PMMA-titania floating macrospheres for the photocatalytic remediation of agro-pharmaceutical wastewater.

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Title: PMMA-titania floating macrospheres for the photocatalytic remediation of agro-pharmaceutical wastewater.
Authors: Hartley, Adam C.1, Moss, Joseph B.1, Keesling Jr., Kyle J.1, Moore, Nathanael J.1, Glover, Justin D.1, Boyd, Joel E.1 boyd@erskine.edu
Source: Water Science & Technology. 2017, Vol. 75 Issue 6, p1362-1369. 8p.
Subjects: Titanium dioxide, Floating (Fluid mechanics), Photocatalytic water purification, Tetracycline, Methyl methacrylate
Abstract: Antibiotics such as tetracycline are used on a large scale in agriculture, and can become concentrated in wastewater lagoons that are used in conjunction with confined animal feeding operations. Solar-illuminated titanium dioxide can be used to photocatalytically degrade aqueous tetracycline, but its application in a lagoon environment requires that the photocatalyst be supported on a macroscopic support material to prevent loss of the nanoscale photocatalyst into the environment. In this work, titanium dioxide was deposited within a porous poly(methyl methacrylate) film on the surface of floating 7.0 cm diameter acrylic spheres. Six of these floating spheres removed over 96% of the tetracycline in 3.5 L of 60 mg/L tetracycline in natural pond water during 24 hours of solar illumination. The durability of these spheres under long-term solar exposure was also investigated along with the amount of photocatalyst lost from the sphere surface during use. These macroscale floating composite spheres provide a new method for removing tetracycline from wastewater lagoons with minimal risk of being displaced in the environment due to the large size of the spheres. [ABSTRACT FROM AUTHOR]
Copyright of Water Science & Technology is the property of IWA Publishing and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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DbLabel: Engineering Source
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  Data: PMMA-titania floating macrospheres for the photocatalytic remediation of agro-pharmaceutical wastewater.
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  Data: <searchLink fieldCode="AR" term="%22Hartley%2C+Adam+C%2E%22">Hartley, Adam C.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Moss%2C+Joseph+B%2E%22">Moss, Joseph B.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Keesling+Jr%2E%2C+Kyle+J%2E%22">Keesling Jr., Kyle J.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Moore%2C+Nathanael+J%2E%22">Moore, Nathanael J.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Glover%2C+Justin+D%2E%22">Glover, Justin D.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Boyd%2C+Joel+E%2E%22">Boyd, Joel E.</searchLink><relatesTo>1</relatesTo><i> boyd@erskine.edu</i>
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  Data: <searchLink fieldCode="JN" term="%22Water+Science+%26+Technology%22">Water Science & Technology</searchLink>. 2017, Vol. 75 Issue 6, p1362-1369. 8p.
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  Data: <searchLink fieldCode="DE" term="%22Titanium+dioxide%22">Titanium dioxide</searchLink><br /><searchLink fieldCode="DE" term="%22Floating+%28Fluid+mechanics%29%22">Floating (Fluid mechanics)</searchLink><br /><searchLink fieldCode="DE" term="%22Photocatalytic+water+purification%22">Photocatalytic water purification</searchLink><br /><searchLink fieldCode="DE" term="%22Tetracycline%22">Tetracycline</searchLink><br /><searchLink fieldCode="DE" term="%22Methyl+methacrylate%22">Methyl methacrylate</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Antibiotics such as tetracycline are used on a large scale in agriculture, and can become concentrated in wastewater lagoons that are used in conjunction with confined animal feeding operations. Solar-illuminated titanium dioxide can be used to photocatalytically degrade aqueous tetracycline, but its application in a lagoon environment requires that the photocatalyst be supported on a macroscopic support material to prevent loss of the nanoscale photocatalyst into the environment. In this work, titanium dioxide was deposited within a porous poly(methyl methacrylate) film on the surface of floating 7.0 cm diameter acrylic spheres. Six of these floating spheres removed over 96% of the tetracycline in 3.5 L of 60 mg/L tetracycline in natural pond water during 24 hours of solar illumination. The durability of these spheres under long-term solar exposure was also investigated along with the amount of photocatalyst lost from the sphere surface during use. These macroscale floating composite spheres provide a new method for removing tetracycline from wastewater lagoons with minimal risk of being displaced in the environment due to the large size of the spheres. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
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  Data: <i>Copyright of Water Science & Technology is the property of IWA Publishing and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.2166/wst.2017.003
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      – Code: eng
        Text: English
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        PageCount: 8
        StartPage: 1362
    Subjects:
      – SubjectFull: Titanium dioxide
        Type: general
      – SubjectFull: Floating (Fluid mechanics)
        Type: general
      – SubjectFull: Photocatalytic water purification
        Type: general
      – SubjectFull: Tetracycline
        Type: general
      – SubjectFull: Methyl methacrylate
        Type: general
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      – TitleFull: PMMA-titania floating macrospheres for the photocatalytic remediation of agro-pharmaceutical wastewater.
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            NameFull: Hartley, Adam C.
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            NameFull: Moss, Joseph B.
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            NameFull: Keesling Jr., Kyle J.
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            NameFull: Moore, Nathanael J.
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            NameFull: Glover, Justin D.
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              Text: 2017
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