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Discussion on “The action of elemental sulfur plus water on 1-octene at low temperatures” by Said-Ahmad et al. (Organic Geochemistry 59, 82–86).

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Title: Discussion on “The action of elemental sulfur plus water on 1-octene at low temperatures” by Said-Ahmad et al. (Organic Geochemistry 59, 82–86).
Authors: Ding, Kangle1,2 dingkl2001@163.com, Adam, Pierre3
Source: Organic Geochemistry. Oct2015, Vol. 87, p133-136. 4p.
Subjects: Octene, Low temperatures, Organic geochemistry, Radicals (Chemistry), Oxygenation (Chemistry), Aqueous solutions
Abstract: A recent article (Said-Ahmad, W., Amrani, A., Aizenshtat, Z., 2013. The action of elemental sulfur plus water on 1-octene at low temperatures. Organic Geochemistry 59, 82–86) is commented on in this discussion. Radical mechanisms proposed by Said-Ahmad et al. (2013) for the formation of sulfurized and oxidized organic compounds in experiments involving elemental sulfur and 1-octene under aqueous conditions, aimed at investigating the interaction of organic matter and sulfur compounds under geological conditions, are not compatible with their experimental results and other studies. In addition, results from the experiments aimed at demonstrating the role of HO radicals in the formation of oxidized organic compounds were incorrectly interpreted by the authors. In this discussion, alternative mechanisms for the formation of the sulfurized and oxygenated products reported by Said-Ahmad et al. (2013) are proposed. [ABSTRACT FROM AUTHOR]
Copyright of Organic Geochemistry is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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DbLabel: Engineering Source
An: 109180998
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PubType: Academic Journal
PubTypeId: academicJournal
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  Data: Discussion on “The action of elemental sulfur plus water on 1-octene at low temperatures” by Said-Ahmad et al. (Organic Geochemistry 59, 82–86).
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  Data: <searchLink fieldCode="AR" term="%22Ding%2C+Kangle%22">Ding, Kangle</searchLink><relatesTo>1,2</relatesTo><i> dingkl2001@163.com</i><br /><searchLink fieldCode="AR" term="%22Adam%2C+Pierre%22">Adam, Pierre</searchLink><relatesTo>3</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Organic+Geochemistry%22">Organic Geochemistry</searchLink>. Oct2015, Vol. 87, p133-136. 4p.
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  Data: <searchLink fieldCode="DE" term="%22Octene%22">Octene</searchLink><br /><searchLink fieldCode="DE" term="%22Low+temperatures%22">Low temperatures</searchLink><br /><searchLink fieldCode="DE" term="%22Organic+geochemistry%22">Organic geochemistry</searchLink><br /><searchLink fieldCode="DE" term="%22Radicals+%28Chemistry%29%22">Radicals (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Oxygenation+%28Chemistry%29%22">Oxygenation (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Aqueous+solutions%22">Aqueous solutions</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: A recent article (Said-Ahmad, W., Amrani, A., Aizenshtat, Z., 2013. The action of elemental sulfur plus water on 1-octene at low temperatures. Organic Geochemistry 59, 82–86) is commented on in this discussion. Radical mechanisms proposed by Said-Ahmad et al. (2013) for the formation of sulfurized and oxidized organic compounds in experiments involving elemental sulfur and 1-octene under aqueous conditions, aimed at investigating the interaction of organic matter and sulfur compounds under geological conditions, are not compatible with their experimental results and other studies. In addition, results from the experiments aimed at demonstrating the role of HO radicals in the formation of oxidized organic compounds were incorrectly interpreted by the authors. In this discussion, alternative mechanisms for the formation of the sulfurized and oxygenated products reported by Said-Ahmad et al. (2013) are proposed. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Organic Geochemistry is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1016/j.orggeochem.2015.06.011
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      – Code: eng
        Text: English
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        PageCount: 4
        StartPage: 133
    Subjects:
      – SubjectFull: Octene
        Type: general
      – SubjectFull: Low temperatures
        Type: general
      – SubjectFull: Organic geochemistry
        Type: general
      – SubjectFull: Radicals (Chemistry)
        Type: general
      – SubjectFull: Oxygenation (Chemistry)
        Type: general
      – SubjectFull: Aqueous solutions
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      – TitleFull: Discussion on “The action of elemental sulfur plus water on 1-octene at low temperatures” by Said-Ahmad et al. (Organic Geochemistry 59, 82–86).
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              Text: Oct2015
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              Y: 2015
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