Bibliographic Details
| Title: |
Post-synthetic modification of zinc metal-organic frameworks through palladium-catalysed carbon–carbon bond formation. |
| Authors: |
Burrows, Andrew D.1 a.d.burrows@bath.ac.uk, Fisher, Laura C.1,2, Mays, Timothy J.2, Rigby, Sean P.3, Ashbrook, Sharon E.4, Dawson, Daniel M.4 |
| Source: |
Journal of Organometallic Chemistry. Sep2015, Vol. 792, p134-138. 5p. |
| Subjects: |
Zinc compounds, Metal-organic frameworks, Organic synthesis, Palladium catalysts, Carbon-carbon bonds, Bond formation mechanism |
| Abstract: |
Post-synthetic Suzuki coupling reactions have been undertaken on the halide-functionalised metal-organic frameworks (MOFs) [Zn 4 O(bdc-Br) 3 ] (bdc-Br = 2-bromo-1,4-benzenedicarboxylate, IRMOF-2) and [Zn 4 O(bdc-I) 3 ] (bdc-I = 2-iodo-1,4-benzenedicarboxylate). Although the bulky catalyst employed leads to relatively low conversions, the use of core–shell MOFs demonstrates that the reactions are not confined to the crystal surfaces. [ABSTRACT FROM AUTHOR] |
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| Database: |
Engineering Source |
