Concentration and movement of neonicotinoids as particulate matter downwind during agricultural practices using air samplers in southwestern Ontario, Canada.

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Title: Concentration and movement of neonicotinoids as particulate matter downwind during agricultural practices using air samplers in southwestern Ontario, Canada.
Authors: Forero, Luis Gabriel1, Limay-Rios, Victor1, Xue, Yingen1, Schaafsma, Arthur1
Source: Chemosphere. Dec2017, Vol. 188, p130-138. 9p.
Subjects: Neonicotinoids -- Environmental aspects, Seed treatment, Particulate matter, Air sampling, Tillage, Clothianidin, Agriculture, Soil testing
Geographic Terms: Ontario
Abstract: Atmospheric emissions of neonicotinoid seed treatment insecticides as particulate matter in field crops occur mainly for two reasons: 1) due to abraded dust of treated seed generated during planting using vacuum planters, and 2) as a result of disturbances (tillage or wind events) in the surface of parental soils which release wind erodible soil-bound residues. In the present study, concentration and movement of neonicotinoids as particulate matter were quantified under real conditions using passive and active air samplers. Average neonicotinoid concentrations in Total Suspended Particulate (TSP) using passive samplers were 0.48 ng/cm 2 , trace, trace (LOD 0.80 and 0.04 ng/cm 2 for clothianidin and thiamethoxam, respectively), and using active samplers 16.22, 1.91 and 0.61 ng/m 3 during planting, tillage and wind events, respectively. There was a difference between events on total neonicotinoid concentration collected in particulate matter using either passive or active sampling. Distance of sampling from the source field during planting of treated seed had an effect on total neonicotinoid air concentration. However, during tillage distance did not present an effect on measured concentrations. Using hypothetical scenarios, values of contact exposure for a honey bee were estimated to be in the range from 1.1% to 36.4% of the reference contact LD 50 value of clothianidin of 44 ng/bee. [ABSTRACT FROM AUTHOR]
Copyright of Chemosphere is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Concentration and movement of neonicotinoids as particulate matter downwind during agricultural practices using air samplers in southwestern Ontario, Canada.
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  Data: <searchLink fieldCode="JN" term="%22Chemosphere%22">Chemosphere</searchLink>. Dec2017, Vol. 188, p130-138. 9p.
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  Data: <searchLink fieldCode="DE" term="%22Neonicotinoids+--+Environmental+aspects%22">Neonicotinoids -- Environmental aspects</searchLink><br /><searchLink fieldCode="DE" term="%22Seed+treatment%22">Seed treatment</searchLink><br /><searchLink fieldCode="DE" term="%22Particulate+matter%22">Particulate matter</searchLink><br /><searchLink fieldCode="DE" term="%22Air+sampling%22">Air sampling</searchLink><br /><searchLink fieldCode="DE" term="%22Tillage%22">Tillage</searchLink><br /><searchLink fieldCode="DE" term="%22Clothianidin%22">Clothianidin</searchLink><br /><searchLink fieldCode="DE" term="%22Agriculture%22">Agriculture</searchLink><br /><searchLink fieldCode="DE" term="%22Soil+testing%22">Soil testing</searchLink>
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  Data: <searchLink fieldCode="DE" term="%22Ontario%22">Ontario</searchLink>
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  Data: Atmospheric emissions of neonicotinoid seed treatment insecticides as particulate matter in field crops occur mainly for two reasons: 1) due to abraded dust of treated seed generated during planting using vacuum planters, and 2) as a result of disturbances (tillage or wind events) in the surface of parental soils which release wind erodible soil-bound residues. In the present study, concentration and movement of neonicotinoids as particulate matter were quantified under real conditions using passive and active air samplers. Average neonicotinoid concentrations in Total Suspended Particulate (TSP) using passive samplers were 0.48 ng/cm 2 , trace, trace (LOD 0.80 and 0.04 ng/cm 2 for clothianidin and thiamethoxam, respectively), and using active samplers 16.22, 1.91 and 0.61 ng/m 3 during planting, tillage and wind events, respectively. There was a difference between events on total neonicotinoid concentration collected in particulate matter using either passive or active sampling. Distance of sampling from the source field during planting of treated seed had an effect on total neonicotinoid air concentration. However, during tillage distance did not present an effect on measured concentrations. Using hypothetical scenarios, values of contact exposure for a honey bee were estimated to be in the range from 1.1% to 36.4% of the reference contact LD 50 value of clothianidin of 44 ng/bee. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
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  Data: <i>Copyright of Chemosphere is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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    Identifiers:
      – Type: doi
        Value: 10.1016/j.chemosphere.2017.08.126
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 9
        StartPage: 130
    Subjects:
      – SubjectFull: Neonicotinoids -- Environmental aspects
        Type: general
      – SubjectFull: Seed treatment
        Type: general
      – SubjectFull: Particulate matter
        Type: general
      – SubjectFull: Air sampling
        Type: general
      – SubjectFull: Tillage
        Type: general
      – SubjectFull: Clothianidin
        Type: general
      – SubjectFull: Agriculture
        Type: general
      – SubjectFull: Soil testing
        Type: general
      – SubjectFull: Ontario
        Type: general
    Titles:
      – TitleFull: Concentration and movement of neonicotinoids as particulate matter downwind during agricultural practices using air samplers in southwestern Ontario, Canada.
        Type: main
  BibRelationships:
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      – PersonEntity:
          Name:
            NameFull: Forero, Luis Gabriel
      – PersonEntity:
          Name:
            NameFull: Limay-Rios, Victor
      – PersonEntity:
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            NameFull: Xue, Yingen
      – PersonEntity:
          Name:
            NameFull: Schaafsma, Arthur
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          Dates:
            – D: 01
              M: 12
              Text: Dec2017
              Type: published
              Y: 2017
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              Value: 00456535
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            – Type: volume
              Value: 188
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            – TitleFull: Chemosphere
              Type: main
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