Detection and measurement of delay in the yield of negative ions from the ionization chamber of a mass spectrometer.

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Title: Detection and measurement of delay in the yield of negative ions from the ionization chamber of a mass spectrometer.
Authors: Lukin, V.1 lukin@anrb.ru, Khvostenko, O.1, Tuimedov, G.1
Source: Technical Physics Letters. Feb2016, Vol. 42 Issue 2, p215-218. 4p.
Subjects: Anion analysis, Ionization chambers, Mass spectrometers, Extraction (Chemistry), Excess electrons
Abstract: The times of extraction of negative ions from the ionization chamber of a mass spectrometer have been measured. The obtained values amount to several dozen microseconds or above-that is, significantly exceed the time of free ion escape from the chamber. It is established that ions are retained in the ionization chamber because of their adsorption on the inner surface. This leads to distortion of the experimentally measured lifetimes of negative ions that become unstable with respect to autodetachment of the excess electron. [ABSTRACT FROM AUTHOR]
Copyright of Technical Physics Letters is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Detection and measurement of delay in the yield of negative ions from the ionization chamber of a mass spectrometer.
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  Data: <searchLink fieldCode="AR" term="%22Lukin%2C+V%2E%22">Lukin, V.</searchLink><relatesTo>1</relatesTo><i> lukin@anrb.ru</i><br /><searchLink fieldCode="AR" term="%22Khvostenko%2C+O%2E%22">Khvostenko, O.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Tuimedov%2C+G%2E%22">Tuimedov, G.</searchLink><relatesTo>1</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Technical+Physics+Letters%22">Technical Physics Letters</searchLink>. Feb2016, Vol. 42 Issue 2, p215-218. 4p.
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  Data: <searchLink fieldCode="DE" term="%22Anion+analysis%22">Anion analysis</searchLink><br /><searchLink fieldCode="DE" term="%22Ionization+chambers%22">Ionization chambers</searchLink><br /><searchLink fieldCode="DE" term="%22Mass+spectrometers%22">Mass spectrometers</searchLink><br /><searchLink fieldCode="DE" term="%22Extraction+%28Chemistry%29%22">Extraction (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Excess+electrons%22">Excess electrons</searchLink>
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  Data: The times of extraction of negative ions from the ionization chamber of a mass spectrometer have been measured. The obtained values amount to several dozen microseconds or above-that is, significantly exceed the time of free ion escape from the chamber. It is established that ions are retained in the ionization chamber because of their adsorption on the inner surface. This leads to distortion of the experimentally measured lifetimes of negative ions that become unstable with respect to autodetachment of the excess electron. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
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  Group: Ab
  Data: <i>Copyright of Technical Physics Letters is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1134/S1063785016020292
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        Text: English
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      – SubjectFull: Mass spectrometers
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      – SubjectFull: Extraction (Chemistry)
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      – SubjectFull: Excess electrons
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      – TitleFull: Detection and measurement of delay in the yield of negative ions from the ionization chamber of a mass spectrometer.
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