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Determination of Redox Reaction Rates and Orders by In Situ Liquid Cell Electron Microscopy of Pd and Au Solution Growth.

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Title: Determination of Redox Reaction Rates and Orders by In Situ Liquid Cell Electron Microscopy of Pd and Au Solution Growth.
Authors: Sutter, Eli A.1 esutter@bnl.gov, Sutter, Peter W.1
Source: Journal of the American Chemical Society. 12/3/2014, Vol. 136 Issue 48, p16865-16870. 6p.
Subjects: Oxidation-reduction reaction, Scanning transmission electron microscopy, Nanoparticles, Lead compounds, Electron beam research
Abstract: In-situ liquid cell transmission and scanning transmission electron microscopy (TEM/STEM) experiments are important, as they provide direct insight into processes in liquids, such as solution growth of nanoparticles, among others. In liquid cell TEM/STEM redox reaction experiments, the hydrated electrons e-aq created by the electron beam are responsible for the reduction of metal-ion complexes. Here we investigate the rate equation of redox reactions involving reduction by e-aq generated by the electron beam during in situ liquid TEM/STEM. Specifically we consider the growth of Pd on Au seeds in aqueous solutions containing Pd-chloro complexes. From the quantification of the rate of Pd deposition at different electron beam currents and as a function of distance from a stationary, nanometer-sized exciting beam, we determine that the reaction is first order with respect to the concentration of hydrated electrons, [e-aq]. By comparing Pd- and Au-deposition, we further demonstrate that measurements of the local deposition rate on nanoparticles in the solution via real-time imaging can be used to measure not only [e-aq] but also the rate of reduction of a metal-ion complex to zerovalent metal atoms in solution. [ABSTRACT FROM AUTHOR]
Copyright of Journal of the American Chemical Society is the property of American Chemical Society and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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DbLabel: Engineering Source
An: 100042977
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PubTypeId: academicJournal
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  Label: Title
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  Data: Determination of Redox Reaction Rates and Orders by In Situ Liquid Cell Electron Microscopy of Pd and Au Solution Growth.
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  Data: <searchLink fieldCode="AR" term="%22Sutter%2C+Eli+A%2E%22">Sutter, Eli A.</searchLink><relatesTo>1</relatesTo><i> esutter@bnl.gov</i><br /><searchLink fieldCode="AR" term="%22Sutter%2C+Peter+W%2E%22">Sutter, Peter W.</searchLink><relatesTo>1</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+the+American+Chemical+Society%22">Journal of the American Chemical Society</searchLink>. 12/3/2014, Vol. 136 Issue 48, p16865-16870. 6p.
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  Data: <searchLink fieldCode="DE" term="%22Oxidation-reduction+reaction%22">Oxidation-reduction reaction</searchLink><br /><searchLink fieldCode="DE" term="%22Scanning+transmission+electron+microscopy%22">Scanning transmission electron microscopy</searchLink><br /><searchLink fieldCode="DE" term="%22Nanoparticles%22">Nanoparticles</searchLink><br /><searchLink fieldCode="DE" term="%22Lead+compounds%22">Lead compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Electron+beam+research%22">Electron beam research</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: In-situ liquid cell transmission and scanning transmission electron microscopy (TEM/STEM) experiments are important, as they provide direct insight into processes in liquids, such as solution growth of nanoparticles, among others. In liquid cell TEM/STEM redox reaction experiments, the hydrated electrons e-aq created by the electron beam are responsible for the reduction of metal-ion complexes. Here we investigate the rate equation of redox reactions involving reduction by e-aq generated by the electron beam during in situ liquid TEM/STEM. Specifically we consider the growth of Pd on Au seeds in aqueous solutions containing Pd-chloro complexes. From the quantification of the rate of Pd deposition at different electron beam currents and as a function of distance from a stationary, nanometer-sized exciting beam, we determine that the reaction is first order with respect to the concentration of hydrated electrons, [e-aq]. By comparing Pd- and Au-deposition, we further demonstrate that measurements of the local deposition rate on nanoparticles in the solution via real-time imaging can be used to measure not only [e-aq] but also the rate of reduction of a metal-ion complex to zerovalent metal atoms in solution. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of the American Chemical Society is the property of American Chemical Society and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1021/ja508279v
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      – Code: eng
        Text: English
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        PageCount: 6
        StartPage: 16865
    Subjects:
      – SubjectFull: Oxidation-reduction reaction
        Type: general
      – SubjectFull: Scanning transmission electron microscopy
        Type: general
      – SubjectFull: Nanoparticles
        Type: general
      – SubjectFull: Lead compounds
        Type: general
      – SubjectFull: Electron beam research
        Type: general
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      – TitleFull: Determination of Redox Reaction Rates and Orders by In Situ Liquid Cell Electron Microscopy of Pd and Au Solution Growth.
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              M: 12
              Text: 12/3/2014
              Type: published
              Y: 2014
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