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Cocrystal of the [MnIV(C2H7N5)3]4+ ion and biguanidium: a double hydrogen-bond interaction with guanidinium-recognizing anions.

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Bibliographic Details
Title: Cocrystal of the [MnIV(C2H7N5)3]4+ ion and biguanidium: a double hydrogen-bond interaction with guanidinium-recognizing anions.
Authors: Li-Ping Lu1, Miao-Li Zhu, Helen1 miaoli@sxu.edu.cn, Pin Yang1 yangpin@sxu.edu.cn
Source: Acta Crystallographica: Section C (Wiley-Blackwell). Jan2004, Vol. 60 Issue 1, pM18-M20. 3p. 2 Diagrams, 2 Charts.
Subjects: Hydrogen bonding, Cations, Biguanide, Nitrates
Abstract: Examines the double hydrogen-bond interaction with guanidinium-bond interaction with guanidinium-recognizing anions of cocrystal of the [MnIV(C2H7N5)3]4+ ion and biguanidium. Existence of moieties as divalent cations and as neutral molecules; Interaction between biguanide and nitrate groups; Proposition of molecular recognition mode of anionic entities.
Database: Engineering Source
Description
Abstract:Examines the double hydrogen-bond interaction with guanidinium-bond interaction with guanidinium-recognizing anions of cocrystal of the [MnIV(C2H7N5)3]4+ ion and biguanidium. Existence of moieties as divalent cations and as neutral molecules; Interaction between biguanide and nitrate groups; Proposition of molecular recognition mode of anionic entities.
ISSN:01082701
DOI:10.1107/S0108270103024892