Preparing cationic cotton linter cellulose with high substitution degree by ultrasonic treatment.

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Title: Preparing cationic cotton linter cellulose with high substitution degree by ultrasonic treatment.
Authors: Zhang, Fulong1 zfl363@126.com, Pang, Zhiqiang1 zhiqiang8508@126.com, Dong, Cuihua1 xiaodong771111@163.com, Liu, Zong2 zliu73@wisc.edu
Source: Carbohydrate Polymers. Nov2015, Vol. 132, p214-220. 7p.
Subjects: Cation analysis, Linters, Substitution reactions, Cellulose, Chemical derivatives, Ultrasonics, Hydrogen bonding
Abstract: As an important cellulose derivative, cationic cellulose has becoming an attractive material. However, it remains challenging to produce cationic cellulose with high substitute degree. In this paper, we successfully increased the substitute degree of cationic cellulose by introducing ultrasonic treatment, which efficiently breaks hydrogen bonds of the chemical structure of cationic cellulose. Properties of cationic cellulose were studied by scanning electron spectroscope (SEM), contact angle, X-ray diffraction (XRD) and thermogravimetric analysis (TGA). Experimental results show that the cationic cellulose has rougher surface and lower crystallinity degree as compared to the original sample. TGA analysis verifies that the thermostability of CLC decreases after the cationic modification. The residual of the cationic cellulose (25 wt%) after pyrolysis increases significantly as compared to that of the original cellulose (15 wt%). [ABSTRACT FROM AUTHOR]
Copyright of Carbohydrate Polymers is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Preparing cationic cotton linter cellulose with high substitution degree by ultrasonic treatment.
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  Data: <searchLink fieldCode="AR" term="%22Zhang%2C+Fulong%22">Zhang, Fulong</searchLink><relatesTo>1</relatesTo><i> zfl363@126.com</i><br /><searchLink fieldCode="AR" term="%22Pang%2C+Zhiqiang%22">Pang, Zhiqiang</searchLink><relatesTo>1</relatesTo><i> zhiqiang8508@126.com</i><br /><searchLink fieldCode="AR" term="%22Dong%2C+Cuihua%22">Dong, Cuihua</searchLink><relatesTo>1</relatesTo><i> xiaodong771111@163.com</i><br /><searchLink fieldCode="AR" term="%22Liu%2C+Zong%22">Liu, Zong</searchLink><relatesTo>2</relatesTo><i> zliu73@wisc.edu</i>
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  Data: <searchLink fieldCode="JN" term="%22Carbohydrate+Polymers%22">Carbohydrate Polymers</searchLink>. Nov2015, Vol. 132, p214-220. 7p.
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  Data: <searchLink fieldCode="DE" term="%22Cation+analysis%22">Cation analysis</searchLink><br /><searchLink fieldCode="DE" term="%22Linters%22">Linters</searchLink><br /><searchLink fieldCode="DE" term="%22Substitution+reactions%22">Substitution reactions</searchLink><br /><searchLink fieldCode="DE" term="%22Cellulose%22">Cellulose</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+derivatives%22">Chemical derivatives</searchLink><br /><searchLink fieldCode="DE" term="%22Ultrasonics%22">Ultrasonics</searchLink><br /><searchLink fieldCode="DE" term="%22Hydrogen+bonding%22">Hydrogen bonding</searchLink>
– Name: Abstract
  Label: Abstract
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  Data: As an important cellulose derivative, cationic cellulose has becoming an attractive material. However, it remains challenging to produce cationic cellulose with high substitute degree. In this paper, we successfully increased the substitute degree of cationic cellulose by introducing ultrasonic treatment, which efficiently breaks hydrogen bonds of the chemical structure of cationic cellulose. Properties of cationic cellulose were studied by scanning electron spectroscope (SEM), contact angle, X-ray diffraction (XRD) and thermogravimetric analysis (TGA). Experimental results show that the cationic cellulose has rougher surface and lower crystallinity degree as compared to the original sample. TGA analysis verifies that the thermostability of CLC decreases after the cationic modification. The residual of the cationic cellulose (25 wt%) after pyrolysis increases significantly as compared to that of the original cellulose (15 wt%). [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Carbohydrate Polymers is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1016/j.carbpol.2015.06.055
    Languages:
      – Code: eng
        Text: English
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      Pagination:
        PageCount: 7
        StartPage: 214
    Subjects:
      – SubjectFull: Cation analysis
        Type: general
      – SubjectFull: Linters
        Type: general
      – SubjectFull: Substitution reactions
        Type: general
      – SubjectFull: Cellulose
        Type: general
      – SubjectFull: Chemical derivatives
        Type: general
      – SubjectFull: Ultrasonics
        Type: general
      – SubjectFull: Hydrogen bonding
        Type: general
    Titles:
      – TitleFull: Preparing cationic cotton linter cellulose with high substitution degree by ultrasonic treatment.
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            NameFull: Zhang, Fulong
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            NameFull: Pang, Zhiqiang
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            NameFull: Dong, Cuihua
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            NameFull: Liu, Zong
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          Dates:
            – D: 05
              M: 11
              Text: Nov2015
              Type: published
              Y: 2015
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              Value: 01448617
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              Value: 132
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            – TitleFull: Carbohydrate Polymers
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