Variability of aerosols and chemical composition of PM10, PM2.5 and PM1 on a platform of the Prague underground metro.

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Title: Variability of aerosols and chemical composition of PM10, PM2.5 and PM1 on a platform of the Prague underground metro.
Authors: Cusack, M.1 cusack@icpf.cas.cz, Talbot, N.1, Ondráček, J.1, Minguillón, M.C.2, Martins, V.2,3, Klouda, K.4, Schwarz, J.1, Ždímal, V.1
Source: Atmospheric Environment. Oct2015, Vol. 118, p176-183. 8p.
Subjects: Atmospheric aerosols, Atmospheric chemistry, Particulate matter, Inorganic chemistry, Passenger trains
Geographic Terms: Prague (Czech Republic)
Abstract: Measurements of PM 10 , PM 2.5 and PM 1 and particle number concentration and size distribution were measured for 24 h on a platform of the Prague underground metro in October 2013. The three PM fractions were analysed for major and minor elements, secondary inorganic aerosols (SIA) and total carbon (TC). Measurements were performed both when the metro was inoperative and closed to the public (referred to as background), and when the metro was in operation and open to passengers. PM concentrations were elevated during both periods, but were substantially increased in the coarse fraction during hours when the metro was in operation. Average PM concentrations were 214.8, 93.9 and 44.8 μg m −3 for PM 10 , PM 2.5 and PM 1 , respectively (determined gravimetrically). Average particle number concentrations were 8.5 × 10 3 cm −3 for background hours and 11.5 × 10 3 cm −3 during operational hours. Particle number concentrations were found to not vary as significantly as PM concentrations throughout the day. Variations in PM were strongly governed by passing trains, with highest concentrations recorded during rush hour. When trains were less frequent, PM concentrations were shown to fluctuate in unison with the entrance and exit of trains (as shown by wind velocity measured on the platform). PM was found to be highly enriched with iron, especially in the coarse fraction, comprising 46% of PM 10 (98.9 μg m −3 ). This reduces to 6.7 μg m −3 during background hours, proving that the trains themselves were the main source of iron, most probably from wheel-rail mechanical abrasion. Other enriched elements relative to background hours included Ba, Cu, Mn, Cr, Mo, Ni and Co, among others. Many of these elements exhibited a similar size distribution, further indicating their sources were common and were attributed to train operations. [ABSTRACT FROM AUTHOR]
Copyright of Atmospheric Environment is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Variability of aerosols and chemical composition of PM10, PM2.5 and PM1 on a platform of the Prague underground metro.
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  Data: Measurements of PM 10 , PM 2.5 and PM 1 and particle number concentration and size distribution were measured for 24 h on a platform of the Prague underground metro in October 2013. The three PM fractions were analysed for major and minor elements, secondary inorganic aerosols (SIA) and total carbon (TC). Measurements were performed both when the metro was inoperative and closed to the public (referred to as background), and when the metro was in operation and open to passengers. PM concentrations were elevated during both periods, but were substantially increased in the coarse fraction during hours when the metro was in operation. Average PM concentrations were 214.8, 93.9 and 44.8 μg m −3 for PM 10 , PM 2.5 and PM 1 , respectively (determined gravimetrically). Average particle number concentrations were 8.5 × 10 3 cm −3 for background hours and 11.5 × 10 3 cm −3 during operational hours. Particle number concentrations were found to not vary as significantly as PM concentrations throughout the day. Variations in PM were strongly governed by passing trains, with highest concentrations recorded during rush hour. When trains were less frequent, PM concentrations were shown to fluctuate in unison with the entrance and exit of trains (as shown by wind velocity measured on the platform). PM was found to be highly enriched with iron, especially in the coarse fraction, comprising 46% of PM 10 (98.9 μg m −3 ). This reduces to 6.7 μg m −3 during background hours, proving that the trains themselves were the main source of iron, most probably from wheel-rail mechanical abrasion. Other enriched elements relative to background hours included Ba, Cu, Mn, Cr, Mo, Ni and Co, among others. Many of these elements exhibited a similar size distribution, further indicating their sources were common and were attributed to train operations. [ABSTRACT FROM AUTHOR]
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  Data: <i>Copyright of Atmospheric Environment is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1016/j.atmosenv.2015.08.013
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      – Code: eng
        Text: English
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        PageCount: 8
        StartPage: 176
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      – SubjectFull: Atmospheric aerosols
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      – SubjectFull: Atmospheric chemistry
        Type: general
      – SubjectFull: Particulate matter
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      – SubjectFull: Inorganic chemistry
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      – SubjectFull: Passenger trains
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      – SubjectFull: Prague (Czech Republic)
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      – TitleFull: Variability of aerosols and chemical composition of PM10, PM2.5 and PM1 on a platform of the Prague underground metro.
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              Text: Oct2015
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