View in EDS

Synthesis and Photophysical Properties of λ5-Phosphinines as a Tunable Fluorophore.

Saved in:
Bibliographic Details
Title: Synthesis and Photophysical Properties of λ5-Phosphinines as a Tunable Fluorophore.
Authors: Naoki Hashimoto1, Rika Umano1, Yusuke Ochi1, Kiyoka Shimahara1, Jun Nakamura2, Shigeki Mori2, Hidetoshi Ohta1, Yutaka Watanabe1, Minoru Hayashi1 mhayashi@ehime-u.ac.jp
Source: Journal of the American Chemical Society. 2/14/2018, Vol. 140 Issue 6, p2046-2049. 4p.
Subjects: Phosphorine, Photoexcitation, Fluorescence, Electrophilic substitution reactions, Fluorophore synthesis
Abstract: A practical synthesis of a variety of λ5-phosphinines, which show distinct fluorescence both in solution and solid state, is described. Both C4-selective electrophilic substitutions and the following conversions realized an easy preparation of a wide range of derivatives having several substituents for electronic modification, which provides the potential for fine-tuning of the photophysical properties. [ABSTRACT FROM AUTHOR]
Copyright of Journal of the American Chemical Society is the property of American Chemical Society and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
FullText Text:
  Availability: 0
Header DbId: egs
DbLabel: Engineering Source
An: 128050537
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
IllustrationInfo
Items – Name: Title
  Label: Title
  Group: Ti
  Data: Synthesis and Photophysical Properties of λ<superscript>5</superscript>-Phosphinines as a Tunable Fluorophore.
– Name: Author
  Label: Authors
  Group: Au
  Data: <searchLink fieldCode="AR" term="%22Naoki+Hashimoto%22">Naoki Hashimoto</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Rika+Umano%22">Rika Umano</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Yusuke+Ochi%22">Yusuke Ochi</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Kiyoka+Shimahara%22">Kiyoka Shimahara</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Jun+Nakamura%22">Jun Nakamura</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Shigeki+Mori%22">Shigeki Mori</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Hidetoshi+Ohta%22">Hidetoshi Ohta</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Yutaka+Watanabe%22">Yutaka Watanabe</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Minoru+Hayashi%22">Minoru Hayashi</searchLink><relatesTo>1</relatesTo><i> mhayashi@ehime-u.ac.jp</i>
– Name: TitleSource
  Label: Source
  Group: Src
  Data: <searchLink fieldCode="JN" term="%22Journal+of+the+American+Chemical+Society%22">Journal of the American Chemical Society</searchLink>. 2/14/2018, Vol. 140 Issue 6, p2046-2049. 4p.
– Name: Subject
  Label: Subjects
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Phosphorine%22">Phosphorine</searchLink><br /><searchLink fieldCode="DE" term="%22Photoexcitation%22">Photoexcitation</searchLink><br /><searchLink fieldCode="DE" term="%22Fluorescence%22">Fluorescence</searchLink><br /><searchLink fieldCode="DE" term="%22Electrophilic+substitution+reactions%22">Electrophilic substitution reactions</searchLink><br /><searchLink fieldCode="DE" term="%22Fluorophore+synthesis%22">Fluorophore synthesis</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: A practical synthesis of a variety of λ5-phosphinines, which show distinct fluorescence both in solution and solid state, is described. Both C4-selective electrophilic substitutions and the following conversions realized an easy preparation of a wide range of derivatives having several substituents for electronic modification, which provides the potential for fine-tuning of the photophysical properties. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of the American Chemical Society is the property of American Chemical Society and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
PLink https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&db=egs&AN=128050537
RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1021/jacs.7b13018
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 4
        StartPage: 2046
    Subjects:
      – SubjectFull: Phosphorine
        Type: general
      – SubjectFull: Photoexcitation
        Type: general
      – SubjectFull: Fluorescence
        Type: general
      – SubjectFull: Electrophilic substitution reactions
        Type: general
      – SubjectFull: Fluorophore synthesis
        Type: general
    Titles:
      – TitleFull: Synthesis and Photophysical Properties of λ5-Phosphinines as a Tunable Fluorophore.
        Type: main
  BibRelationships:
    HasContributorRelationships:
      – PersonEntity:
          Name:
            NameFull: Naoki Hashimoto
      – PersonEntity:
          Name:
            NameFull: Rika Umano
      – PersonEntity:
          Name:
            NameFull: Yusuke Ochi
      – PersonEntity:
          Name:
            NameFull: Kiyoka Shimahara
      – PersonEntity:
          Name:
            NameFull: Jun Nakamura
      – PersonEntity:
          Name:
            NameFull: Shigeki Mori
      – PersonEntity:
          Name:
            NameFull: Hidetoshi Ohta
      – PersonEntity:
          Name:
            NameFull: Yutaka Watanabe
      – PersonEntity:
          Name:
            NameFull: Minoru Hayashi
    IsPartOfRelationships:
      – BibEntity:
          Dates:
            – D: 14
              M: 02
              Text: 2/14/2018
              Type: published
              Y: 2018
          Identifiers:
            – Type: issn-print
              Value: 00027863
          Numbering:
            – Type: volume
              Value: 140
            – Type: issue
              Value: 6
          Titles:
            – TitleFull: Journal of the American Chemical Society
              Type: main
ResultId 1