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Alkali metal salts of rutin – Synthesis, spectroscopic (FT-IR, FT-Raman, UV–VIS), antioxidant and antimicrobial studies.

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Title: Alkali metal salts of rutin – Synthesis, spectroscopic (FT-IR, FT-Raman, UV–VIS), antioxidant and antimicrobial studies.
Authors: Samsonowicz, M.1 m.samsonowicz@pb.edu.pl, Kamińska, I.1, Kalinowska, M.1, Lewandowski, W.1
Source: Spectrochimica Acta Part A: Molecular & Biomolecular Spectroscopy. Dec2015, Vol. 151, p926-938. 13p.
Subjects: Alkali metals, Salts, Rutin, Chemical synthesis, Fourier transform infrared spectroscopy, Chemical structure
Abstract: In this work several metal salts of rutin with lithium, sodium, potassium, rubidium and cesium were synthesized. Their molecular structures were discussed on the basis of spectroscopic (FT-IR, FT-Raman, UV–VIS) studies. Optimized geometrical structure of rutin was calculated by B3LYP/6-311++G ∗∗ method and sodium salt of rutin were calculated by B3LYP/LanL2DZ method. Metal chelation change the biological properties of ligand therefore the antioxidant (FRAP and DPPH) and antimicrobial activities (toward Escherichia coli , Staphylococcus aureus , Enterococcus faecium , Proteus vulgaris , Pseudomonas aeruginosa , Klebsiella pneumonia , Candida albicans and Saccharomyces cerevisiae ) of alkali metal salts were evaluated and compared with the biological properties of rutin. [ABSTRACT FROM AUTHOR]
Copyright of Spectrochimica Acta Part A: Molecular & Biomolecular Spectroscopy is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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Header DbId: egs
DbLabel: Engineering Source
An: 109358430
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
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  Data: Alkali metal salts of rutin – Synthesis, spectroscopic (FT-IR, FT-Raman, UV–VIS), antioxidant and antimicrobial studies.
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  Data: <searchLink fieldCode="DE" term="%22Alkali+metals%22">Alkali metals</searchLink><br /><searchLink fieldCode="DE" term="%22Salts%22">Salts</searchLink><br /><searchLink fieldCode="DE" term="%22Rutin%22">Rutin</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+synthesis%22">Chemical synthesis</searchLink><br /><searchLink fieldCode="DE" term="%22Fourier+transform+infrared+spectroscopy%22">Fourier transform infrared spectroscopy</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+structure%22">Chemical structure</searchLink>
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  Data: In this work several metal salts of rutin with lithium, sodium, potassium, rubidium and cesium were synthesized. Their molecular structures were discussed on the basis of spectroscopic (FT-IR, FT-Raman, UV–VIS) studies. Optimized geometrical structure of rutin was calculated by B3LYP/6-311++G ∗∗ method and sodium salt of rutin were calculated by B3LYP/LanL2DZ method. Metal chelation change the biological properties of ligand therefore the antioxidant (FRAP and DPPH) and antimicrobial activities (toward Escherichia coli , Staphylococcus aureus , Enterococcus faecium , Proteus vulgaris , Pseudomonas aeruginosa , Klebsiella pneumonia , Candida albicans and Saccharomyces cerevisiae ) of alkali metal salts were evaluated and compared with the biological properties of rutin. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
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  Data: <i>Copyright of Spectrochimica Acta Part A: Molecular & Biomolecular Spectroscopy is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
PLink https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&db=egs&AN=109358430
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        Value: 10.1016/j.saa.2015.07.027
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        Text: English
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      – SubjectFull: Alkali metals
        Type: general
      – SubjectFull: Salts
        Type: general
      – SubjectFull: Rutin
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      – SubjectFull: Chemical synthesis
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      – SubjectFull: Fourier transform infrared spectroscopy
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              Text: Dec2015
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