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Submicron Patterning of Polymer Brushes: An Unexpected Discovery from Inkjet Printing of Polyelectrolyte Macroinitiators.

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Title: Submicron Patterning of Polymer Brushes: An Unexpected Discovery from Inkjet Printing of Polyelectrolyte Macroinitiators.
Authors: Parry, Adam V. S.1, Straub, Alexander J.1,2, Villar-Alvarez, Eva M.1,3, Phuengphol, Takdanai4, Nicoll, Jonathan E. R.1, W. K., Xavier Lim4, Jordan, Lianne M.1, Moore, Katie L.4, Taboada, Pablo3, Yeates, Stephen G.1, Edmondson, Steve4 stephen.edmondson@manchester.ac.uk
Source: Journal of the American Chemical Society. 7/27/2016, Vol. 138 Issue 29, p9009-9012. 4p.
Subjects: Polymers, Ink-jet printers, Polyelectrolytes, Homopolymerizations, Ionic strength
Abstract: Using an electrostatic-based super inkjet printer we report the high-resolution deposition of polyelectrolyte macroinitiators and subsequent polymer brush growth using SI-ARGET-ATRP. We go on to demonstrate for the first time a submicron patterning phenomenon through the addition of either a like charged polyelectrolyte homopolymer or through careful control of ionic strength. As a result patterning of polymer brushes down to ca. 300 nm is reported. We present a possible mechanistic model and consider how this may be applied to other polyelectrolyte-based systems as a general method for submicron patterning. [ABSTRACT FROM AUTHOR]
Copyright of Journal of the American Chemical Society is the property of American Chemical Society and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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PubType: Academic Journal
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  Data: Submicron Patterning of Polymer Brushes: An Unexpected Discovery from Inkjet Printing of Polyelectrolyte Macroinitiators.
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  Data: <searchLink fieldCode="AR" term="%22Parry%2C+Adam+V%2E+S%2E%22">Parry, Adam V. S.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Straub%2C+Alexander+J%2E%22">Straub, Alexander J.</searchLink><relatesTo>1,2</relatesTo><br /><searchLink fieldCode="AR" term="%22Villar-Alvarez%2C+Eva+M%2E%22">Villar-Alvarez, Eva M.</searchLink><relatesTo>1,3</relatesTo><br /><searchLink fieldCode="AR" term="%22Phuengphol%2C+Takdanai%22">Phuengphol, Takdanai</searchLink><relatesTo>4</relatesTo><br /><searchLink fieldCode="AR" term="%22Nicoll%2C+Jonathan+E%2E+R%2E%22">Nicoll, Jonathan E. R.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22W%2E+K%2E%2C+Xavier+Lim%22">W. K., Xavier Lim</searchLink><relatesTo>4</relatesTo><br /><searchLink fieldCode="AR" term="%22Jordan%2C+Lianne+M%2E%22">Jordan, Lianne M.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Moore%2C+Katie+L%2E%22">Moore, Katie L.</searchLink><relatesTo>4</relatesTo><br /><searchLink fieldCode="AR" term="%22Taboada%2C+Pablo%22">Taboada, Pablo</searchLink><relatesTo>3</relatesTo><br /><searchLink fieldCode="AR" term="%22Yeates%2C+Stephen+G%2E%22">Yeates, Stephen G.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Edmondson%2C+Steve%22">Edmondson, Steve</searchLink><relatesTo>4</relatesTo><i> stephen.edmondson@manchester.ac.uk</i>
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+the+American+Chemical+Society%22">Journal of the American Chemical Society</searchLink>. 7/27/2016, Vol. 138 Issue 29, p9009-9012. 4p.
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  Data: <searchLink fieldCode="DE" term="%22Polymers%22">Polymers</searchLink><br /><searchLink fieldCode="DE" term="%22Ink-jet+printers%22">Ink-jet printers</searchLink><br /><searchLink fieldCode="DE" term="%22Polyelectrolytes%22">Polyelectrolytes</searchLink><br /><searchLink fieldCode="DE" term="%22Homopolymerizations%22">Homopolymerizations</searchLink><br /><searchLink fieldCode="DE" term="%22Ionic+strength%22">Ionic strength</searchLink>
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  Data: Using an electrostatic-based super inkjet printer we report the high-resolution deposition of polyelectrolyte macroinitiators and subsequent polymer brush growth using SI-ARGET-ATRP. We go on to demonstrate for the first time a submicron patterning phenomenon through the addition of either a like charged polyelectrolyte homopolymer or through careful control of ionic strength. As a result patterning of polymer brushes down to ca. 300 nm is reported. We present a possible mechanistic model and consider how this may be applied to other polyelectrolyte-based systems as a general method for submicron patterning. [ABSTRACT FROM AUTHOR]
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  Data: <i>Copyright of Journal of the American Chemical Society is the property of American Chemical Society and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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      – SubjectFull: Polyelectrolytes
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              Text: 7/27/2016
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