Analysis of Proton -- Proton Transfer Dynamics in Rotating Solids and Their Use for 3D Structure Determination.
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| Title: | Analysis of Proton -- Proton Transfer Dynamics in Rotating Solids and Their Use for 3D Structure Determination. |
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| Authors: | Lange, Adam1, Seidel, Karsten1, Verdier, Laurent1, Luca, Sorin1 maba@mpibpc.de, Baldus, Marc |
| Source: | Journal of the American Chemical Society. 10/15/2003, Vol. 125 Issue 41, p12640-12648. 9p. |
| Subjects: | Proton-proton interactions, Nuclear magnetic resonance, Solids, Dynamics |
| Abstract: | Presents a detailed analysis of proton-proton transfer dynamics under magic angle spinning nuclear magnetic resonance(NMR). NMR mixing schemes and experimental conditions under which model compounds are evaluated; Interpretation of the resulting buildup rates in terms of internuclear proton-proton distances; Use of dependencies in the context of a three-dimensional structure determination in the solid state. |
| Database: | Engineering Source |
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