General cooperative effects of single atom ligands on a metal: a 195Pt NMR chemical shift as a function of coordinated halido ligands’ ionic radii overall sum.
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| Title: | General cooperative effects of single atom ligands on a metal: a 195Pt NMR chemical shift as a function of coordinated halido ligands’ ionic radii overall sum. |
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| Authors: | Benedetti, M.1, de Castro, F.1, Antonucci, D.1, Papadia, P.1, Fanizzi, F. P.1 |
| Source: | Dalton Transactions: An International Journal of Inorganic Chemistry. 9/21/2015, Vol. 44 Issue 35, p15377-15381. 5p. |
| Subjects: | Ligand exchange reactions, Coordination compounds, Atoms, Nuclear magnetic resonance, Halides |
| Abstract: | An inverse linear relationship between the experimentally observed 195Pt NMR signals and the overall sum of coordinated halido ligands’ ionic radii was discovered in Pt(ii) and Pt(iv) complexes. The reduction of 195Pt NMR frequencies parallels the increase of coordinated halido ligands’ ionic radii sum. This suggests that each halido ligand may act as a conducting ring whose induced electric current shields the 195Pt NMR signals proportionally to the ionic radius of the coordinated halido ligand. [ABSTRACT FROM AUTHOR] |
| Copyright of Dalton Transactions: An International Journal of Inorganic Chemistry is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
| FullText | Text: Availability: 0 |
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| Header | DbId: egs DbLabel: Engineering Source An: 109124013 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: General cooperative effects of single atom ligands on a metal: a <superscript>195</superscript>Pt NMR chemical shift as a function of coordinated halido ligands’ ionic radii overall sum. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Benedetti%2C+M%2E%22">Benedetti, M.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22de+Castro%2C+F%2E%22">de Castro, F.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Antonucci%2C+D%2E%22">Antonucci, D.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Papadia%2C+P%2E%22">Papadia, P.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Fanizzi%2C+F%2E+P%2E%22">Fanizzi, F. P.</searchLink><relatesTo>1</relatesTo> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Dalton+Transactions%3A+An+International+Journal+of+Inorganic+Chemistry%22">Dalton Transactions: An International Journal of Inorganic Chemistry</searchLink>. 9/21/2015, Vol. 44 Issue 35, p15377-15381. 5p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Ligand+exchange+reactions%22">Ligand exchange reactions</searchLink><br /><searchLink fieldCode="DE" term="%22Coordination+compounds%22">Coordination compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Atoms%22">Atoms</searchLink><br /><searchLink fieldCode="DE" term="%22Nuclear+magnetic+resonance%22">Nuclear magnetic resonance</searchLink><br /><searchLink fieldCode="DE" term="%22Halides%22">Halides</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: An inverse linear relationship between the experimentally observed 195Pt NMR signals and the overall sum of coordinated halido ligands’ ionic radii was discovered in Pt(ii) and Pt(iv) complexes. The reduction of 195Pt NMR frequencies parallels the increase of coordinated halido ligands’ ionic radii sum. This suggests that each halido ligand may act as a conducting ring whose induced electric current shields the 195Pt NMR signals proportionally to the ionic radius of the coordinated halido ligand. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Dalton Transactions: An International Journal of Inorganic Chemistry is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1039/c5dt02285a Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 5 StartPage: 15377 Subjects: – SubjectFull: Ligand exchange reactions Type: general – SubjectFull: Coordination compounds Type: general – SubjectFull: Atoms Type: general – SubjectFull: Nuclear magnetic resonance Type: general – SubjectFull: Halides Type: general Titles: – TitleFull: General cooperative effects of single atom ligands on a metal: a 195Pt NMR chemical shift as a function of coordinated halido ligands’ ionic radii overall sum. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Benedetti, M. – PersonEntity: Name: NameFull: de Castro, F. – PersonEntity: Name: NameFull: Antonucci, D. – PersonEntity: Name: NameFull: Papadia, P. – PersonEntity: Name: NameFull: Fanizzi, F. P. IsPartOfRelationships: – BibEntity: Dates: – D: 21 M: 09 Text: 9/21/2015 Type: published Y: 2015 Identifiers: – Type: issn-print Value: 14779226 Numbering: – Type: volume Value: 44 – Type: issue Value: 35 Titles: – TitleFull: Dalton Transactions: An International Journal of Inorganic Chemistry Type: main |
| ResultId | 1 |
