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Electrochemistry of Secondary Amine Substituted 2,5-di(2-thienyl)pyrrole Derivative and Its Copolymer.

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Title: Electrochemistry of Secondary Amine Substituted 2,5-di(2-thienyl)pyrrole Derivative and Its Copolymer.
Authors: Gumusay, Ogun1, Soganci, Tugba1, Soyleyici, Hakan Can2, Ak, Metin1 metinak@pau.edu.tr, Cetisli, Halil1
Source: Journal of The Electrochemical Society. 2017, Vol. 164 Issue 7, pH421-H429. 9p.
Subjects: Conducting polymers testing, Monomers, Copolymerization
Abstract: Since the discovery of conductive polymers, one of the most promising innovations in the field of polymer chemistry, these materials have been used in many practical applications. However, new monomers are being designed to overcome some of the disadvantages of conductive polymers, such as their inherent stability, low optical and electrical properties. It is known that minor arrangement on the monomer structure lead to very large changes in the polymer properties. In this study, a thienyl pyrrole monomer, one of the most studied monomers in the field of conductive polymers, has been produced using hydrazine derivatives instead of amines. For this purpose, the model monomer, N-phenyl-2,5-di(thiophen-2-yl)-1H-pyrrol-1-amine, was synthesized and the optical, electrochemical and electrochromic properties of its conductive polymer were investigated. Furthermore, copolymer studies with 3,4-ethylenedioxythiophene (EDOT) have been done to emphasize the importance of copolymerization on electrochromic properties of the conducting polymers. Effects of the feed ratio of the monomers and applied potential for copolymerization on optical and electrochemical properties of the electrochemically synthesized copolymers were investigated in detail. [ABSTRACT FROM AUTHOR]
Copyright of Journal of The Electrochemical Society is the property of IOP Publishing and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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DbLabel: Engineering Source
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  Data: Electrochemistry of Secondary Amine Substituted 2,5-di(2-thienyl)pyrrole Derivative and Its Copolymer.
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  Data: Since the discovery of conductive polymers, one of the most promising innovations in the field of polymer chemistry, these materials have been used in many practical applications. However, new monomers are being designed to overcome some of the disadvantages of conductive polymers, such as their inherent stability, low optical and electrical properties. It is known that minor arrangement on the monomer structure lead to very large changes in the polymer properties. In this study, a thienyl pyrrole monomer, one of the most studied monomers in the field of conductive polymers, has been produced using hydrazine derivatives instead of amines. For this purpose, the model monomer, N-phenyl-2,5-di(thiophen-2-yl)-1H-pyrrol-1-amine, was synthesized and the optical, electrochemical and electrochromic properties of its conductive polymer were investigated. Furthermore, copolymer studies with 3,4-ethylenedioxythiophene (EDOT) have been done to emphasize the importance of copolymerization on electrochromic properties of the conducting polymers. Effects of the feed ratio of the monomers and applied potential for copolymerization on optical and electrochemical properties of the electrochemically synthesized copolymers were investigated in detail. [ABSTRACT FROM AUTHOR]
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  Data: <i>Copyright of Journal of The Electrochemical Society is the property of IOP Publishing and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1149/2.0291707jes
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      – Code: eng
        Text: English
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        PageCount: 9
        StartPage: H421
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        Type: general
      – SubjectFull: Monomers
        Type: general
      – SubjectFull: Copolymerization
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      – TitleFull: Electrochemistry of Secondary Amine Substituted 2,5-di(2-thienyl)pyrrole Derivative and Its Copolymer.
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            NameFull: Soyleyici, Hakan Can
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            NameFull: Ak, Metin
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            NameFull: Cetisli, Halil
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              M: 06
              Text: 2017
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