Strategies for electrosynthesis of poly(vinylbenzyltrimethylammonium chloride) and composite films.

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Title: Strategies for electrosynthesis of poly(vinylbenzyltrimethylammonium chloride) and composite films.
Authors: Zhang, Tianshi1 (AUTHOR) zhangt9@mcmaster.ca, Zhitomirsky, Igor1 (AUTHOR)
Source: Materials & Manufacturing Processes. 2017, Vol. 32 Issue 4, p404-408. 5p.
Subjects: Electrosynthesis, Ammonium chloride, Composite materials, Zirconium oxide, Electroforming, Polyelectrolytes
Abstract: Poly(vinylbenzyl trimethyl ammonium chloride) (PVT) exhibits functional properties, which have generated interest in the fabrication of PVT and composite films. New electrochemical strategies have been utilized for the deposition of PVT-zirconia composites. The problems, related to the electrodeposition of strong polyelectrolytes, such as PVT, were addressed by the development of charge compensation mechanisms. The deposition strategies involved electrophoretic cathodic deposition (EPD) of PVT and EPD or electrochemical synthesis of zirconia. The proof of concept investigations involved deposition yield studies under different conditions, Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), differential thermal analysis (DTA), and electron microscopy studies. The electrochemical strategies can be used for electrodeposition of various composites, utilizing the properties of functional polymers and inorganic materials. [ABSTRACT FROM PUBLISHER]
Copyright of Materials & Manufacturing Processes is the property of Taylor & Francis Ltd and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Label: Title
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  Data: Strategies for electrosynthesis of poly(vinylbenzyltrimethylammonium chloride) and composite films.
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  Data: <searchLink fieldCode="AR" term="%22Zhang%2C+Tianshi%22">Zhang, Tianshi</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> zhangt9@mcmaster.ca</i><br /><searchLink fieldCode="AR" term="%22Zhitomirsky%2C+Igor%22">Zhitomirsky, Igor</searchLink><relatesTo>1</relatesTo> (AUTHOR)
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  Data: <searchLink fieldCode="JN" term="%22Materials+%26+Manufacturing+Processes%22">Materials & Manufacturing Processes</searchLink>. 2017, Vol. 32 Issue 4, p404-408. 5p.
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  Data: <searchLink fieldCode="DE" term="%22Electrosynthesis%22">Electrosynthesis</searchLink><br /><searchLink fieldCode="DE" term="%22Ammonium+chloride%22">Ammonium chloride</searchLink><br /><searchLink fieldCode="DE" term="%22Composite+materials%22">Composite materials</searchLink><br /><searchLink fieldCode="DE" term="%22Zirconium+oxide%22">Zirconium oxide</searchLink><br /><searchLink fieldCode="DE" term="%22Electroforming%22">Electroforming</searchLink><br /><searchLink fieldCode="DE" term="%22Polyelectrolytes%22">Polyelectrolytes</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Poly(vinylbenzyl trimethyl ammonium chloride) (PVT) exhibits functional properties, which have generated interest in the fabrication of PVT and composite films. New electrochemical strategies have been utilized for the deposition of PVT-zirconia composites. The problems, related to the electrodeposition of strong polyelectrolytes, such as PVT, were addressed by the development of charge compensation mechanisms. The deposition strategies involved electrophoretic cathodic deposition (EPD) of PVT and EPD or electrochemical synthesis of zirconia. The proof of concept investigations involved deposition yield studies under different conditions, Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), differential thermal analysis (DTA), and electron microscopy studies. The electrochemical strategies can be used for electrodeposition of various composites, utilizing the properties of functional polymers and inorganic materials. [ABSTRACT FROM PUBLISHER]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Materials & Manufacturing Processes is the property of Taylor & Francis Ltd and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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    Identifiers:
      – Type: doi
        Value: 10.1080/10426914.2016.1176192
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      – Code: eng
        Text: English
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        PageCount: 5
        StartPage: 404
    Subjects:
      – SubjectFull: Electrosynthesis
        Type: general
      – SubjectFull: Ammonium chloride
        Type: general
      – SubjectFull: Composite materials
        Type: general
      – SubjectFull: Zirconium oxide
        Type: general
      – SubjectFull: Electroforming
        Type: general
      – SubjectFull: Polyelectrolytes
        Type: general
    Titles:
      – TitleFull: Strategies for electrosynthesis of poly(vinylbenzyltrimethylammonium chloride) and composite films.
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            NameFull: Zhang, Tianshi
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            NameFull: Zhitomirsky, Igor
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              M: 04
              Text: 2017
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