Peculiarities of near-electrode relaxation processes in the polyethylene melt filled with graphite and carbon black.

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Title: Peculiarities of near-electrode relaxation processes in the polyethylene melt filled with graphite and carbon black.
Authors: Kuryptya, Ya. A.1, Savchenko, B. M.1, Kovalchuk, O. V.1, Kovalchuk, T. M.2 akoval@knutd.com.ua, Shostak, T. S.2
Source: Semiconductor Physics, Quantum Electronics & Optoelectronics. 2016, Vol. 19 Issue 3, p290-294. 5p.
Subjects: Oscilloscopes, Electric measurement instruments, Polyethylene synthesis, Ethylene synthesis, Carbon-black
Abstract: By using the oscilloscope method within the frequency range 10 to 106 Hz at the temperature 492.1 K and pressure 11.31 MPa at the output of the single-screw extruder, the dielectric properties of the composite melt – linear low-density polyethylene + 20 wt.% of graphite + 10 wt.% of carbon black – have been investigated. It has been shown that in the whole frequency range, near-electrode processes significantly effect on charge transfer. For the frequencies less than 100 Hz, in the near-electrode area the conductance is provided with hopping movement of electrons. For the frequencies over 100 Hz, charge transfer occurs through the ion movement. It has been shown that the transfer of ions in the near-electrode area can be described using the relaxation process that, unlike the vast majority of processes described in the publications, meets the well-known relations only in terms of the complex conductivity. It has been shown that, in the terms of the complex conductivity, this relaxation process can be approximated with Debye equation, as well as it has been estimated the relaxation time (8.5 ms) for this process. According to the parameters included in the Debye equation, it has been estimated the thickness of the near-electrode area (17 μm) and shown that it practically coincides with the sizes of graphite particles. [ABSTRACT FROM AUTHOR]
Copyright of Semiconductor Physics, Quantum Electronics & Optoelectronics is the property of V. Lashkaryov Institute of Semiconductor Physics and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Peculiarities of near-electrode relaxation processes in the polyethylene melt filled with graphite and carbon black.
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  Data: <searchLink fieldCode="JN" term="%22Semiconductor+Physics%2C+Quantum+Electronics+%26+Optoelectronics%22">Semiconductor Physics, Quantum Electronics & Optoelectronics</searchLink>. 2016, Vol. 19 Issue 3, p290-294. 5p.
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  Data: <searchLink fieldCode="DE" term="%22Oscilloscopes%22">Oscilloscopes</searchLink><br /><searchLink fieldCode="DE" term="%22Electric+measurement+instruments%22">Electric measurement instruments</searchLink><br /><searchLink fieldCode="DE" term="%22Polyethylene+synthesis%22">Polyethylene synthesis</searchLink><br /><searchLink fieldCode="DE" term="%22Ethylene+synthesis%22">Ethylene synthesis</searchLink><br /><searchLink fieldCode="DE" term="%22Carbon-black%22">Carbon-black</searchLink>
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  Data: By using the oscilloscope method within the frequency range 10 to 106 Hz at the temperature 492.1 K and pressure 11.31 MPa at the output of the single-screw extruder, the dielectric properties of the composite melt – linear low-density polyethylene + 20 wt.% of graphite + 10 wt.% of carbon black – have been investigated. It has been shown that in the whole frequency range, near-electrode processes significantly effect on charge transfer. For the frequencies less than 100 Hz, in the near-electrode area the conductance is provided with hopping movement of electrons. For the frequencies over 100 Hz, charge transfer occurs through the ion movement. It has been shown that the transfer of ions in the near-electrode area can be described using the relaxation process that, unlike the vast majority of processes described in the publications, meets the well-known relations only in terms of the complex conductivity. It has been shown that, in the terms of the complex conductivity, this relaxation process can be approximated with Debye equation, as well as it has been estimated the relaxation time (8.5 ms) for this process. According to the parameters included in the Debye equation, it has been estimated the thickness of the near-electrode area (17 μm) and shown that it practically coincides with the sizes of graphite particles. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Semiconductor Physics, Quantum Electronics & Optoelectronics is the property of V. Lashkaryov Institute of Semiconductor Physics and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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        Value: 10.15407/spqeo19.03.290
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      – Code: eng
        Text: English
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        PageCount: 5
        StartPage: 290
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      – SubjectFull: Oscilloscopes
        Type: general
      – SubjectFull: Electric measurement instruments
        Type: general
      – SubjectFull: Polyethylene synthesis
        Type: general
      – SubjectFull: Ethylene synthesis
        Type: general
      – SubjectFull: Carbon-black
        Type: general
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      – TitleFull: Peculiarities of near-electrode relaxation processes in the polyethylene melt filled with graphite and carbon black.
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              Text: 2016
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