Passive sampling of airborne furan indoors by solid-phase microextraction.

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Title: Passive sampling of airborne furan indoors by solid-phase microextraction.
Authors: Lin, Li-Ting1, Tsai, Alicia Lishin2, Tseng, Yves Max2, Tsai, Shih-Wei1
Source: International Journal of Environmental Analytical Chemistry. Jan2015, Vol. 95 Issue 1, p45-56. 12p.
Subjects: Furans, Passive sampling devices (Environmental sampling), Solid phase extraction, Indoor air pollution, Diffusion, Thermal desorption
Abstract: Furan may be formed in food under heat treatment and is highly suspected to appear in indoor air. The possible exposure to indoor furan raises concerns because it has been found to cause carcinogenicity and cytotoxicity in animals. To determine airborne furan, solid-phase microextraction (SPME) technique was utilised as a diffusive sampler. The Carboxen/Polydimethylsiloxane (CAR/PDMS, 75 μm) fibre was used, and the SPME fibre assembly was inserted into a polytetrafluoroethene tubing. Furan of known concentrations was generated in Tedlar gas bags for the evaluation of SPME diffusive samplers. After sampling, the sampler was inserted into the injection port of a gas chromatograph coupled with a mass spectrometer (GC/MS) for thermal desorption and analysis. Validation of the SPME device with active sampling by charcoal tube was performed side by side as well. The charcoal tube was desorbed by acetone before analysis with GC/MS. The experimental sampling constant of the sampler was found equal to (9.93 ± 1.28) × 10−3(cm3 min−1) at 25°C. Furthermore, side-by-side validations between SPME device and charcoal tube showed linear relationship withr = 0.9927. The designed passive sampling device for furan has the advantages of both passive sampling and SPME technique and looks suitable for assessing indoor air quality. [ABSTRACT FROM AUTHOR]
Copyright of International Journal of Environmental Analytical Chemistry is the property of Taylor & Francis Ltd and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Passive sampling of airborne furan indoors by solid-phase microextraction.
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  Data: <searchLink fieldCode="AR" term="%22Lin%2C+Li-Ting%22">Lin, Li-Ting</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Tsai%2C+Alicia+Lishin%22">Tsai, Alicia Lishin</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Tseng%2C+Yves+Max%22">Tseng, Yves Max</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Tsai%2C+Shih-Wei%22">Tsai, Shih-Wei</searchLink><relatesTo>1</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22International+Journal+of+Environmental+Analytical+Chemistry%22">International Journal of Environmental Analytical Chemistry</searchLink>. Jan2015, Vol. 95 Issue 1, p45-56. 12p.
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  Data: <searchLink fieldCode="DE" term="%22Furans%22">Furans</searchLink><br /><searchLink fieldCode="DE" term="%22Passive+sampling+devices+%28Environmental+sampling%29%22">Passive sampling devices (Environmental sampling)</searchLink><br /><searchLink fieldCode="DE" term="%22Solid+phase+extraction%22">Solid phase extraction</searchLink><br /><searchLink fieldCode="DE" term="%22Indoor+air+pollution%22">Indoor air pollution</searchLink><br /><searchLink fieldCode="DE" term="%22Diffusion%22">Diffusion</searchLink><br /><searchLink fieldCode="DE" term="%22Thermal+desorption%22">Thermal desorption</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Furan may be formed in food under heat treatment and is highly suspected to appear in indoor air. The possible exposure to indoor furan raises concerns because it has been found to cause carcinogenicity and cytotoxicity in animals. To determine airborne furan, solid-phase microextraction (SPME) technique was utilised as a diffusive sampler. The Carboxen/Polydimethylsiloxane (CAR/PDMS, 75 μm) fibre was used, and the SPME fibre assembly was inserted into a polytetrafluoroethene tubing. Furan of known concentrations was generated in Tedlar gas bags for the evaluation of SPME diffusive samplers. After sampling, the sampler was inserted into the injection port of a gas chromatograph coupled with a mass spectrometer (GC/MS) for thermal desorption and analysis. Validation of the SPME device with active sampling by charcoal tube was performed side by side as well. The charcoal tube was desorbed by acetone before analysis with GC/MS. The experimental sampling constant of the sampler was found equal to (9.93 ± 1.28) × 10−3(cm3 min−1) at 25°C. Furthermore, side-by-side validations between SPME device and charcoal tube showed linear relationship withr = 0.9927. The designed passive sampling device for furan has the advantages of both passive sampling and SPME technique and looks suitable for assessing indoor air quality. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of International Journal of Environmental Analytical Chemistry is the property of Taylor & Francis Ltd and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1080/03067319.2014.983438
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      – Code: eng
        Text: English
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        PageCount: 12
        StartPage: 45
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      – SubjectFull: Furans
        Type: general
      – SubjectFull: Passive sampling devices (Environmental sampling)
        Type: general
      – SubjectFull: Solid phase extraction
        Type: general
      – SubjectFull: Indoor air pollution
        Type: general
      – SubjectFull: Diffusion
        Type: general
      – SubjectFull: Thermal desorption
        Type: general
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      – TitleFull: Passive sampling of airborne furan indoors by solid-phase microextraction.
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            NameFull: Lin, Li-Ting
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            NameFull: Tsai, Alicia Lishin
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            NameFull: Tseng, Yves Max
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            NameFull: Tsai, Shih-Wei
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            – D: 01
              M: 01
              Text: Jan2015
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              Y: 2015
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