Bibliographic Details
| Title: |
Synthesis and Photophysical Properties of λ5-Phosphinines as a Tunable Fluorophore. |
| Authors: |
Naoki Hashimoto1, Rika Umano1, Yusuke Ochi1, Kiyoka Shimahara1, Jun Nakamura2, Shigeki Mori2, Hidetoshi Ohta1, Yutaka Watanabe1, Minoru Hayashi1 mhayashi@ehime-u.ac.jp |
| Source: |
Journal of the American Chemical Society. 2/14/2018, Vol. 140 Issue 6, p2046-2049. 4p. |
| Subjects: |
Phosphorine, Photoexcitation, Fluorescence, Electrophilic substitution reactions, Fluorophore synthesis |
| Abstract: |
A practical synthesis of a variety of λ5-phosphinines, which show distinct fluorescence both in solution and solid state, is described. Both C4-selective electrophilic substitutions and the following conversions realized an easy preparation of a wide range of derivatives having several substituents for electronic modification, which provides the potential for fine-tuning of the photophysical properties. [ABSTRACT FROM AUTHOR] |
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| Database: |
Engineering Source |
