Syntheses of novel 1,5‐benzodiazepine derivatives: Crystal structures, spectroscopic characterizations, Hirshfeld surface analyses, molecular docking studies, DFT calculations, corrosion inhibition anticipation, and antibacterial activities. - El Ghayati, Lhoussaine; Sert, Yusuf; Sebbar, Nada Kheira; Ramli, Youssef; Ahabchane, Noureddine Hamou; Talbaoui, Ahmed; Mague, Joel T.; El Ibrahimi, Brahim; Taha, Mohamed Labd; Essassi, El Mokhtar; Al‐Zaqri, Nabil; Alsalme, Ali (Journal of Heterocyclic Chemistry, 2021)