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Post-synthetic modification of zinc metal-organic frameworks through palladium-catalysed carbon–carbon bond formation.

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Title: Post-synthetic modification of zinc metal-organic frameworks through palladium-catalysed carbon–carbon bond formation.
Authors: Burrows, Andrew D.1 a.d.burrows@bath.ac.uk, Fisher, Laura C.1,2, Mays, Timothy J.2, Rigby, Sean P.3, Ashbrook, Sharon E.4, Dawson, Daniel M.4
Source: Journal of Organometallic Chemistry. Sep2015, Vol. 792, p134-138. 5p.
Subjects: Zinc compounds, Metal-organic frameworks, Organic synthesis, Palladium catalysts, Carbon-carbon bonds, Bond formation mechanism
Abstract: Post-synthetic Suzuki coupling reactions have been undertaken on the halide-functionalised metal-organic frameworks (MOFs) [Zn 4 O(bdc-Br) 3 ] (bdc-Br = 2-bromo-1,4-benzenedicarboxylate, IRMOF-2) and [Zn 4 O(bdc-I) 3 ] (bdc-I = 2-iodo-1,4-benzenedicarboxylate). Although the bulky catalyst employed leads to relatively low conversions, the use of core–shell MOFs demonstrates that the reactions are not confined to the crystal surfaces. [ABSTRACT FROM AUTHOR]
Copyright of Journal of Organometallic Chemistry is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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DbLabel: Engineering Source
An: 108785857
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  Data: Post-synthetic modification of zinc metal-organic frameworks through palladium-catalysed carbon–carbon bond formation.
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Organometallic+Chemistry%22">Journal of Organometallic Chemistry</searchLink>. Sep2015, Vol. 792, p134-138. 5p.
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  Data: <searchLink fieldCode="DE" term="%22Zinc+compounds%22">Zinc compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Metal-organic+frameworks%22">Metal-organic frameworks</searchLink><br /><searchLink fieldCode="DE" term="%22Organic+synthesis%22">Organic synthesis</searchLink><br /><searchLink fieldCode="DE" term="%22Palladium+catalysts%22">Palladium catalysts</searchLink><br /><searchLink fieldCode="DE" term="%22Carbon-carbon+bonds%22">Carbon-carbon bonds</searchLink><br /><searchLink fieldCode="DE" term="%22Bond+formation+mechanism%22">Bond formation mechanism</searchLink>
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  Data: Post-synthetic Suzuki coupling reactions have been undertaken on the halide-functionalised metal-organic frameworks (MOFs) [Zn 4 O(bdc-Br) 3 ] (bdc-Br = 2-bromo-1,4-benzenedicarboxylate, IRMOF-2) and [Zn 4 O(bdc-I) 3 ] (bdc-I = 2-iodo-1,4-benzenedicarboxylate). Although the bulky catalyst employed leads to relatively low conversions, the use of core–shell MOFs demonstrates that the reactions are not confined to the crystal surfaces. [ABSTRACT FROM AUTHOR]
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  Data: <i>Copyright of Journal of Organometallic Chemistry is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1016/j.jorganchem.2015.03.031
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        Text: English
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      – SubjectFull: Zinc compounds
        Type: general
      – SubjectFull: Metal-organic frameworks
        Type: general
      – SubjectFull: Organic synthesis
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      – SubjectFull: Palladium catalysts
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              Text: Sep2015
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