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Evidence for Direct Transmetalation of AuIII-F with Boronic Acids.

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Title: Evidence for Direct Transmetalation of AuIII-F with Boronic Acids.
Authors: Kumar, Roopender1, Linden, Anthony1, Nevado, Cristina1
Source: Journal of the American Chemical Society. 10/26/2016, Vol. 138 Issue 42, p13790-13793. 4p. 1 Chart.
Subjects: Organometallic chemistry, Boronic acids, Bond formation mechanism, Suzuki reaction, Chemical reagents
Abstract: The underlying reactivity of AuIII–F species with aryl boronic acids has been studied in detail taking advantage of four novel, stable difluoro-[(C^N)AuF2], arylmonofluoro-[(C^N)AuArF], and alkylmonofluoro-[(C^N)AuAlkF] gold(III) complexes, prepared and isolated in monomeric form. We provide the first experimental evidence for a direct AuIII–F/B transmetalation preceding the Csp2–Csp2 or Csp3–Csp2 bond formation. [ABSTRACT FROM AUTHOR]
Copyright of Journal of the American Chemical Society is the property of American Chemical Society and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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DbLabel: Engineering Source
An: 119438432
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
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  Label: Title
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  Data: Evidence for Direct Transmetalation of Au<superscript>III</superscript>-F with Boronic Acids.
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  Data: <searchLink fieldCode="AR" term="%22Kumar%2C+Roopender%22">Kumar, Roopender</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Linden%2C+Anthony%22">Linden, Anthony</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Nevado%2C+Cristina%22">Nevado, Cristina</searchLink><relatesTo>1</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+the+American+Chemical+Society%22">Journal of the American Chemical Society</searchLink>. 10/26/2016, Vol. 138 Issue 42, p13790-13793. 4p. 1 Chart.
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  Data: <searchLink fieldCode="DE" term="%22Organometallic+chemistry%22">Organometallic chemistry</searchLink><br /><searchLink fieldCode="DE" term="%22Boronic+acids%22">Boronic acids</searchLink><br /><searchLink fieldCode="DE" term="%22Bond+formation+mechanism%22">Bond formation mechanism</searchLink><br /><searchLink fieldCode="DE" term="%22Suzuki+reaction%22">Suzuki reaction</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+reagents%22">Chemical reagents</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: The underlying reactivity of AuIII–F species with aryl boronic acids has been studied in detail taking advantage of four novel, stable difluoro-[(C^N)AuF2], arylmonofluoro-[(C^N)AuArF], and alkylmonofluoro-[(C^N)AuAlkF] gold(III) complexes, prepared and isolated in monomeric form. We provide the first experimental evidence for a direct AuIII–F/B transmetalation preceding the Csp2–Csp2 or Csp3–Csp2 bond formation. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of the American Chemical Society is the property of American Chemical Society and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1021/jacs.6b07763
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      – Code: eng
        Text: English
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        PageCount: 4
        StartPage: 13790
    Subjects:
      – SubjectFull: Organometallic chemistry
        Type: general
      – SubjectFull: Boronic acids
        Type: general
      – SubjectFull: Bond formation mechanism
        Type: general
      – SubjectFull: Suzuki reaction
        Type: general
      – SubjectFull: Chemical reagents
        Type: general
    Titles:
      – TitleFull: Evidence for Direct Transmetalation of AuIII-F with Boronic Acids.
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            NameFull: Kumar, Roopender
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            NameFull: Linden, Anthony
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            NameFull: Nevado, Cristina
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            – D: 26
              M: 10
              Text: 10/26/2016
              Type: published
              Y: 2016
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              Value: 138
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              Value: 42
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            – TitleFull: Journal of the American Chemical Society
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