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A Synthesis of Cyanolide A by Intramolecular Oxa-Michael Addition.

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Title: A Synthesis of Cyanolide A by Intramolecular Oxa-Michael Addition.
Authors: Bates, Roderick W.1 roderick@ntu.edu.sg, Tee Guan Lek1
Source: Synthesis. 2014, Vol. 46 Issue 13, p1731-1738. 8p.
Subjects: Macrolide antibiotics synthesis, Michael reaction, Glycosylation, Stereoselective reactions, Barbier reactions, Metathesis reactions, Carbonylation, Grignard reagents
Abstract: A synthesis of cyanolide A, a diolide natural product, has been achieved using a diastereoselective Barbier reaction, earlystage glycosylation, and intramolecular oxa-Michael addition to form the THP ring. [ABSTRACT FROM AUTHOR]
Copyright of Synthesis is the property of Georg Thieme Verlag Stuttgart and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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Header DbId: egs
DbLabel: Engineering Source
An: 103526196
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
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  Data: A Synthesis of Cyanolide A by Intramolecular Oxa-Michael Addition.
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  Data: <searchLink fieldCode="AR" term="%22Bates%2C+Roderick+W%2E%22">Bates, Roderick W.</searchLink><relatesTo>1</relatesTo><i> roderick@ntu.edu.sg</i><br /><searchLink fieldCode="AR" term="%22Tee+Guan+Lek%22">Tee Guan Lek</searchLink><relatesTo>1</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Synthesis%22">Synthesis</searchLink>. 2014, Vol. 46 Issue 13, p1731-1738. 8p.
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  Data: <searchLink fieldCode="DE" term="%22Macrolide+antibiotics+synthesis%22">Macrolide antibiotics synthesis</searchLink><br /><searchLink fieldCode="DE" term="%22Michael+reaction%22">Michael reaction</searchLink><br /><searchLink fieldCode="DE" term="%22Glycosylation%22">Glycosylation</searchLink><br /><searchLink fieldCode="DE" term="%22Stereoselective+reactions%22">Stereoselective reactions</searchLink><br /><searchLink fieldCode="DE" term="%22Barbier+reactions%22">Barbier reactions</searchLink><br /><searchLink fieldCode="DE" term="%22Metathesis+reactions%22">Metathesis reactions</searchLink><br /><searchLink fieldCode="DE" term="%22Carbonylation%22">Carbonylation</searchLink><br /><searchLink fieldCode="DE" term="%22Grignard+reagents%22">Grignard reagents</searchLink>
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  Label: Abstract
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  Data: A synthesis of cyanolide A, a diolide natural product, has been achieved using a diastereoselective Barbier reaction, earlystage glycosylation, and intramolecular oxa-Michael addition to form the THP ring. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
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  Data: <i>Copyright of Synthesis is the property of Georg Thieme Verlag Stuttgart and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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    Identifiers:
      – Type: doi
        Value: 10.1055/s-0033-1341153
    Languages:
      – Code: eng
        Text: English
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      Pagination:
        PageCount: 8
        StartPage: 1731
    Subjects:
      – SubjectFull: Macrolide antibiotics synthesis
        Type: general
      – SubjectFull: Michael reaction
        Type: general
      – SubjectFull: Glycosylation
        Type: general
      – SubjectFull: Stereoselective reactions
        Type: general
      – SubjectFull: Barbier reactions
        Type: general
      – SubjectFull: Metathesis reactions
        Type: general
      – SubjectFull: Carbonylation
        Type: general
      – SubjectFull: Grignard reagents
        Type: general
    Titles:
      – TitleFull: A Synthesis of Cyanolide A by Intramolecular Oxa-Michael Addition.
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            NameFull: Bates, Roderick W.
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            NameFull: Tee Guan Lek
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              Text: 2014
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              Y: 2014
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              Value: 46
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              Value: 13
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            – TitleFull: Synthesis
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