Preparing cationic cotton linter cellulose with high substitution degree by ultrasonic treatment.
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| Title: | Preparing cationic cotton linter cellulose with high substitution degree by ultrasonic treatment. |
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| Authors: | Zhang, Fulong1 zfl363@126.com, Pang, Zhiqiang1 zhiqiang8508@126.com, Dong, Cuihua1 xiaodong771111@163.com, Liu, Zong2 zliu73@wisc.edu |
| Source: | Carbohydrate Polymers. Nov2015, Vol. 132, p214-220. 7p. |
| Subjects: | Cation analysis, Linters, Substitution reactions, Cellulose, Chemical derivatives, Ultrasonics, Hydrogen bonding |
| Abstract: | As an important cellulose derivative, cationic cellulose has becoming an attractive material. However, it remains challenging to produce cationic cellulose with high substitute degree. In this paper, we successfully increased the substitute degree of cationic cellulose by introducing ultrasonic treatment, which efficiently breaks hydrogen bonds of the chemical structure of cationic cellulose. Properties of cationic cellulose were studied by scanning electron spectroscope (SEM), contact angle, X-ray diffraction (XRD) and thermogravimetric analysis (TGA). Experimental results show that the cationic cellulose has rougher surface and lower crystallinity degree as compared to the original sample. TGA analysis verifies that the thermostability of CLC decreases after the cationic modification. The residual of the cationic cellulose (25 wt%) after pyrolysis increases significantly as compared to that of the original cellulose (15 wt%). [ABSTRACT FROM AUTHOR] |
| Copyright of Carbohydrate Polymers is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
| FullText | Text: Availability: 0 |
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| Header | DbId: egs DbLabel: Engineering Source An: 108786999 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Preparing cationic cotton linter cellulose with high substitution degree by ultrasonic treatment. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Zhang%2C+Fulong%22">Zhang, Fulong</searchLink><relatesTo>1</relatesTo><i> zfl363@126.com</i><br /><searchLink fieldCode="AR" term="%22Pang%2C+Zhiqiang%22">Pang, Zhiqiang</searchLink><relatesTo>1</relatesTo><i> zhiqiang8508@126.com</i><br /><searchLink fieldCode="AR" term="%22Dong%2C+Cuihua%22">Dong, Cuihua</searchLink><relatesTo>1</relatesTo><i> xiaodong771111@163.com</i><br /><searchLink fieldCode="AR" term="%22Liu%2C+Zong%22">Liu, Zong</searchLink><relatesTo>2</relatesTo><i> zliu73@wisc.edu</i> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Carbohydrate+Polymers%22">Carbohydrate Polymers</searchLink>. Nov2015, Vol. 132, p214-220. 7p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Cation+analysis%22">Cation analysis</searchLink><br /><searchLink fieldCode="DE" term="%22Linters%22">Linters</searchLink><br /><searchLink fieldCode="DE" term="%22Substitution+reactions%22">Substitution reactions</searchLink><br /><searchLink fieldCode="DE" term="%22Cellulose%22">Cellulose</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+derivatives%22">Chemical derivatives</searchLink><br /><searchLink fieldCode="DE" term="%22Ultrasonics%22">Ultrasonics</searchLink><br /><searchLink fieldCode="DE" term="%22Hydrogen+bonding%22">Hydrogen bonding</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: As an important cellulose derivative, cationic cellulose has becoming an attractive material. However, it remains challenging to produce cationic cellulose with high substitute degree. In this paper, we successfully increased the substitute degree of cationic cellulose by introducing ultrasonic treatment, which efficiently breaks hydrogen bonds of the chemical structure of cationic cellulose. Properties of cationic cellulose were studied by scanning electron spectroscope (SEM), contact angle, X-ray diffraction (XRD) and thermogravimetric analysis (TGA). Experimental results show that the cationic cellulose has rougher surface and lower crystallinity degree as compared to the original sample. TGA analysis verifies that the thermostability of CLC decreases after the cationic modification. The residual of the cationic cellulose (25 wt%) after pyrolysis increases significantly as compared to that of the original cellulose (15 wt%). [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Carbohydrate Polymers is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1016/j.carbpol.2015.06.055 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 7 StartPage: 214 Subjects: – SubjectFull: Cation analysis Type: general – SubjectFull: Linters Type: general – SubjectFull: Substitution reactions Type: general – SubjectFull: Cellulose Type: general – SubjectFull: Chemical derivatives Type: general – SubjectFull: Ultrasonics Type: general – SubjectFull: Hydrogen bonding Type: general Titles: – TitleFull: Preparing cationic cotton linter cellulose with high substitution degree by ultrasonic treatment. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Zhang, Fulong – PersonEntity: Name: NameFull: Pang, Zhiqiang – PersonEntity: Name: NameFull: Dong, Cuihua – PersonEntity: Name: NameFull: Liu, Zong IsPartOfRelationships: – BibEntity: Dates: – D: 05 M: 11 Text: Nov2015 Type: published Y: 2015 Identifiers: – Type: issn-print Value: 01448617 Numbering: – Type: volume Value: 132 Titles: – TitleFull: Carbohydrate Polymers Type: main |
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