Gated Materials for On-Command Release of Guest Molecules.

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Title: Gated Materials for On-Command Release of Guest Molecules.
Authors: Aznar, Elena1,2, Oroval, Mar1,2, Pascual, Lluís1,2, Murguía, Jose Ramón1,2,3, Martínez-Máñez, Ramón1,2,4 rmaez@qim.upv.es, Sancenón, Félix1,2,4
Source: Chemical Reviews. 1/27/2016, Vol. 116 Issue 2, p561-718. 158p.
Subjects: Gate array circuits, Biochemistry, Stimulus & response (Psychology), Porous materials, Mass transfer
Abstract: Multidisciplinary research at the forefront of the field of hybrid materials has paved the way to the development of endless examples of smart devices. One appealing concept in this fertile field is related to the design of gated materials. These are constructed for finely tuning the delivery of chemical or biochemical species from voids of porous supports to a solution in response to predefined stimuli. Such gated materials are composed mainly of two subunits: (i) a porous inorganic support in which a cargo is loaded and (ii) certain molecular or supramolecular entities, generally grafted onto the external surface, which can control mass transport from pores. On the basis of this concept, a large number of imaginative examples have been developed. This review intends to be a comprehensive analysis of papers published until 2014 on hybrid mesoporous gated materials. The molecules used as gates, the opening mechanisms, and controlled release behavior are detailed. We hope this review will not only help researchers who work in this field but also may open the minds of related ones to develop new advances in this fertile research area. [ABSTRACT FROM AUTHOR]
Copyright of Chemical Reviews is the property of American Chemical Society and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Gated Materials for On-Command Release of Guest Molecules.
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  Data: <searchLink fieldCode="JN" term="%22Chemical+Reviews%22">Chemical Reviews</searchLink>. 1/27/2016, Vol. 116 Issue 2, p561-718. 158p.
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  Data: <searchLink fieldCode="DE" term="%22Gate+array+circuits%22">Gate array circuits</searchLink><br /><searchLink fieldCode="DE" term="%22Biochemistry%22">Biochemistry</searchLink><br /><searchLink fieldCode="DE" term="%22Stimulus+%26+response+%28Psychology%29%22">Stimulus & response (Psychology)</searchLink><br /><searchLink fieldCode="DE" term="%22Porous+materials%22">Porous materials</searchLink><br /><searchLink fieldCode="DE" term="%22Mass+transfer%22">Mass transfer</searchLink>
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  Data: Multidisciplinary research at the forefront of the field of hybrid materials has paved the way to the development of endless examples of smart devices. One appealing concept in this fertile field is related to the design of gated materials. These are constructed for finely tuning the delivery of chemical or biochemical species from voids of porous supports to a solution in response to predefined stimuli. Such gated materials are composed mainly of two subunits: (i) a porous inorganic support in which a cargo is loaded and (ii) certain molecular or supramolecular entities, generally grafted onto the external surface, which can control mass transport from pores. On the basis of this concept, a large number of imaginative examples have been developed. This review intends to be a comprehensive analysis of papers published until 2014 on hybrid mesoporous gated materials. The molecules used as gates, the opening mechanisms, and controlled release behavior are detailed. We hope this review will not only help researchers who work in this field but also may open the minds of related ones to develop new advances in this fertile research area. [ABSTRACT FROM AUTHOR]
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  Data: <i>Copyright of Chemical Reviews is the property of American Chemical Society and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1021/acs.chemrev.5b00456
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        Text: English
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              Text: 1/27/2016
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