Synthesis and structural characterization of Ba14Pd3Ir8O33

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Title: Synthesis and structural characterization of Ba14Pd3Ir8O33
Authors: Burley, Jonathan C.1, Battle, Peter D.1 peter.battle@chem.ox.ac.uk, Jordan, Nicola A.1, Sloan, Jeremy1, Weill, François2
Source: Journal of Solid State Chemistry. Aug2003, Vol. 174 Issue 1, p96. 8p.
Subjects: Polycrystals, X-ray diffraction, Electron diffraction
Abstract: Ba14Pd3Ir8O33 has been prepared in polycrystalline form and characterized by X-ray, neutron and electron diffraction, lattice imaging and magnetometry. The structure can be described as the n=5,m=9 member of the (A3O9)n(A3A′O6)m series which derives from the n=∞, m=0 2H perovskite structure. Ir and Pd cations occupy chains of octahedral and trigonal-prismatic sites in a disordered manner. An alternative description of the structure in (3+1)-dimensional superspace is also presented. No magnetic phase transitions were observed above 5 K. [Copyright &y& Elsevier]
Copyright of Journal of Solid State Chemistry is the property of Academic Press Inc. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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An: 10318771
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  Data: Synthesis and structural characterization of Ba<subscript>14</subscript>Pd<subscript>3</subscript>Ir<subscript>8</subscript>O<subscript>33</subscript>
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  Data: <searchLink fieldCode="AR" term="%22Burley%2C+Jonathan+C%2E%22">Burley, Jonathan C.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Battle%2C+Peter+D%2E%22">Battle, Peter D.</searchLink><relatesTo>1</relatesTo><i> peter.battle@chem.ox.ac.uk</i><br /><searchLink fieldCode="AR" term="%22Jordan%2C+Nicola+A%2E%22">Jordan, Nicola A.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Sloan%2C+Jeremy%22">Sloan, Jeremy</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Weill%2C+François%22">Weill, François</searchLink><relatesTo>2</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Solid+State+Chemistry%22">Journal of Solid State Chemistry</searchLink>. Aug2003, Vol. 174 Issue 1, p96. 8p.
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  Data: <searchLink fieldCode="DE" term="%22Polycrystals%22">Polycrystals</searchLink><br /><searchLink fieldCode="DE" term="%22X-ray+diffraction%22">X-ray diffraction</searchLink><br /><searchLink fieldCode="DE" term="%22Electron+diffraction%22">Electron diffraction</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Ba14Pd3Ir8O33 has been prepared in polycrystalline form and characterized by X-ray, neutron and electron diffraction, lattice imaging and magnetometry. The structure can be described as the <f>n=5,m=9</f> member of the (A3O9)n(A3A′O6)m series which derives from the <f>n=∞</f>, <f>m=0</f> <f>2H</f> perovskite structure. Ir and Pd cations occupy chains of octahedral and trigonal-prismatic sites in a disordered manner. An alternative description of the structure in (3+1)-dimensional superspace is also presented. No magnetic phase transitions were observed above 5 K. [Copyright &y& Elsevier]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of Solid State Chemistry is the property of Academic Press Inc. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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      – Type: doi
        Value: 10.1016/S0022-4596(03)00182-8
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      – Code: eng
        Text: English
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        Type: general
      – SubjectFull: X-ray diffraction
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      – SubjectFull: Electron diffraction
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      – TitleFull: Synthesis and structural characterization of Ba14Pd3Ir8O33
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            NameFull: Jordan, Nicola A.
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            NameFull: Sloan, Jeremy
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            – D: 01
              M: 08
              Text: Aug2003
              Type: published
              Y: 2003
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