Co-hydroprocessing gas-oil with residual lipids: effect of residence time and H2/Oil ratio.

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Bibliographic Details
Title: Co-hydroprocessing gas-oil with residual lipids: effect of residence time and H2/Oil ratio.
Authors: Dimitriadis, Athanasios1, Bezergianni, Stella1 sbezerg@cperi.certh.gr
Source: Journal of Cleaner Production. Sep2016, Vol. 131, p321-326. 6p.
Subjects: Lipids, Hydrotreating catalysts, Hydrogen, Diesel fuels, Petroleum refineries
Abstract: Co-hydroprocessing of petroleum fractions with residual lipids is a promising technology for hybrid fuels production. The aim of this study is the identification of an effective operating window for co-hydroprocessing of Heavy Atmospheric Gas Oil (HAGO) with Waste Cooking Oil (WCO) within the nominal operating limits of a refinery. In particular, two Liquid Hourly Space Velocities or LHSVs (0.66 and 1 h −1 ) and three hydrogen-to-oil or H 2 /Oil ratios (300, 400 and 500 L H 2 /L feed) were studied for a HAGO/WCO 90/10 V/V blended feedstock over a commercial hydrotreating NiMo/Al 2 O 3 catalyst. The two parameters were evaluated with respect to the attained diesel content and quality of the produced hybrid fuels. All experiments were performed at a constant pressure of 5.6 MPa and temperature of 350 °C. The results have shown that higher LHSV is preferable in terms of the hydrogen consumption affecting the conversion cost. As far as H 2 /Oil is concerned, high H 2 /Oil ratios are more effective, rendering higher conversion, diesel content and heteroatom removal. [ABSTRACT FROM AUTHOR]
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Database: Engineering Source
Description
Abstract:Co-hydroprocessing of petroleum fractions with residual lipids is a promising technology for hybrid fuels production. The aim of this study is the identification of an effective operating window for co-hydroprocessing of Heavy Atmospheric Gas Oil (HAGO) with Waste Cooking Oil (WCO) within the nominal operating limits of a refinery. In particular, two Liquid Hourly Space Velocities or LHSVs (0.66 and 1 h −1 ) and three hydrogen-to-oil or H 2 /Oil ratios (300, 400 and 500 L H 2 /L feed) were studied for a HAGO/WCO 90/10 V/V blended feedstock over a commercial hydrotreating NiMo/Al 2 O 3 catalyst. The two parameters were evaluated with respect to the attained diesel content and quality of the produced hybrid fuels. All experiments were performed at a constant pressure of 5.6 MPa and temperature of 350 °C. The results have shown that higher LHSV is preferable in terms of the hydrogen consumption affecting the conversion cost. As far as H 2 /Oil is concerned, high H 2 /Oil ratios are more effective, rendering higher conversion, diesel content and heteroatom removal. [ABSTRACT FROM AUTHOR]
ISSN:09596526
DOI:10.1016/j.jclepro.2016.05.027