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Synthesis and evaluation of catalytic application of porous resin

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Title: Synthesis and evaluation of catalytic application of porous resin
Authors: Nabavinia, Mahboubeh
Committee Members: Noshadi, Iman; Savelski, Mariano; Hesketh, Robert
Summary: The abilities to tailor catalytic functional groups and chemical characteristics onto a robust polymer structure make mesoporous phenolic resins great candidates for catalytic support applications. The use of a template synthesis method for configuring a catalytic structure is neither commercially nor environmentally friendly. In this Ph.D. thesis, new one-pot template-free methods for synthesizing mesoporous metal-doped phenol-formaldehyderesin were developed. The methods facilitate scaling for industrial catalytic applications in pharmaceutical, environmental, and medical applications. Heterogeneous palladium centered catalytic mesoporous structures were synthesized by a single-stage template-free method. BET adsorption measurements, SEM, EDX, XPS, and TEM were used to study the surface area, uniformity of Pd distribution, and an interconnected porous network structure. Subsequently, the activity of the catalyst was evaluated in bed batch and continuous reactors for Suzuki-Miyaura cross-coupling reactions. The catalyst was confirmed for biocompatibility and used for extracellular synthesis of anti-cancer PP121 drug in the mono-cell layer and 3D printed model structures with encapsulated cells. The metabolic activity and flow cytometry results confirmed the efficiency of this catalyst for in-situ drug synthesis. Additionally, this catalyst was doped using cobalt and nickel and evaluated for CO2 capture and electrochemical conversion to fuels and chemicals.
URL: https://rdw.rowan.edu/etd/2803
Database: OpenDissertations
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Header DbId: ddu
DbLabel: OpenDissertations
An: ddu.oai.rdw.rowan.edu.etd.3805
AccessLevel: 6
PubType: Dissertation/ Thesis
PubTypeId: dissertation
PreciseRelevancyScore: 0
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Items – Name: Title
  Label: Title
  Group: Ti
  Data: Synthesis and evaluation of catalytic application of porous resin
– Name: Author
  Label: Authors
  Group: Au
  Data: <searchLink fieldCode="AR" term="%22Nabavinia%2C+Mahboubeh%22">Nabavinia, Mahboubeh</searchLink>
– Name: Author
  Label: Committee Members
  Group: Au
  Data: <searchLink fieldCode="CO" term="%22Noshadi%2C+Iman%22">Noshadi, Iman</searchLink>; <searchLink fieldCode="CO" term="%22Savelski%2C+Mariano%22">Savelski, Mariano</searchLink>; <searchLink fieldCode="CO" term="%22Hesketh%2C+Robert%22">Hesketh, Robert</searchLink>
– Name: Abstract
  Label: Summary
  Group: Ab
  Data: The abilities to tailor catalytic functional groups and chemical characteristics onto a robust polymer structure make mesoporous phenolic resins great candidates for catalytic support applications. The use of a template synthesis method for configuring a catalytic structure is neither commercially nor environmentally friendly. In this Ph.D. thesis, new one-pot template-free methods for synthesizing mesoporous metal-doped phenol-formaldehyderesin were developed. The methods facilitate scaling for industrial catalytic applications in pharmaceutical, environmental, and medical applications. Heterogeneous palladium centered catalytic mesoporous structures were synthesized by a single-stage template-free method. BET adsorption measurements, SEM, EDX, XPS, and TEM were used to study the surface area, uniformity of Pd distribution, and an interconnected porous network structure. Subsequently, the activity of the catalyst was evaluated in bed batch and continuous reactors for Suzuki-Miyaura cross-coupling reactions. The catalyst was confirmed for biocompatibility and used for extracellular synthesis of anti-cancer PP121 drug in the mono-cell layer and 3D printed model structures with encapsulated cells. The metabolic activity and flow cytometry results confirmed the efficiency of this catalyst for in-situ drug synthesis. Additionally, this catalyst was doped using cobalt and nickel and evaluated for CO2 capture and electrochemical conversion to fuels and chemicals.
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  Data: <link linkTarget="URL" linkTerm="https://rdw.rowan.edu/etd/2803" linkWindow="_blank">https://rdw.rowan.edu/etd/2803</link>
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RecordInfo BibRecord:
  BibEntity:
    Languages:
      – Code: eng
        Text: English
    Subjects:
      – SubjectFull: Carbon dioxide capture
        Type: general
      – SubjectFull: Catalyst
        Type: general
      – SubjectFull: Electrochemical conversion
        Type: general
      – SubjectFull: In-situ drug synthesis
        Type: general
      – SubjectFull: Resin
        Type: general
      – SubjectFull: Template-free
        Type: general
      – SubjectFull: Phenolic resins; Mesoporous materials--Synthesis; Catalyst supports
        Type: general
      – SubjectFull: Chemical Engineering
        Type: general
    Titles:
      – TitleFull: Synthesis and evaluation of catalytic application of porous resin
        Type: main
  BibRelationships:
    HasContributorRelationships:
      – PersonEntity:
          Name:
            NameFull: Nabavinia, Mahboubeh
    IsPartOfRelationships:
      – BibEntity:
          Dates:
            – D: 04
              M: 06
              Type: published
              Y: 2020
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