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Copolymerization of alpha-methyl styrene with butyl acrylate in bulk.

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Title: Copolymerization of alpha-methyl styrene with butyl acrylate in bulk.
Authors: McManus, N.T.1, Penlidis, A.1 penlidis@cape.uwaterloo.ca, Dube, M.A.2
Source: Polymer. Mar2002, Vol. 43 Issue 5, p1607-1614. 8p.
Subjects: Copolymerization, Alpha-methylstyrol, Reactivity (Chemistry), Monomers, Molecular weights
Abstract: The kinetics of the copolymerization of alpha-methyl styrene (AMS) and butyl acrylate (BA) have been studied for the first time. Reactivity ratios for the system have been assessed over a range of temperatures (60–140 °C). Copolymerization models that account for monomer depropagation have been considered in order to determine the importance of depropagation effects for the chosen set of reaction conditions. Full conversion range experiments have been carried out to assess the effects of feed composition, temperature and initiator concentration on polymerization kinetics. [ABSTRACT FROM AUTHOR]
Copyright of Polymer is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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Header DbId: egs
DbLabel: Engineering Source
An: 122777008
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
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  Data: Copolymerization of alpha-methyl styrene with butyl acrylate in bulk.
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  Data: <searchLink fieldCode="AR" term="%22McManus%2C+N%2ET%2E%22">McManus, N.T.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Penlidis%2C+A%2E%22">Penlidis, A.</searchLink><relatesTo>1</relatesTo><i> penlidis@cape.uwaterloo.ca</i><br /><searchLink fieldCode="AR" term="%22Dube%2C+M%2EA%2E%22">Dube, M.A.</searchLink><relatesTo>2</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Polymer%22">Polymer</searchLink>. Mar2002, Vol. 43 Issue 5, p1607-1614. 8p.
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  Data: <searchLink fieldCode="DE" term="%22Copolymerization%22">Copolymerization</searchLink><br /><searchLink fieldCode="DE" term="%22Alpha-methylstyrol%22">Alpha-methylstyrol</searchLink><br /><searchLink fieldCode="DE" term="%22Reactivity+%28Chemistry%29%22">Reactivity (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Monomers%22">Monomers</searchLink><br /><searchLink fieldCode="DE" term="%22Molecular+weights%22">Molecular weights</searchLink>
– Name: Abstract
  Label: Abstract
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  Data: The kinetics of the copolymerization of alpha-methyl styrene (AMS) and butyl acrylate (BA) have been studied for the first time. Reactivity ratios for the system have been assessed over a range of temperatures (60–140 °C). Copolymerization models that account for monomer depropagation have been considered in order to determine the importance of depropagation effects for the chosen set of reaction conditions. Full conversion range experiments have been carried out to assess the effects of feed composition, temperature and initiator concentration on polymerization kinetics. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
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  Data: <i>Copyright of Polymer is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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      – Type: doi
        Value: 10.1016/S0032-3861(01)00738-8
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      – Code: eng
        Text: English
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        PageCount: 8
        StartPage: 1607
    Subjects:
      – SubjectFull: Copolymerization
        Type: general
      – SubjectFull: Alpha-methylstyrol
        Type: general
      – SubjectFull: Reactivity (Chemistry)
        Type: general
      – SubjectFull: Monomers
        Type: general
      – SubjectFull: Molecular weights
        Type: general
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      – TitleFull: Copolymerization of alpha-methyl styrene with butyl acrylate in bulk.
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            NameFull: Penlidis, A.
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              Text: Mar2002
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              Y: 2002
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              Value: 43
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