Li2MoO4-based composite ceramics fabricated from temperature- and atmosphere-sensitive MnZn ferrite at room temperature.

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Title: Li2MoO4-based composite ceramics fabricated from temperature- and atmosphere-sensitive MnZn ferrite at room temperature.
Authors: Väätäjä, Maria1 maria.vaataja@oulu.fi, Kähäri, Hanna1, Juuti, Jari1, Jantunen, Heli1
Source: Journal of the American Ceramic Society. Aug2017, Vol. 100 Issue 8, p3626-3635. 10p. 1 Color Photograph, 1 Chart, 5 Graphs.
Subjects: Ferrite circulators, Circulators (Electrical engineering), Ferrite devices, Ceramics, Construction materials
Abstract: The first magnetic ceramic composites manufactured, using the room-temperature densification method are reported. The samples were prepared at room temperature using Li2MoO4 as a matrix and MnZn ferrite with loading levels of 10-30 vol-% followed by postprocessing at 120°C. The method utilizes the water solubility of the dielectric Li2MoO4 and compression pressure instead of high temperatures typical of conventional solid-state sintering. Hence, composite manufacturing using temperature- and atmosphere-sensitive materials is possible without special conditions. This was demonstrated with MnZn ferrite, which is prone to oxidation when heat treated in air. Samples manufactured with room-temperature densification showed no signs of reactivity during processing, whereas reference samples sintered at 685°C suffered from oxidation and formation of an additional reaction phase. The densities achieved with different loading levels of MnZn ferrite with both methods were very similar. Measurements up to 1 GHz showed relatively high values of relative permittivity (21.7 at 1 GHz) and permeability (2.6 at 1 GHz) with 30 vol-% loading of MnZn ferrite in the samples manufactured by room-temperature densification. In addition, pre-granulation is proposed to improve the processability of the composite powders in room-temperature densification. [ABSTRACT FROM AUTHOR]
Copyright of Journal of the American Ceramic Society is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Label: Title
  Group: Ti
  Data: Li<subscript>2</subscript>MoO<subscript>4</subscript>-based composite ceramics fabricated from temperature- and atmosphere-sensitive MnZn ferrite at room temperature.
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  Data: <searchLink fieldCode="AR" term="%22Väätäjä%2C+Maria%22">Väätäjä, Maria</searchLink><relatesTo>1</relatesTo><i> maria.vaataja@oulu.fi</i><br /><searchLink fieldCode="AR" term="%22Kähäri%2C+Hanna%22">Kähäri, Hanna</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Juuti%2C+Jari%22">Juuti, Jari</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Jantunen%2C+Heli%22">Jantunen, Heli</searchLink><relatesTo>1</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+the+American+Ceramic+Society%22">Journal of the American Ceramic Society</searchLink>. Aug2017, Vol. 100 Issue 8, p3626-3635. 10p. 1 Color Photograph, 1 Chart, 5 Graphs.
– Name: Subject
  Label: Subjects
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Ferrite+circulators%22">Ferrite circulators</searchLink><br /><searchLink fieldCode="DE" term="%22Circulators+%28Electrical+engineering%29%22">Circulators (Electrical engineering)</searchLink><br /><searchLink fieldCode="DE" term="%22Ferrite+devices%22">Ferrite devices</searchLink><br /><searchLink fieldCode="DE" term="%22Ceramics%22">Ceramics</searchLink><br /><searchLink fieldCode="DE" term="%22Construction+materials%22">Construction materials</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: The first magnetic ceramic composites manufactured, using the room-temperature densification method are reported. The samples were prepared at room temperature using Li2MoO4 as a matrix and MnZn ferrite with loading levels of 10-30 vol-% followed by postprocessing at 120°C. The method utilizes the water solubility of the dielectric Li2MoO4 and compression pressure instead of high temperatures typical of conventional solid-state sintering. Hence, composite manufacturing using temperature- and atmosphere-sensitive materials is possible without special conditions. This was demonstrated with MnZn ferrite, which is prone to oxidation when heat treated in air. Samples manufactured with room-temperature densification showed no signs of reactivity during processing, whereas reference samples sintered at 685°C suffered from oxidation and formation of an additional reaction phase. The densities achieved with different loading levels of MnZn ferrite with both methods were very similar. Measurements up to 1 GHz showed relatively high values of relative permittivity (21.7 at 1 GHz) and permeability (2.6 at 1 GHz) with 30 vol-% loading of MnZn ferrite in the samples manufactured by room-temperature densification. In addition, pre-granulation is proposed to improve the processability of the composite powders in room-temperature densification. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of the American Ceramic Society is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1111/jace.14914
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      – Code: eng
        Text: English
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        PageCount: 10
        StartPage: 3626
    Subjects:
      – SubjectFull: Ferrite circulators
        Type: general
      – SubjectFull: Circulators (Electrical engineering)
        Type: general
      – SubjectFull: Ferrite devices
        Type: general
      – SubjectFull: Ceramics
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      – SubjectFull: Construction materials
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      – TitleFull: Li2MoO4-based composite ceramics fabricated from temperature- and atmosphere-sensitive MnZn ferrite at room temperature.
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            NameFull: Väätäjä, Maria
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            NameFull: Kähäri, Hanna
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            NameFull: Juuti, Jari
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            NameFull: Jantunen, Heli
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            – D: 01
              M: 08
              Text: Aug2017
              Type: published
              Y: 2017
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            – TitleFull: Journal of the American Ceramic Society
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