Deposition and characterization of Cu2SnS3 thin films by co-evaporation for photovoltaic application.

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Title: Deposition and characterization of Cu2SnS3 thin films by co-evaporation for photovoltaic application.
Authors: Srinivasa Reddy, T.1, Amiruddin, R.1, Santhosh Kumar, M.C.1 Srinusolasa728@gmail.com
Source: Solar Energy Materials & Solar Cells. Dec2015, Vol. 143, p128-134. 7p.
Subjects: Copper-tin alloys, Metallic thin films, Thin film deposition, Evaporation (Chemistry), Photovoltaic cells, Band gaps
Abstract: Cu 2 SnS 3 (CTS) is a p-type direct band gap ternary compound semiconductor. Its constituent elements are non-toxic, abundant in earth crust and low cost. We report the deposition of Cu 2 SnS 3 thin films on soda-lime glass substrate by co-evaporation technique at different substrate temperatures. The effect of substrate temperature on the growth of CTS thin films has been investigated. X-ray diffraction study confirms the formation of tetragonal phase of Cu 2 SnS 3 . The Raman analysis confirms the ternary/binary phases of the CTS thin films. The surface morphology of the film is examined by atomic force microscopy (AFM) and Scanning electron microscopy (SEM). Energy dispersive spectroscopy (EDS) has been used for analyzing the film composition. The X-ray photoelectron spectroscopy (XPS) shows that Cu, Sn and S are in the oxidation states of +1, +4 and −2 respectively. The optical band gap of CTS thin films is 1.23 eV and the absorption coefficient is the order of 10 5 cm −1 . Hall measurements confirm the p-type nature of the as-prepared CTS films. The carrier concentration, resistivity and mobility are 2.81×10 21 cm −3 , 1.31×10 −3 Ω cm and 1.70 cm 2 V −1 S −1 respectively. [ABSTRACT FROM AUTHOR]
Copyright of Solar Energy Materials & Solar Cells is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Deposition and characterization of Cu2SnS3 thin films by co-evaporation for photovoltaic application.
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  Data: <searchLink fieldCode="AR" term="%22Srinivasa+Reddy%2C+T%2E%22">Srinivasa Reddy, T.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Amiruddin%2C+R%2E%22">Amiruddin, R.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Santhosh+Kumar%2C+M%2EC%2E%22">Santhosh Kumar, M.C.</searchLink><relatesTo>1</relatesTo><i> Srinusolasa728@gmail.com</i>
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  Data: <searchLink fieldCode="JN" term="%22Solar+Energy+Materials+%26+Solar+Cells%22">Solar Energy Materials & Solar Cells</searchLink>. Dec2015, Vol. 143, p128-134. 7p.
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  Data: <searchLink fieldCode="DE" term="%22Copper-tin+alloys%22">Copper-tin alloys</searchLink><br /><searchLink fieldCode="DE" term="%22Metallic+thin+films%22">Metallic thin films</searchLink><br /><searchLink fieldCode="DE" term="%22Thin+film+deposition%22">Thin film deposition</searchLink><br /><searchLink fieldCode="DE" term="%22Evaporation+%28Chemistry%29%22">Evaporation (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Photovoltaic+cells%22">Photovoltaic cells</searchLink><br /><searchLink fieldCode="DE" term="%22Band+gaps%22">Band gaps</searchLink>
– Name: Abstract
  Label: Abstract
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  Data: Cu 2 SnS 3 (CTS) is a p-type direct band gap ternary compound semiconductor. Its constituent elements are non-toxic, abundant in earth crust and low cost. We report the deposition of Cu 2 SnS 3 thin films on soda-lime glass substrate by co-evaporation technique at different substrate temperatures. The effect of substrate temperature on the growth of CTS thin films has been investigated. X-ray diffraction study confirms the formation of tetragonal phase of Cu 2 SnS 3 . The Raman analysis confirms the ternary/binary phases of the CTS thin films. The surface morphology of the film is examined by atomic force microscopy (AFM) and Scanning electron microscopy (SEM). Energy dispersive spectroscopy (EDS) has been used for analyzing the film composition. The X-ray photoelectron spectroscopy (XPS) shows that Cu, Sn and S are in the oxidation states of +1, +4 and −2 respectively. The optical band gap of CTS thin films is 1.23 eV and the absorption coefficient is the order of 10 5 cm −1 . Hall measurements confirm the p-type nature of the as-prepared CTS films. The carrier concentration, resistivity and mobility are 2.81×10 21 cm −3 , 1.31×10 −3 Ω cm and 1.70 cm 2 V −1 S −1 respectively. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Solar Energy Materials & Solar Cells is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1016/j.solmat.2015.06.049
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      – Code: eng
        Text: English
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        PageCount: 7
        StartPage: 128
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      – SubjectFull: Copper-tin alloys
        Type: general
      – SubjectFull: Metallic thin films
        Type: general
      – SubjectFull: Thin film deposition
        Type: general
      – SubjectFull: Evaporation (Chemistry)
        Type: general
      – SubjectFull: Photovoltaic cells
        Type: general
      – SubjectFull: Band gaps
        Type: general
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      – TitleFull: Deposition and characterization of Cu2SnS3 thin films by co-evaporation for photovoltaic application.
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            NameFull: Srinivasa Reddy, T.
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            NameFull: Amiruddin, R.
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            NameFull: Santhosh Kumar, M.C.
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              M: 12
              Text: Dec2015
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              Y: 2015
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