Plasmonic silver nanoparticles for improved organic solar cells

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Title: Plasmonic silver nanoparticles for improved organic solar cells
Authors: Kalfagiannis, N.1 nkalf@physics.auth.gr, Karagiannidis, P.G.1, Pitsalidis, C.1, Panagiotopoulos, N.T.2, Gravalidis, C.1, Kassavetis, S.1, Patsalas, P.3, Logothetidis, S.1
Source: Solar Energy Materials & Solar Cells. Sep2012, Vol. 104, p165-174. 10p.
Subject Terms: *Solar cells, *Energy consumption, Plasmons (Physics), Silver nanoparticles, Organic electronics, Comparative studies, Performance evaluation, Heterojunctions
Abstract: Absract: In the present work we compare the performance of organic solar cells, based on the bulk heterojunction system of P3HT:PCBM when adequate silver nanoparticles (NPs) are incorporated in two distinct places among the device structure. Introduction of NPs on top of the transparent anode revealed better overall performance with an increased efficiency of 17%. Alternatively, placing the NPs on top of the active photovoltaic layer resulted to 25% higher photo-current generation albeit with inferior electrical characteristics (i.e series and shunt resistance). Our findings suggest that enhanced scattering to non-specular directions from NPs site is maximized when penetrating light meets the particles after the polymer blend, but even this mechanism is not sufficient enough to explain the enhanced short circuit current observed. A second mechanism should be feasible; that is plasmon enhancement which is more efficient in the case where NPs are in direct contact with the polymer blend. J–V characteristics measured in the dark showed that NPs placed on top of the ITO film act as enhanced hole conducting sites, as evident by the lower series resistance values in these cells, suggesting this mechanism as more significant in this case. [ABSTRACT FROM AUTHOR]
Copyright of Solar Energy Materials & Solar Cells is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Plasmonic silver nanoparticles for improved organic solar cells
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  Data: <searchLink fieldCode="AR" term="%22Kalfagiannis%2C+N%2E%22">Kalfagiannis, N.</searchLink><relatesTo>1</relatesTo><i> nkalf@physics.auth.gr</i><br /><searchLink fieldCode="AR" term="%22Karagiannidis%2C+P%2EG%2E%22">Karagiannidis, P.G.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Pitsalidis%2C+C%2E%22">Pitsalidis, C.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Panagiotopoulos%2C+N%2ET%2E%22">Panagiotopoulos, N.T.</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Gravalidis%2C+C%2E%22">Gravalidis, C.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Kassavetis%2C+S%2E%22">Kassavetis, S.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Patsalas%2C+P%2E%22">Patsalas, P.</searchLink><relatesTo>3</relatesTo><br /><searchLink fieldCode="AR" term="%22Logothetidis%2C+S%2E%22">Logothetidis, S.</searchLink><relatesTo>1</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Solar+Energy+Materials+%26+Solar+Cells%22">Solar Energy Materials & Solar Cells</searchLink>. Sep2012, Vol. 104, p165-174. 10p.
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  Data: *<searchLink fieldCode="DE" term="%22Solar+cells%22">Solar cells</searchLink><br />*<searchLink fieldCode="DE" term="%22Energy+consumption%22">Energy consumption</searchLink><br /><searchLink fieldCode="DE" term="%22Plasmons+%28Physics%29%22">Plasmons (Physics)</searchLink><br /><searchLink fieldCode="DE" term="%22Silver+nanoparticles%22">Silver nanoparticles</searchLink><br /><searchLink fieldCode="DE" term="%22Organic+electronics%22">Organic electronics</searchLink><br /><searchLink fieldCode="DE" term="%22Comparative+studies%22">Comparative studies</searchLink><br /><searchLink fieldCode="DE" term="%22Performance+evaluation%22">Performance evaluation</searchLink><br /><searchLink fieldCode="DE" term="%22Heterojunctions%22">Heterojunctions</searchLink>
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  Data: Absract: In the present work we compare the performance of organic solar cells, based on the bulk heterojunction system of P3HT:PCBM when adequate silver nanoparticles (NPs) are incorporated in two distinct places among the device structure. Introduction of NPs on top of the transparent anode revealed better overall performance with an increased efficiency of 17%. Alternatively, placing the NPs on top of the active photovoltaic layer resulted to 25% higher photo-current generation albeit with inferior electrical characteristics (i.e series and shunt resistance). Our findings suggest that enhanced scattering to non-specular directions from NPs site is maximized when penetrating light meets the particles after the polymer blend, but even this mechanism is not sufficient enough to explain the enhanced short circuit current observed. A second mechanism should be feasible; that is plasmon enhancement which is more efficient in the case where NPs are in direct contact with the polymer blend. J–V characteristics measured in the dark showed that NPs placed on top of the ITO film act as enhanced hole conducting sites, as evident by the lower series resistance values in these cells, suggesting this mechanism as more significant in this case. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
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  Data: <i>Copyright of Solar Energy Materials & Solar Cells is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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      – Type: doi
        Value: 10.1016/j.solmat.2012.05.018
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      – Code: eng
        Text: English
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        PageCount: 10
        StartPage: 165
    Subjects:
      – SubjectFull: Solar cells
        Type: general
      – SubjectFull: Energy consumption
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      – SubjectFull: Plasmons (Physics)
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      – SubjectFull: Silver nanoparticles
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      – SubjectFull: Organic electronics
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      – SubjectFull: Comparative studies
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      – SubjectFull: Performance evaluation
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      – SubjectFull: Heterojunctions
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      – TitleFull: Plasmonic silver nanoparticles for improved organic solar cells
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              M: 09
              Text: Sep2012
              Type: published
              Y: 2012
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