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Iron cyclopentadienone complexes derived from C2-symmetric bis-propargylic alcohols; preparation and applications to catalysis.

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Title: Iron cyclopentadienone complexes derived from C2-symmetric bis-propargylic alcohols; preparation and applications to catalysis.
Authors: Hodgkinson, Roy1, Del Grosso, Alessandro1, Clarkson, Guy1, Wills, Martin1
Source: Dalton Transactions: An International Journal of Inorganic Chemistry. 3/7/2016, Vol. 45 Issue 9, p3992-4005. 14p.
Subjects: Iron compound synthesis, Cyclopentadiene derivatives, Propargyl alcohol, Carbonyl compounds, Alcohol oxidation, Reduction of ketones, Catalytic activity
Abstract: A series of complexes containing the iron-cyclopentadienone structure were prepared by cyclising bis-propargylic alcohols and their derivatives with iron pentacarbonyl. The resulting complexes were characterised and tested in the catalysis of ketone reduction and alcohol oxidation. The complexes are competent catalysts for ketone reduction and alcohol oxidations. [ABSTRACT FROM AUTHOR]
Copyright of Dalton Transactions: An International Journal of Inorganic Chemistry is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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DbLabel: Engineering Source
An: 113278291
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PubType: Academic Journal
PubTypeId: academicJournal
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  Data: Iron cyclopentadienone complexes derived from C<subscript>2</subscript>-symmetric bis-propargylic alcohols; preparation and applications to catalysis.
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  Data: <searchLink fieldCode="DE" term="%22Iron+compound+synthesis%22">Iron compound synthesis</searchLink><br /><searchLink fieldCode="DE" term="%22Cyclopentadiene+derivatives%22">Cyclopentadiene derivatives</searchLink><br /><searchLink fieldCode="DE" term="%22Propargyl+alcohol%22">Propargyl alcohol</searchLink><br /><searchLink fieldCode="DE" term="%22Carbonyl+compounds%22">Carbonyl compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Alcohol+oxidation%22">Alcohol oxidation</searchLink><br /><searchLink fieldCode="DE" term="%22Reduction+of+ketones%22">Reduction of ketones</searchLink><br /><searchLink fieldCode="DE" term="%22Catalytic+activity%22">Catalytic activity</searchLink>
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  Data: A series of complexes containing the iron-cyclopentadienone structure were prepared by cyclising bis-propargylic alcohols and their derivatives with iron pentacarbonyl. The resulting complexes were characterised and tested in the catalysis of ketone reduction and alcohol oxidation. The complexes are competent catalysts for ketone reduction and alcohol oxidations. [ABSTRACT FROM AUTHOR]
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  Data: <i>Copyright of Dalton Transactions: An International Journal of Inorganic Chemistry is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1039/c5dt04610f
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      – Code: eng
        Text: English
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        PageCount: 14
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    Subjects:
      – SubjectFull: Iron compound synthesis
        Type: general
      – SubjectFull: Cyclopentadiene derivatives
        Type: general
      – SubjectFull: Propargyl alcohol
        Type: general
      – SubjectFull: Carbonyl compounds
        Type: general
      – SubjectFull: Alcohol oxidation
        Type: general
      – SubjectFull: Reduction of ketones
        Type: general
      – SubjectFull: Catalytic activity
        Type: general
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      – TitleFull: Iron cyclopentadienone complexes derived from C2-symmetric bis-propargylic alcohols; preparation and applications to catalysis.
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              Text: 3/7/2016
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              Y: 2016
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