Synthesis and Characterization of 6,6ˊ-bis(1-(2-ethylhexyl)-1 H -1,2,3-triazol-4-yl)-2,2ˊ-bipyridine (EH–BTzBP) for Actinide/Lanthanide Extraction and Separation.
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| Title: | Synthesis and Characterization of 6,6ˊ-bis(1-(2-ethylhexyl)-1 H -1,2,3-triazol-4-yl)-2,2ˊ-bipyridine (EH–BTzBP) for Actinide/Lanthanide Extraction and Separation. |
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| Authors: | Muller, Julie M.1, Nash, Kenneth L.1 |
| Source: | Solvent Extraction & Ion Exchange. 2016, Vol. 34 Issue 4, p322-333. 12p. |
| Subjects: | Chemical synthesis, Solubility, Solution (Chemistry), Solvent extraction, Solvents, Anions, Hydrogen peroxide |
| Abstract: | A new N-donor extractant, 6,6ˊ-bis(1-(2-ethylhexyl)-1H-1,2,3-triazol-4-yl)-2,2ˊ-bipyridine (EH-BTzBP), was synthesized and tested for Am(III)/Ln(III) extraction and separation. EH-BTzBP in combination with 2-bromohexanoic acid (as lipophilic anion source) selectively extracts Am(III) from acidic solutions (HNO3≤ 0.1M) with Am(III)/Eu(III) separation factors of about 70. Phase transfer kinetics is rapid, back-extraction of metal ions posed no issues, and there is no evidence of ligand degradation by acid hydrolysis or contact with hydrogen peroxide (which simulates some effects of radiolysis). [ABSTRACT FROM PUBLISHER] |
| Copyright of Solvent Extraction & Ion Exchange is the property of Taylor & Francis Ltd and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
| FullText | Text: Availability: 0 |
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| Header | DbId: egs DbLabel: Engineering Source An: 116414221 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Synthesis and Characterization of 6,6ˊ-bis(1-(2-ethylhexyl)-1 H -1,2,3-triazol-4-yl)-2,2ˊ-bipyridine (EH–BTzBP) for Actinide/Lanthanide Extraction and Separation. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Muller%2C+Julie+M%2E%22">Muller, Julie M.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Nash%2C+Kenneth+L%2E%22">Nash, Kenneth L.</searchLink><relatesTo>1</relatesTo> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Solvent+Extraction+%26+Ion+Exchange%22">Solvent Extraction & Ion Exchange</searchLink>. 2016, Vol. 34 Issue 4, p322-333. 12p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Chemical+synthesis%22">Chemical synthesis</searchLink><br /><searchLink fieldCode="DE" term="%22Solubility%22">Solubility</searchLink><br /><searchLink fieldCode="DE" term="%22Solution+%28Chemistry%29%22">Solution (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Solvent+extraction%22">Solvent extraction</searchLink><br /><searchLink fieldCode="DE" term="%22Solvents%22">Solvents</searchLink><br /><searchLink fieldCode="DE" term="%22Anions%22">Anions</searchLink><br /><searchLink fieldCode="DE" term="%22Hydrogen+peroxide%22">Hydrogen peroxide</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: A new N-donor extractant, 6,6ˊ-bis(1-(2-ethylhexyl)-1H-1,2,3-triazol-4-yl)-2,2ˊ-bipyridine (EH-BTzBP), was synthesized and tested for Am(III)/Ln(III) extraction and separation. EH-BTzBP in combination with 2-bromohexanoic acid (as lipophilic anion source) selectively extracts Am(III) from acidic solutions (HNO3≤ 0.1M) with Am(III)/Eu(III) separation factors of about 70. Phase transfer kinetics is rapid, back-extraction of metal ions posed no issues, and there is no evidence of ligand degradation by acid hydrolysis or contact with hydrogen peroxide (which simulates some effects of radiolysis). [ABSTRACT FROM PUBLISHER] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Solvent Extraction & Ion Exchange is the property of Taylor & Francis Ltd and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1080/07366299.2016.1172852 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 12 StartPage: 322 Subjects: – SubjectFull: Chemical synthesis Type: general – SubjectFull: Solubility Type: general – SubjectFull: Solution (Chemistry) Type: general – SubjectFull: Solvent extraction Type: general – SubjectFull: Solvents Type: general – SubjectFull: Anions Type: general – SubjectFull: Hydrogen peroxide Type: general Titles: – TitleFull: Synthesis and Characterization of 6,6ˊ-bis(1-(2-ethylhexyl)-1 H -1,2,3-triazol-4-yl)-2,2ˊ-bipyridine (EH–BTzBP) for Actinide/Lanthanide Extraction and Separation. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Muller, Julie M. – PersonEntity: Name: NameFull: Nash, Kenneth L. IsPartOfRelationships: – BibEntity: Dates: – D: 01 M: 07 Text: 2016 Type: published Y: 2016 Identifiers: – Type: issn-print Value: 07366299 Numbering: – Type: volume Value: 34 – Type: issue Value: 4 Titles: – TitleFull: Solvent Extraction & Ion Exchange Type: main |
| ResultId | 1 |
