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Rhodium-Catalysed Hydroboration of Terminal Alkynes Using Pinacolborane Promoted by Tri(2-furyl)phosphine.

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Title: Rhodium-Catalysed Hydroboration of Terminal Alkynes Using Pinacolborane Promoted by Tri(2-furyl)phosphine.
Authors: Kongchen Wang1, Bates, Roderick W.1 roderick@ntu.edu.sg
Source: Synthesis. 2017, Vol. 49 Issue 12, p2749-2752. 4p.
Subjects: Phosphine, Alkynes, Hydroboration, Boronic esters, Catalysis
Abstract: Tri(2-furyl)phosphine is a superior ligand to triphenylphosphine in the rhodium-catalysed hydroboration of alkynes with pinacolborane to yield alkenylboronates. In general the reactions are faster and the products are cleaner. [ABSTRACT FROM AUTHOR]
Copyright of Synthesis is the property of Georg Thieme Verlag Stuttgart and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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  Availability: 0
Header DbId: egs
DbLabel: Engineering Source
An: 123380034
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
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  Data: Rhodium-Catalysed Hydroboration of Terminal Alkynes Using Pinacolborane Promoted by Tri(2-furyl)phosphine.
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  Data: <searchLink fieldCode="AR" term="%22Kongchen+Wang%22">Kongchen Wang</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Bates%2C+Roderick+W%2E%22">Bates, Roderick W.</searchLink><relatesTo>1</relatesTo><i> roderick@ntu.edu.sg</i>
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  Data: <searchLink fieldCode="JN" term="%22Synthesis%22">Synthesis</searchLink>. 2017, Vol. 49 Issue 12, p2749-2752. 4p.
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  Data: <searchLink fieldCode="DE" term="%22Phosphine%22">Phosphine</searchLink><br /><searchLink fieldCode="DE" term="%22Alkynes%22">Alkynes</searchLink><br /><searchLink fieldCode="DE" term="%22Hydroboration%22">Hydroboration</searchLink><br /><searchLink fieldCode="DE" term="%22Boronic+esters%22">Boronic esters</searchLink><br /><searchLink fieldCode="DE" term="%22Catalysis%22">Catalysis</searchLink>
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  Label: Abstract
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  Data: Tri(2-furyl)phosphine is a superior ligand to triphenylphosphine in the rhodium-catalysed hydroboration of alkynes with pinacolborane to yield alkenylboronates. In general the reactions are faster and the products are cleaner. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
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  Group: Ab
  Data: <i>Copyright of Synthesis is the property of Georg Thieme Verlag Stuttgart and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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    Identifiers:
      – Type: doi
        Value: 10.1055/s-0036-1588977
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 4
        StartPage: 2749
    Subjects:
      – SubjectFull: Phosphine
        Type: general
      – SubjectFull: Alkynes
        Type: general
      – SubjectFull: Hydroboration
        Type: general
      – SubjectFull: Boronic esters
        Type: general
      – SubjectFull: Catalysis
        Type: general
    Titles:
      – TitleFull: Rhodium-Catalysed Hydroboration of Terminal Alkynes Using Pinacolborane Promoted by Tri(2-furyl)phosphine.
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      – PersonEntity:
          Name:
            NameFull: Kongchen Wang
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          Name:
            NameFull: Bates, Roderick W.
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            – D: 15
              M: 06
              Text: 2017
              Type: published
              Y: 2017
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              Value: 00397881
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              Value: 49
            – Type: issue
              Value: 12
          Titles:
            – TitleFull: Synthesis
              Type: main
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