Application of plasma deposited organosilicon thin films for the corrosion protection of metals

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Title: Application of plasma deposited organosilicon thin films for the corrosion protection of metals
Authors: Fracassi, F.1 fracassi@chimica.uniba.it, d'Agostino, R.1, Palumbo, F.1, Angelini, E.2, Grassini, S.2, Rosalbino, F.2
Source: Surface & Coatings Technology. Sep/Oct2003, Vol. 174-175, p107. 5p.
Subjects: Chemical vapor deposition, Silicon, Organic compounds, Thin films
Abstract: In this contribution it will be shown that plasma enhanced chemical vapor deposition (PECVD) of silicon containing organic compounds is a promising approach for the corrosion protection of metals (steel and magnesium alloys). When the deposition process is preceded by a suitable plasma treatment, which depends on the particular metal under study, a marked increase of the protective properties measured with electrochemical impedance spectroscopy (EIS) is detected. The highest impedance modulus obtained for Mg is 450 KΩ·cm2, 8000 times higher than for the bare metal. Highly protective coatings are obtained for inorganic films, free of sylanols. A marked decrease of the impedance modulus of coated substrates has been registered after immersion in electrolyte solution due to the presence of pinholes which represents defect points where localized corrosion starts. [Copyright &y& Elsevier]
Copyright of Surface & Coatings Technology is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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An: 10575649
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  Data: Application of plasma deposited organosilicon thin films for the corrosion protection of metals
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  Data: <searchLink fieldCode="AR" term="%22Fracassi%2C+F%2E%22">Fracassi, F.</searchLink><relatesTo>1</relatesTo><i> fracassi@chimica.uniba.it</i><br /><searchLink fieldCode="AR" term="%22d'Agostino%2C+R%2E%22">d'Agostino, R.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Palumbo%2C+F%2E%22">Palumbo, F.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Angelini%2C+E%2E%22">Angelini, E.</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Grassini%2C+S%2E%22">Grassini, S.</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Rosalbino%2C+F%2E%22">Rosalbino, F.</searchLink><relatesTo>2</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Surface+%26+Coatings+Technology%22">Surface & Coatings Technology</searchLink>. Sep/Oct2003, Vol. 174-175, p107. 5p.
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  Data: <searchLink fieldCode="DE" term="%22Chemical+vapor+deposition%22">Chemical vapor deposition</searchLink><br /><searchLink fieldCode="DE" term="%22Silicon%22">Silicon</searchLink><br /><searchLink fieldCode="DE" term="%22Organic+compounds%22">Organic compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Thin+films%22">Thin films</searchLink>
– Name: Abstract
  Label: Abstract
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  Data: In this contribution it will be shown that plasma enhanced chemical vapor deposition (PECVD) of silicon containing organic compounds is a promising approach for the corrosion protection of metals (steel and magnesium alloys). When the deposition process is preceded by a suitable plasma treatment, which depends on the particular metal under study, a marked increase of the protective properties measured with electrochemical impedance spectroscopy (EIS) is detected. The highest impedance modulus obtained for Mg is 450 KΩ·cm2, 8000 times higher than for the bare metal. Highly protective coatings are obtained for inorganic films, free of sylanols. A marked decrease of the impedance modulus of coated substrates has been registered after immersion in electrolyte solution due to the presence of pinholes which represents defect points where localized corrosion starts. [Copyright &y& Elsevier]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Surface & Coatings Technology is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1016/S0257-8972(03)00422-5
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      – Code: eng
        Text: English
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        PageCount: 5
        StartPage: 107
    Subjects:
      – SubjectFull: Chemical vapor deposition
        Type: general
      – SubjectFull: Silicon
        Type: general
      – SubjectFull: Organic compounds
        Type: general
      – SubjectFull: Thin films
        Type: general
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      – TitleFull: Application of plasma deposited organosilicon thin films for the corrosion protection of metals
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            NameFull: Fracassi, F.
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            NameFull: Palumbo, F.
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            NameFull: Angelini, E.
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            NameFull: Grassini, S.
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            NameFull: Rosalbino, F.
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            – D: 01
              M: 09
              Text: Sep/Oct2003
              Type: published
              Y: 2003
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              Value: 02578972
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              Value: 174-175
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            – TitleFull: Surface & Coatings Technology
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