View in EDS

Synthesis, structures and cytotoxicity studies of p-sulfonatocalix[4]arene lanthanide complexes.

Saved in:
Bibliographic Details
Title: Synthesis, structures and cytotoxicity studies of p-sulfonatocalix[4]arene lanthanide complexes.
Authors: Miller-Shakesby, David M.1, Burke, Benjamin P.1,2, Nigam, Shubhanchi1,2, Stasiuk, Graeme J.2,3, Prior, Timothy J.1, Archibald, Stephen J.1,2, Redshaw, Carl1
Source: CrystEngComm. 7/14/2016, Vol. 18 Issue 26, p4977-4987. 11p.
Subjects: Rare earth metals, Crystal structure research, Sulfonates, Calixarenes, Coordination polymers
Abstract: A number of p-sulfonatocalix[4]arene complexes of the lanthanides (Tb, Gd, and Eu) have been prepared, some in the presence of tetraazamacrocycle 1,4,7,10-tetraazacyclododecane-1,4,7-triacetic acid (DO3A), and fully characterised. Crystal structure determinations reveal lanthanide coordination at the sulfonate group, bridging several calixarene units, giving coordination polymers. All complexes in this study have been determined to be relatively non-toxic using in vitro cell assays with CC50 values in the range 30–170 μM. [ABSTRACT FROM AUTHOR]
Copyright of CrystEngComm is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
FullText Text:
  Availability: 0
Header DbId: egs
DbLabel: Engineering Source
An: 116485740
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
IllustrationInfo
Items – Name: Title
  Label: Title
  Group: Ti
  Data: Synthesis, structures and cytotoxicity studies of p-sulfonatocalix[4]arene lanthanide complexes.
– Name: Author
  Label: Authors
  Group: Au
  Data: <searchLink fieldCode="AR" term="%22Miller-Shakesby%2C+David+M%2E%22">Miller-Shakesby, David M.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Burke%2C+Benjamin+P%2E%22">Burke, Benjamin P.</searchLink><relatesTo>1,2</relatesTo><br /><searchLink fieldCode="AR" term="%22Nigam%2C+Shubhanchi%22">Nigam, Shubhanchi</searchLink><relatesTo>1,2</relatesTo><br /><searchLink fieldCode="AR" term="%22Stasiuk%2C+Graeme+J%2E%22">Stasiuk, Graeme J.</searchLink><relatesTo>2,3</relatesTo><br /><searchLink fieldCode="AR" term="%22Prior%2C+Timothy+J%2E%22">Prior, Timothy J.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Archibald%2C+Stephen+J%2E%22">Archibald, Stephen J.</searchLink><relatesTo>1,2</relatesTo><br /><searchLink fieldCode="AR" term="%22Redshaw%2C+Carl%22">Redshaw, Carl</searchLink><relatesTo>1</relatesTo>
– Name: TitleSource
  Label: Source
  Group: Src
  Data: <searchLink fieldCode="JN" term="%22CrystEngComm%22">CrystEngComm</searchLink>. 7/14/2016, Vol. 18 Issue 26, p4977-4987. 11p.
– Name: Subject
  Label: Subjects
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Rare+earth+metals%22">Rare earth metals</searchLink><br /><searchLink fieldCode="DE" term="%22Crystal+structure+research%22">Crystal structure research</searchLink><br /><searchLink fieldCode="DE" term="%22Sulfonates%22">Sulfonates</searchLink><br /><searchLink fieldCode="DE" term="%22Calixarenes%22">Calixarenes</searchLink><br /><searchLink fieldCode="DE" term="%22Coordination+polymers%22">Coordination polymers</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: A number of p-sulfonatocalix[4]arene complexes of the lanthanides (Tb, Gd, and Eu) have been prepared, some in the presence of tetraazamacrocycle 1,4,7,10-tetraazacyclododecane-1,4,7-triacetic acid (DO3A), and fully characterised. Crystal structure determinations reveal lanthanide coordination at the sulfonate group, bridging several calixarene units, giving coordination polymers. All complexes in this study have been determined to be relatively non-toxic using in vitro cell assays with CC50 values in the range 30–170 μM. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of CrystEngComm is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
PLink https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&db=egs&AN=116485740
RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1039/c6ce00209a
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 11
        StartPage: 4977
    Subjects:
      – SubjectFull: Rare earth metals
        Type: general
      – SubjectFull: Crystal structure research
        Type: general
      – SubjectFull: Sulfonates
        Type: general
      – SubjectFull: Calixarenes
        Type: general
      – SubjectFull: Coordination polymers
        Type: general
    Titles:
      – TitleFull: Synthesis, structures and cytotoxicity studies of p-sulfonatocalix[4]arene lanthanide complexes.
        Type: main
  BibRelationships:
    HasContributorRelationships:
      – PersonEntity:
          Name:
            NameFull: Miller-Shakesby, David M.
      – PersonEntity:
          Name:
            NameFull: Burke, Benjamin P.
      – PersonEntity:
          Name:
            NameFull: Nigam, Shubhanchi
      – PersonEntity:
          Name:
            NameFull: Stasiuk, Graeme J.
      – PersonEntity:
          Name:
            NameFull: Prior, Timothy J.
      – PersonEntity:
          Name:
            NameFull: Archibald, Stephen J.
      – PersonEntity:
          Name:
            NameFull: Redshaw, Carl
    IsPartOfRelationships:
      – BibEntity:
          Dates:
            – D: 14
              M: 07
              Text: 7/14/2016
              Type: published
              Y: 2016
          Identifiers:
            – Type: issn-print
              Value: 14668033
          Numbering:
            – Type: volume
              Value: 18
            – Type: issue
              Value: 26
          Titles:
            – TitleFull: CrystEngComm
              Type: main
ResultId 1