Central composite design and genetic algorithm applied for the optimization of ultrasonic-assisted removal of malachite green by ZnO Nanorod-loaded activated carbon.

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Title: Central composite design and genetic algorithm applied for the optimization of ultrasonic-assisted removal of malachite green by ZnO Nanorod-loaded activated carbon.
Authors: Ghaedi, M.1 m_ghaedi@mail.yu.ac.ir, Azad, F. Nasiri1, Dashtian, K.1, Hajati, S.2, Goudarzi, A.3, Soylak, M.4
Source: Spectrochimica Acta Part A: Molecular & Biomolecular Spectroscopy. Oct2016, Vol. 167, p157-164. 8p.
Subjects: Genetic algorithms, Malachite green, Langmuir isotherms, Activated carbon, Fourier transform infrared spectroscopy, X-ray diffraction, Mass transfer, Surface morphology
Abstract: Maximum malachite green (MG) adsorption onto ZnO Nanorod-loaded activated carbon (ZnO-NR-AC) was achieved following the optimization of conditions, while the mass transfer was accelerated by ultrasonic. The central composite design (CCD) and genetic algorithm (GA) were used to estimate the effect of individual variables and their mutual interactions on the MG adsorption as response and to optimize the adsorption process. The ZnO-NR-AC surface morphology and its properties were identified via FESEM, XRD and FTIR. The adsorption equilibrium isotherm and kinetic models investigation revealed the well fit of the experimental data to Langmuir isotherm and pseudo-second-order kinetic model, respectively. It was shown that a small amount of ZnO-NR-AC (with adsorption capacity of 20 mg g − 1 ) is sufficient for the rapid removal of high amount of MG dye in short time (3.99 min). [ABSTRACT FROM AUTHOR]
Copyright of Spectrochimica Acta Part A: Molecular & Biomolecular Spectroscopy is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Label: Title
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  Data: Central composite design and genetic algorithm applied for the optimization of ultrasonic-assisted removal of malachite green by ZnO Nanorod-loaded activated carbon.
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  Data: <searchLink fieldCode="JN" term="%22Spectrochimica+Acta+Part+A%3A+Molecular+%26+Biomolecular+Spectroscopy%22">Spectrochimica Acta Part A: Molecular & Biomolecular Spectroscopy</searchLink>. Oct2016, Vol. 167, p157-164. 8p.
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  Data: <searchLink fieldCode="DE" term="%22Genetic+algorithms%22">Genetic algorithms</searchLink><br /><searchLink fieldCode="DE" term="%22Malachite+green%22">Malachite green</searchLink><br /><searchLink fieldCode="DE" term="%22Langmuir+isotherms%22">Langmuir isotherms</searchLink><br /><searchLink fieldCode="DE" term="%22Activated+carbon%22">Activated carbon</searchLink><br /><searchLink fieldCode="DE" term="%22Fourier+transform+infrared+spectroscopy%22">Fourier transform infrared spectroscopy</searchLink><br /><searchLink fieldCode="DE" term="%22X-ray+diffraction%22">X-ray diffraction</searchLink><br /><searchLink fieldCode="DE" term="%22Mass+transfer%22">Mass transfer</searchLink><br /><searchLink fieldCode="DE" term="%22Surface+morphology%22">Surface morphology</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Maximum malachite green (MG) adsorption onto ZnO Nanorod-loaded activated carbon (ZnO-NR-AC) was achieved following the optimization of conditions, while the mass transfer was accelerated by ultrasonic. The central composite design (CCD) and genetic algorithm (GA) were used to estimate the effect of individual variables and their mutual interactions on the MG adsorption as response and to optimize the adsorption process. The ZnO-NR-AC surface morphology and its properties were identified via FESEM, XRD and FTIR. The adsorption equilibrium isotherm and kinetic models investigation revealed the well fit of the experimental data to Langmuir isotherm and pseudo-second-order kinetic model, respectively. It was shown that a small amount of ZnO-NR-AC (with adsorption capacity of 20 mg g − 1 ) is sufficient for the rapid removal of high amount of MG dye in short time (3.99 min). [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Spectrochimica Acta Part A: Molecular & Biomolecular Spectroscopy is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1016/j.saa.2016.05.025
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        Text: English
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      – SubjectFull: Genetic algorithms
        Type: general
      – SubjectFull: Malachite green
        Type: general
      – SubjectFull: Langmuir isotherms
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      – SubjectFull: Activated carbon
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      – SubjectFull: Fourier transform infrared spectroscopy
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      – SubjectFull: X-ray diffraction
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      – SubjectFull: Mass transfer
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      – SubjectFull: Surface morphology
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      – TitleFull: Central composite design and genetic algorithm applied for the optimization of ultrasonic-assisted removal of malachite green by ZnO Nanorod-loaded activated carbon.
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              Text: Oct2016
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