Size effects in lithium ion batteries.

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Title: Size effects in lithium ion batteries.
Authors: Hu-Rong Yao1,2, Ya-Xia Yin1, Yu-Gao Guo1,2,3,4 ygguo@iccas.ac.cn
Source: Chinese Physics B. Jan2016, Vol. 25 Issue 1, p1-1. 1p.
Subjects: Thermodynamics, Electrodes, Particle size determination, Surface energy, Electrolytes
Abstract: Size-related properties of novel lithium battery materials, arising from kinetics, thermodynamics, and newly discovered lithium storage mechanisms, are reviewed. Complementary experimental and computational investigations of the use of the size effects to modify electrodes and electrolytes for lithium ion batteries are enumerated and discussed together. Size differences in the materials in lithium ion batteries lead to a variety of exciting phenomena. Smaller-particle materials with highly connective interfaces and reduced diffusion paths exhibit higher rate performance than the corresponding bulk materials. The thermodynamics is also changed by the higher surface energy of smaller particles, affecting, for example, secondary surface reactions, lattice parameter, voltage, and the phase transformation mechanism. Newly discovered lithium storage mechanisms that result in superior storage capacity are also briefly highlighted. [ABSTRACT FROM AUTHOR]
Copyright of Chinese Physics B is the property of IOP Publishing and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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DbLabel: Engineering Source
An: 112370067
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PubType: Academic Journal
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  Data: Size effects in lithium ion batteries.
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  Data: <searchLink fieldCode="AR" term="%22Hu-Rong+Yao%22">Hu-Rong Yao</searchLink><relatesTo>1,2</relatesTo><br /><searchLink fieldCode="AR" term="%22Ya-Xia+Yin%22">Ya-Xia Yin</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Yu-Gao+Guo%22">Yu-Gao Guo</searchLink><relatesTo>1,2,3,4</relatesTo><i> ygguo@iccas.ac.cn</i>
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  Data: <searchLink fieldCode="JN" term="%22Chinese+Physics+B%22">Chinese Physics B</searchLink>. Jan2016, Vol. 25 Issue 1, p1-1. 1p.
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  Data: <searchLink fieldCode="DE" term="%22Thermodynamics%22">Thermodynamics</searchLink><br /><searchLink fieldCode="DE" term="%22Electrodes%22">Electrodes</searchLink><br /><searchLink fieldCode="DE" term="%22Particle+size+determination%22">Particle size determination</searchLink><br /><searchLink fieldCode="DE" term="%22Surface+energy%22">Surface energy</searchLink><br /><searchLink fieldCode="DE" term="%22Electrolytes%22">Electrolytes</searchLink>
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  Data: Size-related properties of novel lithium battery materials, arising from kinetics, thermodynamics, and newly discovered lithium storage mechanisms, are reviewed. Complementary experimental and computational investigations of the use of the size effects to modify electrodes and electrolytes for lithium ion batteries are enumerated and discussed together. Size differences in the materials in lithium ion batteries lead to a variety of exciting phenomena. Smaller-particle materials with highly connective interfaces and reduced diffusion paths exhibit higher rate performance than the corresponding bulk materials. The thermodynamics is also changed by the higher surface energy of smaller particles, affecting, for example, secondary surface reactions, lattice parameter, voltage, and the phase transformation mechanism. Newly discovered lithium storage mechanisms that result in superior storage capacity are also briefly highlighted. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Chinese Physics B is the property of IOP Publishing and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1088/1674-1056/25/1/018203
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      – Code: eng
        Text: English
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    Subjects:
      – SubjectFull: Thermodynamics
        Type: general
      – SubjectFull: Electrodes
        Type: general
      – SubjectFull: Particle size determination
        Type: general
      – SubjectFull: Surface energy
        Type: general
      – SubjectFull: Electrolytes
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      – TitleFull: Size effects in lithium ion batteries.
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            NameFull: Hu-Rong Yao
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            NameFull: Ya-Xia Yin
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              Text: Jan2016
              Type: published
              Y: 2016
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              Value: 25
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