Activated carbon fibers for efficient VOC removal from diluted streams: the role of surface functionalities.

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Title: Activated carbon fibers for efficient VOC removal from diluted streams: the role of surface functionalities.
Authors: Baur, Guillaume1, Beswick, Oliver1, Spring, Jonathan1, Yuranov, Igor1, Kiwi-Minsker, Lioubov1 lioubov.kiwi-minsker@epfl.ch
Source: Adsorption. May2015, Vol. 21 Issue 4, p255-264. 10p.
Abstract: The effect of surface functionalities, specific surface area and pore size of activated carbon fibers (ACFs) on the adsorption of toluene and acetaldehyde, two volatile organic compounds (VOC), at low concentrations (~80 ppmv) and short contact time (20 ms) has been studied. Two different types of ACFs characterized by low temperature N adsorption: ultramicroporous ( d < 1 nm) and supermicroporous ( d ~ 1-2 nm) were tested. Both ACFs were effective for the removal of toluene attaining the adsorption capacity as large as 51 wt%. The surface chemistry of ACFs (O-containing functional groups) was characterized by temperature-programmed desorption monitoring the CO/CO evolved. Oxidative treatment of ACFs by nitric acid increased the surface concentration of O-groups. This resulted in lower adsorption capacity towards toluene but higher one towards acetaldehyde. This result was rationalized based on different type of VOC interactions with the carbon surface. [ABSTRACT FROM AUTHOR]
Copyright of Adsorption is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: &lt;searchLink fieldCode=&quot;JN&quot; term=&quot;%22Adsorption%22&quot;&gt;Adsorption&lt;/searchLink&gt;. May2015, Vol. 21 Issue 4, p255-264. 10p.
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  Data: The effect of surface functionalities, specific surface area and pore size of activated carbon fibers (ACFs) on the adsorption of toluene and acetaldehyde, two volatile organic compounds (VOC), at low concentrations (~80 ppmv) and short contact time (20 ms) has been studied. Two different types of ACFs characterized by low temperature N adsorption: ultramicroporous ( d &lt; 1 nm) and supermicroporous ( d ~ 1-2 nm) were tested. Both ACFs were effective for the removal of toluene attaining the adsorption capacity as large as 51 wt%. The surface chemistry of ACFs (O-containing functional groups) was characterized by temperature-programmed desorption monitoring the CO/CO evolved. Oxidative treatment of ACFs by nitric acid increased the surface concentration of O-groups. This resulted in lower adsorption capacity towards toluene but higher one towards acetaldehyde. This result was rationalized based on different type of VOC interactions with the carbon surface. [ABSTRACT FROM AUTHOR]
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  Data: &lt;i&gt;Copyright of Adsorption is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder&#39;s express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.&lt;/i&gt; (Copyright applies to all Abstracts.)
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              Text: May2015
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