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Reaction mode between Si and Fe and evaluation of optimal species in poly-silicic-ferric coagulant

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Title: Reaction mode between Si and Fe and evaluation of optimal species in poly-silicic-ferric coagulant
Authors: FU, Ying1,2 hit_fuying@126.com, YU, Shui-li1 hitysl@163.com, YU, Yan-zhen2, QIU, Li-ping2, HUI, Ban3
Source: Journal of Environmental Sciences (Elsevier). Jun2007, Vol. 19 Issue 6, p678-688. 11p.
Subject Terms: Polymerization, Coagulants, Hydrogen ions, Ions
Abstract: Abstract: A kind of Fe-polysilicate polymer, poly-silicic-ferric (PSF) coagulant was prepared by co-polymerization (hydroxylation of mixture of Fe3+ and fresh polysilicic acid (PS)), in which PSF0.5, PSF1 or PSF3 denotes Si/Fe molar ratio of 0.5, 1 or 3, respectively. The effects of Si/Fe ratio and reaction time (co-polymerization time or aging time) on the reaction mode between Si and Fe were studies, and the optimal species of PSF was evaluated by pH change during the preparation of PSF and coagulation tests. The results showed that the characteristics of PSF are largely affected by both reaction time and Si/Fe ratio. PSF is found to be a essential complex of Si, Fe, and many other ions. The reaction mode between Si and Fe differs with various Si/Fe ratios. The pH of PSF0.5, PSF1 or PSF3 tended to be stable when reaction time is 10, 25 or 55 min, respectively, which is almost consistent with the time reaching the relative stable morphology that is just the optimal species of higher coagulation efficiency. The optimal reaction time reaching optimal species can be evaluated by measuring the pH change during the polymerization process. [Copyright &y& Elsevier]
Copyright of Journal of Environmental Sciences (Elsevier) is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Reaction mode between Si and Fe and evaluation of optimal species in poly-silicic-ferric coagulant
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  Data: <searchLink fieldCode="AR" term="%22FU%2C+Ying%22">FU, Ying</searchLink><relatesTo>1,2</relatesTo><i> hit_fuying@126.com</i><br /><searchLink fieldCode="AR" term="%22YU%2C+Shui-li%22">YU, Shui-li</searchLink><relatesTo>1</relatesTo><i> hitysl@163.com</i><br /><searchLink fieldCode="AR" term="%22YU%2C+Yan-zhen%22">YU, Yan-zhen</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22QIU%2C+Li-ping%22">QIU, Li-ping</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22HUI%2C+Ban%22">HUI, Ban</searchLink><relatesTo>3</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Environmental+Sciences+%28Elsevier%29%22">Journal of Environmental Sciences (Elsevier)</searchLink>. Jun2007, Vol. 19 Issue 6, p678-688. 11p.
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  Data: <searchLink fieldCode="DE" term="%22Polymerization%22">Polymerization</searchLink><br /><searchLink fieldCode="DE" term="%22Coagulants%22">Coagulants</searchLink><br /><searchLink fieldCode="DE" term="%22Hydrogen+ions%22">Hydrogen ions</searchLink><br /><searchLink fieldCode="DE" term="%22Ions%22">Ions</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Abstract: A kind of Fe-polysilicate polymer, poly-silicic-ferric (PSF) coagulant was prepared by co-polymerization (hydroxylation of mixture of Fe3+ and fresh polysilicic acid (PS)), in which PSF0.5, PSF1 or PSF3 denotes Si/Fe molar ratio of 0.5, 1 or 3, respectively. The effects of Si/Fe ratio and reaction time (co-polymerization time or aging time) on the reaction mode between Si and Fe were studies, and the optimal species of PSF was evaluated by pH change during the preparation of PSF and coagulation tests. The results showed that the characteristics of PSF are largely affected by both reaction time and Si/Fe ratio. PSF is found to be a essential complex of Si, Fe, and many other ions. The reaction mode between Si and Fe differs with various Si/Fe ratios. The pH of PSF0.5, PSF1 or PSF3 tended to be stable when reaction time is 10, 25 or 55 min, respectively, which is almost consistent with the time reaching the relative stable morphology that is just the optimal species of higher coagulation efficiency. The optimal reaction time reaching optimal species can be evaluated by measuring the pH change during the polymerization process. [Copyright &y& Elsevier]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of Environmental Sciences (Elsevier) is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1016/S1001-0742(07)60114-4
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      – Code: eng
        Text: English
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        Type: general
      – SubjectFull: Coagulants
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      – SubjectFull: Hydrogen ions
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      – SubjectFull: Ions
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              Text: Jun2007
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              Y: 2007
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