Synthesis of fluorinated oxazoles by oxidative cyclization of fluorinated enamides.
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| Title: | Synthesis of fluorinated oxazoles by oxidative cyclization of fluorinated enamides. |
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| Authors: | Shishlyk, Oleg S.1, Shcherbatiuk, Andrey V.1, Iminov, Rustam T.1, Tverdokhlebov, Anton V.1 a.tverdohlebov@mail.enamine.net, Tolmachev, Andrey A.1,2, Mykhailiuk, Pavel K.1,2 Pavel.Mykhailiuk@gmail.com, Biitseva, Angelina V.2 |
| Source: | Journal of Fluorine Chemistry. Apr2017, Vol. 196, p88-97. 10p. |
| Subjects: | Fluoroalkyl compounds, Oxazoles, Oxidation, Trifluoromethyl compounds, Acylation |
| Abstract: | Novel approach to CF 3 -/CHF 2 -oxazoles was developed. The key reaction was oxidation of fluoroalkyl enamides with PhI(RCO 2 ) 2 . [ABSTRACT FROM AUTHOR] |
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| Database: | Engineering Source |
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