero charge (pHpzc) of 8.52, favoring CPX adsorption under acidic conditions. Adsorption experiments showed a maximum adsorption capacity of 234.8 mg g− 1, with equilibrium reached within 30 min. Kinetic data followed the pseudo-second-order model, while equilibrium data were best described by the Sips isotherm. Thermodynamic analysis indicated that the adsorption process is spontaneous and exothermic, and reusability tests demonstrated retention of more than 90% of the adsorption capacity after five cycles. These results highlight HGA-MIN as an efficient and sustainable material for the removal of ciprofloxacin from water. [ABSTRACT FROM AUTHOR] |
| Copyright of Journal of Polymers & the Environment is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | GreenFILE |
| FullText | Text: Availability: 0 |
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| Header | DbId: 8gh DbLabel: GreenFILE An: 193996546 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Superabsorbent Hydrogel Based on Angico Gum Containing a Hybrid Mineral–Carbon Fraction for Environmental Remediation: Potential for Ciprofloxacin Removal. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Silva%2C+Albert+Santos%22">Silva, Albert Santos</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22de+Oliveira%2C+Luís+Humberto%22">de Oliveira, Luís Humberto</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Moura%2C+Emerson+Alves+Costa%22">Moura, Emerson Alves Costa</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Osajima%2C+Josy+Anteveli%22">Osajima, Josy Anteveli</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Muniz%2C+Edvani+Curti%22">Muniz, Edvani Curti</searchLink><relatesTo>3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Medina-Carrasco%2C+Santiago%22">Medina-Carrasco, Santiago</searchLink><relatesTo>4</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Orta+Cuevas%2C+Maria+del+Mar%22">Orta Cuevas, Maria del Mar</searchLink><relatesTo>2</relatesTo> (AUTHOR)<i> enmaorta@us.es</i><br /><searchLink fieldCode="AR" term="%22Silva-Filho%2C+Edson+C%2E%22">Silva-Filho, Edson C.</searchLink><relatesTo>1</relatesTo> (AUTHOR) – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Journal+of+Polymers+%26+the+Environment%22">Journal of Polymers & the Environment</searchLink>. Jun2026, Vol. 34 Issue 6, p1-22. 22p. – Name: Abstract Label: Abstract Group: Ab Data: The increasing presence of emerging contaminants in aquatic environments has motivated the development of adsorbent materials derived from natural matrices. In this study, for the first time, a superabsorbent hydrogel based on angico gum (HGA) was synthesized and modified by incorporating a hybrid mineral-carbon fraction (MIN), composed of montmorillonite, sepiolite, and activated carbon, aiming to combine the high adsorption capacity of mineral adsorbents with the structural and reusability advantages of hydrogels for the removal of ciprofloxacin (CPX) from aqueous solutions. The resulting composite (HGA-MIN) was characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermogravimetric analysis (TG), scanning electron microscopy (SEM), and X-ray microcomputed tomography (micro-CT). FTIR and XRD analyses confirmed the preservation of the polymeric structure and the successful incorporation of the mineral fraction into the matrix. Micro-CT analysis revealed a reduction in porosity from 81.32% (HGA) to 22.99% (HGA-MIN). The composite exhibited a high swelling capacity (14,811.83%) and a point of zero charge (pHpzc) of 8.52, favoring CPX adsorption under acidic conditions. Adsorption experiments showed a maximum adsorption capacity of 234.8 mg g− 1, with equilibrium reached within 30 min. Kinetic data followed the pseudo-second-order model, while equilibrium data were best described by the Sips isotherm. Thermodynamic analysis indicated that the adsorption process is spontaneous and exothermic, and reusability tests demonstrated retention of more than 90% of the adsorption capacity after five cycles. These results highlight HGA-MIN as an efficient and sustainable material for the removal of ciprofloxacin from water. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Journal of Polymers & the Environment is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1007/s10924-026-03861-z Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 22 StartPage: 1 Titles: – TitleFull: Superabsorbent Hydrogel Based on Angico Gum Containing a Hybrid Mineral–Carbon Fraction for Environmental Remediation: Potential for Ciprofloxacin Removal. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Silva, Albert Santos – PersonEntity: Name: NameFull: de Oliveira, Luís Humberto – PersonEntity: Name: NameFull: Moura, Emerson Alves Costa – PersonEntity: Name: NameFull: Osajima, Josy Anteveli – PersonEntity: Name: NameFull: Muniz, Edvani Curti – PersonEntity: Name: NameFull: Medina-Carrasco, Santiago – PersonEntity: Name: NameFull: Orta Cuevas, Maria del Mar – PersonEntity: Name: NameFull: Silva-Filho, Edson C. IsPartOfRelationships: – BibEntity: Dates: – D: 01 M: 06 Text: Jun2026 Type: published Y: 2026 Identifiers: – Type: issn-print Value: 15662543 Numbering: – Type: volume Value: 34 – Type: issue Value: 6 Titles: – TitleFull: Journal of Polymers & the Environment Type: main |
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