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Design and Synthesis of Ʌ-Shaped Photoswitchable Compounds Employing Tröger’s Base Scaffold.

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Title: Design and Synthesis of Ʌ-Shaped Photoswitchable Compounds Employing Tröger’s Base Scaffold.
Authors: Kazem-Rostami, Masoud1 masoud.kazem-rostami@hdr.mq.edu.au
Source: Synthesis. 2017, Vol. 49 Issue 6, p1214-1222. 9p. 5 Diagrams, 2 Charts, 2 Graphs.
Subjects: Azo compounds, Diazotization, Molecular machinery (Technology), Machine design, Alkylation
Abstract: The production of azo derivatives of a di-amino analogue of Tröger’s base (Hünlich base), by employing the standard procedures of diazotization, azo-coupling and Williamson etherification is described here. These versatile molecules possess a Λ-shaped core, photoswitchable groups and some carry two modifiable extremities to enable further synthesis or molecular assembly. The synthesis is straightforward and requires inexpensive starting materials, which facilitates their application to different fields of research such as light-driven molecular machine design. [ABSTRACT FROM AUTHOR]
Copyright of Synthesis is the property of Georg Thieme Verlag Stuttgart and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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  Availability: 0
Header DbId: egs
DbLabel: Engineering Source
An: 123014213
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
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  Data: Design and Synthesis of Ʌ-Shaped Photoswitchable Compounds Employing Tröger’s Base Scaffold.
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  Data: <searchLink fieldCode="AR" term="%22Kazem-Rostami%2C+Masoud%22">Kazem-Rostami, Masoud</searchLink><relatesTo>1</relatesTo><i> masoud.kazem-rostami@hdr.mq.edu.au</i>
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  Data: <searchLink fieldCode="JN" term="%22Synthesis%22">Synthesis</searchLink>. 2017, Vol. 49 Issue 6, p1214-1222. 9p. 5 Diagrams, 2 Charts, 2 Graphs.
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  Data: <searchLink fieldCode="DE" term="%22Azo+compounds%22">Azo compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Diazotization%22">Diazotization</searchLink><br /><searchLink fieldCode="DE" term="%22Molecular+machinery+%28Technology%29%22">Molecular machinery (Technology)</searchLink><br /><searchLink fieldCode="DE" term="%22Machine+design%22">Machine design</searchLink><br /><searchLink fieldCode="DE" term="%22Alkylation%22">Alkylation</searchLink>
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  Label: Abstract
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  Data: The production of azo derivatives of a di-amino analogue of Tröger’s base (Hünlich base), by employing the standard procedures of diazotization, azo-coupling and Williamson etherification is described here. These versatile molecules possess a Λ-shaped core, photoswitchable groups and some carry two modifiable extremities to enable further synthesis or molecular assembly. The synthesis is straightforward and requires inexpensive starting materials, which facilitates their application to different fields of research such as light-driven molecular machine design. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Synthesis is the property of Georg Thieme Verlag Stuttgart and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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    Identifiers:
      – Type: doi
        Value: 10.1055/s-0036-1588913
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 9
        StartPage: 1214
    Subjects:
      – SubjectFull: Azo compounds
        Type: general
      – SubjectFull: Diazotization
        Type: general
      – SubjectFull: Molecular machinery (Technology)
        Type: general
      – SubjectFull: Machine design
        Type: general
      – SubjectFull: Alkylation
        Type: general
    Titles:
      – TitleFull: Design and Synthesis of Ʌ-Shaped Photoswitchable Compounds Employing Tröger’s Base Scaffold.
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            NameFull: Kazem-Rostami, Masoud
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            – D: 15
              M: 03
              Text: 2017
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              Y: 2017
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              Value: 49
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            – TitleFull: Synthesis
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