Bibliographic Details
| Title: |
Template effect using aroylhydrazone ligand: Synthesis, crystal structure and magnetic properties of a novel ferromagnetically coupled heptanuclear nickel(II) cluster with a vertex-shared dicubane structure. |
| Authors: |
Mameri, Samir1 mameri@unistra.fr |
| Source: |
Inorganica Chimica Acta. Jan2017 Part 1, Vol. 455, p231-234. 4p. |
| Subjects: |
Hydrazones, Magnetic properties of metals, Crystal structure, Nickel compounds, Coordinate covalent bond, Ligands (Chemistry) |
| Abstract: |
The reaction of aroylhydrazone ligand H 2 L with Ni(II) metal ions afforded, upon crystallization under aerobic conditions, a novel heptanuclear Ni(II) cluster without this ligand (template effect of aroylhydrazone ligand). The heptanuclear [Ni II 7 ] compound 1 displays a metallic core which can be presented as a vertex-shared dicubane structure. Noteworthy, (i) this ligand is used for the first time in coordination chemistry, and (ii) this cluster does represent the first example in Nickel chemistry that possesses this topology with a structure not supported by any organic bridging ligand. [ABSTRACT FROM AUTHOR] |
|
Copyright of Inorganica Chimica Acta is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) |
| Database: |
Engineering Source |
