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Manganese(II) and cobalt(II) coordination polymers with m-phenylenediacrylate: Synthesis, structures, and magnetic properties.

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Title: Manganese(II) and cobalt(II) coordination polymers with m-phenylenediacrylate: Synthesis, structures, and magnetic properties.
Authors: Sun, Qian1 xsun@chem.ecnu.edu.cn, Lin, Li-hua1, Zhang, Jie1, Gao, En-Qing1
Source: Inorganica Chimica Acta. Jun2017, Vol. 462, p106-111. 6p.
Subjects: Manganese, Cobalt, Coordination polymers synthesis, Hydrothermal synthesis, Isomorphous structures, Antiferromagnetism, Carboxylates
Abstract: Three coordination polymers based on m-phenylenediacrylic acid (H 2 mpda) with manganese(II) and cobalt(II), [Mn(Hmpda) 2 (H 2 O) 2 ] n ( 1 ), Co(Hmpda) 2 (H 2 O) 2 ] n ( 2 ), [Co(mpda)(H 2 O) 2 ] ( 3 ) were synthesized by the hydrothermal methods and their structures and magnetic properties were fully characterized. Compounds 1 and 2 are isomorphous coordination compounds in which carboxylate-bridged square-grid 2D sheets are separated by bilayers of Hmpda − . While compound 3 is composed of 1D coordination chains based on binuclear units with double carboxylate bridges. Magnetic investigations on the compounds have been carried out and revealed weak antiferromagnetic exchange mediated through the carboxylate bridges. [ABSTRACT FROM AUTHOR]
Copyright of Inorganica Chimica Acta is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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DbLabel: Engineering Source
An: 122699197
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PubTypeId: academicJournal
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  Label: Title
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  Data: Manganese(II) and cobalt(II) coordination polymers with m-phenylenediacrylate: Synthesis, structures, and magnetic properties.
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  Data: <searchLink fieldCode="AR" term="%22Sun%2C+Qian%22">Sun, Qian</searchLink><relatesTo>1</relatesTo><i> xsun@chem.ecnu.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Lin%2C+Li-hua%22">Lin, Li-hua</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Zhang%2C+Jie%22">Zhang, Jie</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Gao%2C+En-Qing%22">Gao, En-Qing</searchLink><relatesTo>1</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Inorganica+Chimica+Acta%22">Inorganica Chimica Acta</searchLink>. Jun2017, Vol. 462, p106-111. 6p.
– Name: Subject
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  Data: <searchLink fieldCode="DE" term="%22Manganese%22">Manganese</searchLink><br /><searchLink fieldCode="DE" term="%22Cobalt%22">Cobalt</searchLink><br /><searchLink fieldCode="DE" term="%22Coordination+polymers+synthesis%22">Coordination polymers synthesis</searchLink><br /><searchLink fieldCode="DE" term="%22Hydrothermal+synthesis%22">Hydrothermal synthesis</searchLink><br /><searchLink fieldCode="DE" term="%22Isomorphous+structures%22">Isomorphous structures</searchLink><br /><searchLink fieldCode="DE" term="%22Antiferromagnetism%22">Antiferromagnetism</searchLink><br /><searchLink fieldCode="DE" term="%22Carboxylates%22">Carboxylates</searchLink>
– Name: Abstract
  Label: Abstract
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  Data: Three coordination polymers based on m-phenylenediacrylic acid (H 2 mpda) with manganese(II) and cobalt(II), [Mn(Hmpda) 2 (H 2 O) 2 ] n ( 1 ), Co(Hmpda) 2 (H 2 O) 2 ] n ( 2 ), [Co(mpda)(H 2 O) 2 ] ( 3 ) were synthesized by the hydrothermal methods and their structures and magnetic properties were fully characterized. Compounds 1 and 2 are isomorphous coordination compounds in which carboxylate-bridged square-grid 2D sheets are separated by bilayers of Hmpda − . While compound 3 is composed of 1D coordination chains based on binuclear units with double carboxylate bridges. Magnetic investigations on the compounds have been carried out and revealed weak antiferromagnetic exchange mediated through the carboxylate bridges. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Inorganica Chimica Acta is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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      – Type: doi
        Value: 10.1016/j.ica.2017.03.023
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      – Code: eng
        Text: English
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        PageCount: 6
        StartPage: 106
    Subjects:
      – SubjectFull: Manganese
        Type: general
      – SubjectFull: Cobalt
        Type: general
      – SubjectFull: Coordination polymers synthesis
        Type: general
      – SubjectFull: Hydrothermal synthesis
        Type: general
      – SubjectFull: Isomorphous structures
        Type: general
      – SubjectFull: Antiferromagnetism
        Type: general
      – SubjectFull: Carboxylates
        Type: general
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      – TitleFull: Manganese(II) and cobalt(II) coordination polymers with m-phenylenediacrylate: Synthesis, structures, and magnetic properties.
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            NameFull: Sun, Qian
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            NameFull: Lin, Li-hua
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            NameFull: Zhang, Jie
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              Text: Jun2017
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